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Volume 43
Main Index

Issue 1


Formation of Multinary Intermetallics from Reduction of Perovskites by Aluminum Flux: M3Au6+xAl26Ti (M = Ca, Sr, Yb), a Stuffed Variant of the BaHg11 Type
Susan E. Latturner and Mercouri G. Kanatzidis
pp 2 - 4; DOI:
10.1021/ic034967q
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Synthesis and Characterization of a Magnetic Semiconductor Na2RuO4 Containing One-Dimensional Chains of Ru6+
Masahiro Shikano, Reinhard K. Kremer, Martin Ahrens, H.-J. Koo, M.-H. Whangbo, and Jacques Darriet
pp 5 - 7; DOI:
10.1021/ic035191w
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Coordinating Anions: (Phosphino)tetraphenylborate Ligands as New Reagents for Synthesis
Christine M. Thomas and Jonas C. Peters
pp 8 - 10; DOI:
10.1021/ic0350234
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Synthesis of Hybrid Framework Materials under "Dry" Hydrothermal Conditions: Crystal Structure and Magnetic Properties of Mn2(H2PO4)2(C2O4)
Zoe A. D. Lethbridge, Martin J. Smith, Satish K. Tiwary, Andrew Harrison, and Philip Lightfoot
pp 11 - 13; DOI:
10.1021/ic0349712
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Research on Soluble Metal Sulfides: From Polysulfido Complexes to Functional Models for the Hydrogenases
Thomas B. Rauchfuss
pp 14 - 26; DOI:
10.1021/ic0343760
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Exohedral Multiple Bonding in Polyhedra. 2. Skeletal Distortions in Ring-Stacked Boranes
Musiri M. Balakrishnarajan and Roald Hoffmann
pp 27 - 32; DOI:
10.1021/ic034891y
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Novel Triazole-Bridged Cadmium Coordination Polymers Varying from Zero- to Three-Dimensionality
Long Yi, Bin Ding, Bin Zhao, Peng Cheng, Dai-Zheng Liao, Shi-Ping Yan, and Zong-Hui Jiang
pp 33 - 43; DOI:
10.1021/ic0348244
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Decomposition of A-Type Sandwiches. Synthesis and Characterization of New Polyoxometalates Incorporating Multiple d-Electron-Centered Units
Michelle D. Ritorto, Travis M. Anderson, Wade A. Neiwert, and Craig L. Hill
pp 44 - 49; DOI:
10.1021/ic035115t
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Lead Tetrakis(imidazolyl)borate Solids: Anion Exchange, Solvent Intercalation, and Self Assembly of an Organic Anion
Barton H. Hamilton, Kathryn A. Kelly, Todd A. Wagler, Matthew P. Espe, and Christopher J. Ziegler
pp 50 - 56; DOI:
10.1021/ic035117d
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Reactions of the Tetrahedral Clusters [MCo3(CO)12]- (M = Ru, Fe) with Functional Mono- and Diynes
Aldjia Choualeb, Pierre Braunstein, Jacky Rosé, and Richard Welter
pp 57 - 71; DOI:
10.1021/ic034832k
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Synthesis of Pt(dpk)Cl4 and the Reversible Hydration to Pt(dpk-O-OH)Cl3·H-phenCl: X-ray, Spectroscopic, and Electrochemical Characterization
Katherine N. Crowder, Stephanie J. Garcia, Rebekah L. Burr, J. Micah North, Mike H. Wilson, Brian L. Conley, Phillip E. Fanwick, Peter S. White, Karl D. Sienerth, and Robert M. Granger, II
pp 72 - 78; DOI:
10.1021/ic035102f
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Monomeric Oxovanadium(IV) Compounds of the General Formula cis-[VIV(=O)(X)(LNN)2]+/0 {X = OH-, Cl-, SO42- and LNN = 2,2'-Bipyridine (Bipy) or 4,4'-Disubstituted Bipy}
Georgios D. Triantafillou, Evagelos I. Tolis, Aris Terzis, Yiannis Deligiannakis, Catherine P. Raptopoulou, Michael P. Sigalas, and Themistoklis A. Kabanos
pp 79 - 91; DOI:
10.1021/ic034440d
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Module-Based Assembly of Copper(II) Chloranilate Compounds: Syntheses, Crystal Structures, and Magnetic Properties of {[Cu2(CA)(terpy)2][Cu(CA)2]}n and {[Cu2(CA)(terpy)2(dmso)2][Cu(CA)2(dmso)2](EtOH)}n (H2CA = Chloranilic Acid, terpy = 2,2':6',2' '-Terpyridine, dmso = Dimethyl Sulfoxide)
Mitsuhiro Kawahara, Md. Khayrul Kabir, Koichi Yamada, Keiichi Adachi, Hitoshi Kumagai, Yasuo Narumi, Koichi Kindo, Susumu Kitagawa, and Satoshi Kawata
pp 92 - 100; DOI:
10.1021/ic035044y
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Polynuclear Manganese Complexes with the Dicarboxylate Ligand m-Phenylenedipropionate: A Hexanuclear Mixed-Valence (3MnIII, 3MnIV) Complex
Cristina Cañada-Vilalta, William E. Streib, John C. Huffman, Ted A. O'Brien, Ernest R. Davidson, and George Christou
pp 101 - 115; DOI:
10.1021/ic034973m
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Higher Order Speciation Effects on Plutonium L3 X-ray Absorption Near Edge Spectra
Steven D. Conradson, Kent D. Abney, Bruce D. Begg, Erik D. Brady, David L. Clark, Christophe den Auwer, Mei Ding, Peter K. Dorhout, Francisco J. Espinosa-Faller, Pamela L. Gordon, Richard G. Haire, Nancy J. Hess, Ryan F. Hess, D. Webster Keogh, Gerard H. Lander, Anthony J. Lupinetti, Luis A. Morales, Mary P. Neu, Phillip D. Palmer, Patricia Paviet-Hartmann, Sean D. Reilly, Wolfgang H. Runde, C. Drew Tait, D. Kirk Veirs, and Franck Wastin
pp 116 - 131; DOI:
10.1021/ic0346477
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Transient Mixed-Valence Character of ReI4(CO)12(4,4'-bpy)4Cl4
Theodore P. Ortiz, Jason A. Marshall, Luke A. Emmert, Jing Yang, Wonsook Choi, Alison L. Costello, and James A. Brozik
pp 132 - 141; DOI:
10.1021/ic034560l
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A Reinterpretation of the Magnetic Properties of the Mixed-Valence (NbV/NbIV) Zintl Phase, Cs9Nb2As6
Athena S. Sefat and J. E. Greedan
pp 142 - 143; DOI:
10.1021/ic035101n
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Structure and Magnetism of the Tetra-Copper(II)-Substituted Heteropolyanion [Cu4K2(H2O)8(-AsW9O33)2]8-
Ulrich Kortz, Saritha Nellutla, Ashley C. Stowe, Naresh S. Dalal, Johan van Tol, and Bassem S. Bassil
pp 144 - 154; DOI:
10.1021/ic034697b
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Structure and Physical Properties of [-Tris(1,4-bis(tetrazol-1-yl)butane-N4,N4')iron(II)] Bis(hexafluorophosphate), a New Fe(II) Spin-Crossover Compound with a Three-Dimensional Threefold Interlocked Crystal Lattice
C. Matthias Grunert, Johannes Schweifer, Peter Weinberger, Wolfgang Linert, Kurt Mereiter, Gerfried Hilscher, Martin Müller, Günter Wiesinger, and Petra J. van Koningsbruggen
pp 155 - 165; DOI:
10.1021/ic034452z
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Cyclotriphosphazene Hydrazides as Efficient Multisite Coordination Ligands. 3-fac-non-geminal-N3 Coordination of spiro-N3P3[O2C12H8][N(Me)NH2]4 (L) in L2CoCl3 and L2M(NO3)2 (M = Ni, Zn, Cd)
Vadapalli Chandrasekhar, Venkatasubbaiah Krishnan, Alexander Steiner, and Jamie F. Bickley
pp 166 - 172; DOI:
10.1021/ic034561d
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Preparation, Characterization, and Condensation of Copper Tellurolate Clusters in the Pores of Periodic Mesoporous Silica MCM-41
Collin M. Kowalchuk, Günter Schmid, Wolfgang Meyer-Zaika, Yining Huang, and John F. Corrigan
pp 173 - 180; DOI:
10.1021/ic0300868
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New 1- and 2-Dimensional Polymeric Structures of Cyanopyridine Complexes of AgI and CuI
Ping Lin, Richard A. Henderson, Ross W. Harrington, William Clegg, Chuan-De Wu, and Xin-Tao Wu
pp 181 - 188; DOI:
10.1021/ic030254w
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Anionic Platinum Complexes with 2-Pyridylphosphines as Ligands for Rhodium: Synthesis of Zwitterionic Pt-Rh Organometallic Compounds
Juan A. Casares, Pablo Espinet, José M. Martín-Alvarez, and Verónica Santos
pp 189 - 197; DOI:
10.1021/ic034863f
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Synthesis and Structures of New Pyromellitate Coordination Polymers with Piperazine as a Ligand
S. V. Ganesan and Srinivasan Natarajan
pp 198 - 205; DOI:
10.1021/ic034836p
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Coordination Chemistry of the Antitumor Metallocene Molybdocene Dichloride with Biological Ligands
Jenny B. Waern and Margaret M. Harding
pp 206 - 213; DOI:
10.1021/ic034892q
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A Convenient Route to Lanthanide Triiodide THF Solvates. Crystal Structures of LnI3(THF)4 [Ln = Pr] and LnI3(THF)3.5 [Ln = Nd, Gd, Y]
Keith Izod, Stephen T. Liddle, and William Clegg
pp 214 - 218; DOI:
10.1021/ic034851u
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Synthesis and Characterization of Mo6 Chalcobromides and Cyano-Substituted Compounds Built from a Novel [(Mo6Bri6Yi2)La6]n- Discrete Cluster Unit (Yi = S or Se and La = Br or CN)
Stéphane Cordier, Nikolaï G. Naumov, Diala Salloum, Frédéric Paul, and Christiane Perrin
pp 219 - 226; DOI:
10.1021/ic034443q
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Cooperative Spin Crossover and Order-Disorder Phenomena in a Mononuclear Compound [Fe(DAPP)(abpt)](ClO4)2 [DAPP = [Bis(3-aminopropyl)(2-pyridylmethyl)amine], abpt = 4-Amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole]
Galina S. Matouzenko, Azzedine Bousseksou, Serguei A. Borshch, Monique Perrin, Samir Zein, Lionel Salmon, Gabor Molnar, and Sylvain Lecocq
pp 227 - 236; DOI:
10.1021/ic034450e
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Novel Lanthanide Coordination Polymers with a Flexible Disulfoxide Ligand, 1,2-Bis(ethylsulfinyl)ethane: Structures, Stereochemistry, and the Influences of Counteranions on the Framework Formations
Jian-Rong Li, Xian-He Bu, and Ruo-Hua Zhang
pp 237 - 244; DOI:
10.1021/ic034772i
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Crystal Structure and Spectroscopic Study of Novel Two- and Three-Dimensional Photoluminescent Eu(III)-Adipate Compounds
YooJin Kim, Myungkoo Suh, and Duk-Young Jung
pp 245 - 250; DOI:
10.1021/ic034418k
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Synthesis of New Porphyrins with Peripheral Conjugated Chelates and Their Use for the Preparation of Porphyrin Dimers Linked by Metal Ions
Sébastien Richeter, Christophe Jeandon, Jean-Paul Gisselbrecht, Roland Graff, Romain Ruppert, and Henry J. Callot
pp 251 - 263; DOI:
10.1021/ic035203d
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Oxyl Radical Required for O-O Bond Formation in Synthetic Mn-Catalyst
Marcus Lundberg, Margareta R. A. Blomberg, and Per E. M. Siegbahn
pp 264 - 274; DOI:
10.1021/ic0348188
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Synthesis and Group 4 Complexes of Tris(pyrrolyl--methyl)amine
Yanhui Shi, Changsheng Cao, and Aaron L. Odom
pp 275 - 281; DOI:
10.1021/ic035049v
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Synthesis and Structure of Ca18Li5In25.07: A Novel Intergrowth of Li-Centered In12 Icosahedral Clusters and Electron-Precise Zintl Layers
Jiang-Gao Mao, Joanna Goodey, and Arnold M. Guloy
pp 282 - 289; DOI:
10.1021/ic034594t
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Interaction of Palladium(II) and Platinum(II) Complexes with Microperoxidase-11 Studied by Electrospray Mass Spectrometry and MS/MS Analysis
Xiaojuan Sun, Chen Jin, Yuhua Mei, Gaosheng Yang, Zijian Guo, and Longgen Zhu
pp 290 - 296; DOI:
10.1021/ic034491a
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A DFT Study of Model Complexes of Zinc Hydrolases and Their Inhibition by Hydroxamic Acids
David A. Brown, Laurence P. Cuffe, Noel J. Fitzpatrick, and Áine T. Ryan
pp 297 - 302; DOI:
10.1021/ic034432x
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Design Aspects for the Development of Mixed-Metal Supramolecular Complexes Capable of Visible Light Induced Photocleavage of DNA
Alvin A. Holder, Shawn Swavey, and Karen J. Brewer
pp 303 - 308; DOI:
10.1021/ic035029t
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Mechanism of the Axial Ligand Substitution Reactions on the Head-to-Tail -Pyridonato-Bridged cis-Diammineplatinum(III) Dinuclear Complex with Olefins
Moritatsu Arime, Koji Ishihara, and Kazuko Matsumoto
pp 309 - 316; DOI:
10.1021/ic034599q
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A Facile Route to Bimetallic Ruthenium Dipyridophenazine Complexes
Clive Metcalfe, Ihtshamul Haq, and Jim A. Thomas
pp 317 - 323; DOI:
10.1021/ic034749x
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Solution Structures of Chromium(VI) Complexes with Glutathione and Model Thiols
Aviva Levina and Peter A. Lay
pp 324 - 335; DOI:
10.1021/ic034901v
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Synthesis, Characterization, and Crystal Structures of Three New Divalent Metal Carboxylate-Sulfonates with a Layered and One-Dimensional Structure
Zhong-Ming Sun, Jiang-Gao Mao, Yan-Qiong Sun, Hui-Yi Zeng, and Abraham Clearfield
pp 336 - 341; DOI:
10.1021/ic0343307
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Ab Initio Calculations and Normal Coordinate Analysis of Ruthenium Tris--diimine Complexes
Bruce D. Alexander and Trevor J. Dines
pp 342 - 350; DOI:
10.1021/ic034721l
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Reactivity of the Hydrido/Nitrosyl Radical MHCl(NO)(CO)(PiPr3)2, M = Ru, Os
Alexei V. Marchenko, Andrei N. Vedernikov, David F. Dye, Maren Pink, Jeffrey M. Zaleski, and Kenneth G. Caulton
pp 351 - 360; DOI:
10.1021/ic0349407
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Low Melting N-4-Functionalized-1-alkyl or Polyfluoroalkyl-1,2,4-triazolium Salts
Yousef R. Mirzaei, Hong Xue, and Jean'ne M. Shreeve
pp 361 - 367; DOI:
10.1021/ic0351693
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Anionic Ligand Exchange on ZrPO4Cl(dmso): Alkoxide and Carboxylate Derivatives
Riccardo Vivani, Silvia Masci, and Giulio Alberti
pp 368 - 374; DOI:
10.1021/ic034695r
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Synthesis and Characterization of New Mg2Al-Paratungstate Layered Double Hydroxides
M. del Arco, D. Carriazo, S. Gutiérrez, C. Martín, and V. Rives
pp 375 - 384; DOI:
10.1021/ic0347790
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Molten Flux Synthesis of an Analogous Series of Layered Alkali Samarium Selenogermanate Compounds
Benjamin R. Martin and Peter K. Dorhout
pp 385 - 391; DOI:
10.1021/ic034724y
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Century-Known Copper Salt Cu(OAc)(OMe) Proven To Be a Unique Magnetic Lattice Composed of Tetranuclear Copper(II) Species with a Rare Binding Mode of the Acetate Anion
Iryna A. Koval, Patrick Gamez, Olivier Roubeau, Willem L.Driessen, Martin Lutz, Anthony L. Spek, and Jan Reedijk:
pp 392 - 392; DOI:
10.1021/ic030315q
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Issue 2


Pushing the Frontiers of Hard and Soft Scorpionate Chemistry
Christopher A. Dodds, Alan R. Kennedy, John Reglinski, and Mark D. Spicer
pp 394 - 395; DOI:
10.1021/ic035167i
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Sensitization of TiO2 by Supramolecules Containing Zinc Porphyrins and Ruthenium-Polypyridyl Complexes
Ana F. Nogueira, Luis Fernando O. Furtado, André L. B. Formiga, Marcelo Nakamura, Koiti Araki, and Henrique E. Toma
pp 396 - 398; DOI:
10.1021/ic0345727
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Synthesis and Characterization of Cyclotetraphosphato Complexes of Rh(I), Ir(I), Ru(II), and Pd(II)
Sou Kamimura, Shigeki Kuwata, Masakazu Iwasaki, and Youichi Ishii
pp 399 - 401; DOI:
10.1021/ic0350382
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X-ray Absorption Spectroscopy of Selenate Reductase
Megan J. Maher, Joanne Santini, Ingrid J. Pickering, Roger C. Prince, Joan M. Macy, and Graham N. George
pp 402 - 404; DOI:
10.1021/ic035136n
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The Unexpected Motional Isotropy of the Tin Atom in a Tricoordinate Stannylium Cation
Joseph B. Lambert, Lijun Lin, Israel Nowik, and Rolfe H. Herber
pp 405 - 407; DOI:
10.1021/ic035152k
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Probing the Solvent Accessibility and Electron Density of Adenine: Oxidation of 7-Deazaadenine in Bent DNA and Purine Doublets
Jennifer D. Tibodeau and H. Holden Thorp
pp 408 - 410; DOI:
10.1021/ic034989c
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Syntheses and Thermal Reactivities of Tetradentate Metalloenediynes of Cu(II) and Zn(II)
Tilak Chandra, Russell A. Allred, Brian J. Kraft, Lisa M. Berreau, and Jeffrey M. Zaleski
pp 411 - 420; DOI:
10.1021/ic030218x
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Dinuclear Complexes of Chiral Tetradentate Pyridylimine Ligands: Diastereoselectivity, Positive Cooperativity, Anion Selectivity, Ligand Self-Sorting Based on Chirality, and Magnetism
Shane G. Telfer, Tomohiro Sato, Reiko Kuroda, Julie Lefebvre, and Daniel B. Leznoff
pp 421 - 429; DOI:
10.1021/ic034585k
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Hybrid Cluster-Cages Formed via Cyanometalate Condensation: CsCo4Ru6S2(CN)12, Co4Ru9S6(CN)9, and Rh4Ru9S6(CN)9 Frameworks
Matthew L. Kuhlman and Thomas B. Rauchfuss
pp 430 - 435; DOI:
10.1021/ic034745s
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R6TT'2, New Variants of the Fe2P Structure Type. Sc6TTe2 (T = Ru, Os, Rh, Ir), Lu6MoSb2, and the Anti-typic Sc6Te0.80Bi1.68
Ling Chen and John D. Corbett
pp 436 - 442; DOI:
10.1021/ic0302581
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A Variable Ag-Cr-Oxalate Channel Lattice: [MxAg0.5-x(H2O)3]@[Ag2.5Cr(C2O4)3], M = K, Cs, Ag
Philip A. W. Dean, Don Craig, Ian Dance, Vanessa Russell, and Marcia Scudder
pp 443 - 449; DOI:
10.1021/ic034988k
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Solvent-Dependent Coordination Polymers: Cobalt Complexes of 3,5-Dinitrobenzoic Acid and 3,5-Dinitro-4-methylbenzoic Acid with 4,4'-Bipyrdine
V. R. Pedireddi and Sunil Varughese
pp 450 - 457; DOI:
10.1021/ic0349499
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Toward a Computational Description of Nitrile Hydratase: Studies of the Ground State Bonding and Spin-Dependent Energetics of Mononuclear, Non-Heme Fe(III) Complexes
Christopher H. Chang, Amy J. Boone, Rodney J. Bartlett, and Nigel G. J. Richards
pp 458 - 472; DOI:
10.1021/ic0350032
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Coordination Frameworks Containing the Pyrimidin-4-olate Ligand. Synthesis, Thermal, Magnetic, and ab Initio XRPD Structural Characterization of Nickel and Zinc Derivatives
Elisa Barea, Jorge A. R. Navarro, Juan M. Salas, Norberto Masciocchi, Simona Galli, and Angelo Sironi
pp 473 - 481; DOI:
10.1021/ic0351287
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Photochromism of Metal Complexes Composed of Diarylethene Ligands and Zn(II), Mn(II), and Cu(II) Hexafluoroacetylacetonates
Kenji Matsuda, Kohsuke Takayama, and Masahiro Irie
pp 482 - 489; DOI:
10.1021/ic035020r
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Rearrangement Reactions of the Transient Lewis Acids (CF3)3B and (CF3)3BCF2: An Experimental and Theoretical Study
Maik Finze, Eduard Bernhardt, Manfred Zähres, and Helge Willner
pp 490 - 505; DOI:
10.1021/ic0350640
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EPR and Magnetic Properties of Heteronuclear MnnMg6-n(O2CNEt2)12: Impact of Structural Distortions on Mn(II) in Weak Ligand Fields
M. Tyler Caudle, Charles. K. Mobley, Laura M. Bafaro, Russell LoBrutto, Gordon T. Yee, and Thomas L. Groy
pp 506 - 514; DOI:
10.1021/ic0349757
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Supramolecular Recognition of Heteropairs of Lanthanide Ions: A Step toward Self-Assembled Bifunctional Probes
Nicolas André, Thomas B. Jensen, Rosario Scopelliti, Daniel Imbert, Mourad Elhabiri, Gérard Hopfgartner, Claude Piguet, and Jean-Claude G. Bünzli
pp 515 - 529; DOI:
10.1021/ic0351996
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A New Totally Flat N(sp2)C(sp2)N(sp2) Pincer Palladacycle: Synthesis and Photoluminescent Properties
Crestina S. Consorti, Gunter Ebeling, Fabiano Rodembusch, Valter Stefani, Paolo R. Livotto, Frank Rominger, Frank H. Quina, Chang Yihwa, and Jairton Dupont
pp 530 - 536; DOI:
10.1021/ic0346679
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Supramolecular Structural Variations with Changes in Anion and Solvent in Silver(I) Complexes of a Semirigid, Bitopic Tris(pyrazolyl)methane Ligand
Daniel L. Reger, Radu F. Semeniuc, Vitaly Rassolov, and Mark D. Smith
pp 537 - 554; DOI:
10.1021/ic035207i
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Neutron Diffraction Study of [H4Co4(C5Me4Et)4], a Tetrahedral Metal Cluster Complex with Four Face-Bridging Hydride Ligands
Robert Bau, Nam N. Ho, Joerg J. Schneider, Sax A. Mason, and Garry J. McIntyre
pp 555 - 558; DOI:
10.1021/ic030275q
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Synthesis and Structural Characterization of 0D Vanadium Borophosphate [Co(en)3]2[V3P3BO19][H2PO4]·4H2O and 1D Vanadium Oxides [Co(en)3][V3O9]·H2O and [Co(dien)2][V3O9]·H2O Templated by Cobalt Complexes: Cooperative Organization of the Complexes and the Inorganic Networks
Yu Wang, Jihong Yu, Qinhe Pan, Yu Du, Yongchun Zou, and Ruren Xu
pp 559 - 565; DOI:
10.1021/ic034241u
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Molecular Paramagnetic Semiconductor: Crystal Structures and Magnetic and Conducting Properties of the Ni(dmit)2 Salts of 6-Oxoverdazyl Radical Cations (dmit = 1,3-Dithiol-2-thione-4,5-dithiolate)
K. Mukai, N. Senba, T. Hatanaka, H. Minakuchi, K. Ohara, M. Taniguchi, Y. Misaki, Y. Hosokoshi, K. Inoue, and N. Azuma
pp 566 - 576; DOI:
10.1021/ic030068q
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Synthesis and Crystal Structures of A New Series of Intramolecular Bridged Alkylcobaloxime Complexes
Kaian Yao, Xin Zhang, Huilan Chen, Yuhua Mei, and Yizhi Li
pp 577 - 583; DOI:
10.1021/ic035147g
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Platinum Complexes with NH Groups on the Carrier Ligand and with Only One Guanine or Hypoxanthine Derivative. Informative Models for Assessing Relative Nucleobase and Nucleotide Hydrogen-Bond Interactions with Amine Ligands in Solution
Maria Carlone, Luigi G. Marzilli, and Giovanni Natile
pp 584 - 592; DOI:
10.1021/ic030236e
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An ab Initio Study on Luminescent Properties and Aurophilic Attraction of Binuclear Gold(I) Complexes with Phosphinothioether Ligands
Qing-Jiang Pan and Hong-Xing Zhang
pp 593 - 601; DOI:
10.1021/ic0300159
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Adducts of Acetylene and Dimethylacetylenedicarboxylate at Sulfurs in Sulfur-Bridged Incomplete Cubane-Type Tungsten Clusters
Yasuhiro Ide, Makoto Sasaki, Masataka Maeyama, and Takashi Shibahara
pp 602 - 612; DOI:
10.1021/ic0349860
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Density Functional Study of a -1,1-Carboxylate Bridged Fe(III)-O-Fe(IV) Model Complex. 2. Comparison with Ribonucleotide Reductase Intermediate X
Wen-Ge Han, Timothy Lovell, Tiqing Liu, and Louis Noodleman
pp 613 - 621; DOI:
10.1021/ic0206443
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Binuclear Rhenium(I) Complexes with Bridging [2.2]Paracyclophane-Diimine Ligands: Probing Electronic Coupling through - Interactions
PJ Ball, Tanya Rarog Shtoyko, Jeanette A. Krause Bauer, Warren J. Oldham, and William B. Connick
pp 622 - 632; DOI:
10.1021/ic0348648
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Syntheses, Structures, and Properties of Intercalation Compounds of Silver(I) Complex with [2.2]Paracyclophane
Megumu Munakata, Shu Qin Liu, Hisashi Konaka, Takayoshi Kuroda-Sowa, Yusaku Suenaga, Masahiko Maekawa, Hisao Nakagawa, and Yuji Yamazaki
pp 633 - 641; DOI:
10.1021/ic0302433
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Generation of Spirotricyclic Site-Differentiated Cyclotriphosphazenes: A Solvent-Free Approach to Multidentate N/O Donor Ligand Systems
Michael Harmjanz, Ingmar M. Piglosiewicz, Brian L. Scott, and Carol J. Burns
pp 642 - 650; DOI:
10.1021/ic034990b
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Synthesis and Spectroscopy of -Oxo (O2-)-Bridged Heme/Non-heme Diiron Complexes: Models for the Active Site of Nitric Oxide Reductase
Ian M. Wasser, Constantinus F. Martens, Claudio N. Verani, Eva Rentschler, Hong-wei Huang, Pierre Moënne-Loccoz, Lev N. Zakharov, Arnold L. Rheingold, and Kenneth D. Karlin
pp 651 - 662; DOI:
10.1021/ic0348143
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Intense Fluorescence of Metal-to-Ligand Charge Transfer in [Pt(0)(binap)2] [binap = 2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]
Zainul Abedin-Siddique, Takeshi Ohno, Koichi Nozaki, and Taro Tsubomura
pp 663 - 673; DOI:
10.1021/ic034527z
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Structural Conversions of Molybdenum-Iron-Sulfur Edge-Bridged Double Cubanes and PN-Type Clusters Topologically Related to the Nitrogenase P-Cluster
Yugen Zhang and R. H. Holm
pp 674 - 682; DOI:
10.1021/ic030259t
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Carbonyl-Carboxylato-Ruthenium Complexes Incorporating Diimine Ligands and Unexpected Cyclometalation of Carboxylate Ligands
Pauline Pearson, Christopher M. Kepert, Glen B. Deacon, Leone Spiccia, Andrew C. Warden, Brian W. Skelton, and Allan H. White
pp 683 - 691; DOI:
10.1021/ic0348401
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Europium(II) and Ytterbium(II) Cyclic Organohydroborates: An Europium(II) Complex with an Agostic Interaction
Xuenian Chen, Soyoung Lim, Christine E. Plenik, Shengming Liu, Bin Du, Edward A. Meyers, and Sheldon G. Shore
pp 692 - 698; DOI:
10.1021/ic030249s
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[Mg(XeF2)n](AsF6)2 (n = 4, 2): First Compounds of Magnesium with XeF2
Melita Tramek, Primo Benki, and Boris emva
pp 699 - 703; DOI:
10.1021/ic034826o
PDF
Iridium(III) Complexes Formed by O-H and/Or C-H Activation of 2-(Arylazo)phenols
Rama Acharyya, Falguni Basuli, Ren-Zhang Wang, Thomas C. W. Mak, and Samaresh Bhattacharya
pp 704 - 711; DOI:
10.1021/ic034785w
PDF
Three Olefin Copper(I) Dimeric Complexes with 2-, 3-, and 4-Pyridylacrylic Acid and Their Electrochemical Properties
Yong-Hua Li, Xi-Sen Wang, Hong Zhao, Rong-Xin Yuan, Jing Zhang, Ren-Gen Xiong, Xiao-Zeng You, Huang-Xian Ju, and Zi-Ling Xue
pp 712 - 715; DOI:
10.1021/ic0343859
PDF
A New Route to Chelating Bis(aryloxide) Ligands and Their Applications to Tantalum and Titanium Organometallic Compounds
Jeffrey W. Anthis, Igor Filippov, and David E. Wigley
pp 716 - 724; DOI:
10.1021/ic030300s
PDF
Tuning the Electronic Structures of Platinum(II) Complexes with a Cyclometalating Aryldiamine Ligand
Hershel Jude, Jeanette A. Krause Bauer, and William B. Connick
pp 725 - 733; DOI:
10.1021/ic0346329
PDF
Synthesis and Structures of Complexes Demonstrating the Coordinative Versatility of the 2,4-Diimino-3-phosphinopentene Anion (-Phosphino--diketiminate)
Neil Burford, Mark D'eon, Paul J. Ragogna, Robert McDonald, and Michael J. Ferguson
pp 734 - 738; DOI:
10.1021/ic0351444
PDF
Hyperfine Splittings in Spin-Frustrated Trinuclear Cu3 Clusters
Moisey I. Belinsky
pp 739 - 746; DOI:
10.1021/ic035141r
PDF
Does -Fluorination Affect the Structural trans-Influence and Kinetic trans-Effect of an Alkyl Ligand? Molecular Structures of Pd(TMEDA)(CH3)(RF) and a Kinetic Study of the trans to cis Isomerization of Pt(TMEDA)(CH3)2I(RF) [RF = CF2CF3, CFHCF3, CH2CF3]
Russell P. Hughes, Monique A. Meyer, Mark D. Tawa, Antony J. Ward, Alex Williamson, Arnold L. Rheingold, and Lev N. Zakharov
pp 747 - 756; DOI:
10.1021/ic030251j
PDF
Structural, NMR, and EPR Studies of S = 1/2 and S = 3/2 Fe(III) Bis(4-Cyanopyridine) Complexes of Dodecasubstituted Porphyrins
Liliya A. Yatsunyk and F. Ann Walker
pp 757 - 777; DOI:
10.1021/ic035010q
PDF
Quantum Chemical Investigations and Bonding Analysis of Iron Complexes with Mixed Cyano and Carbonyl Ligands
Christoph Loschen and Gernot Frenking
pp 778 - 784; DOI:
10.1021/ic034807e
PDF
Characterization and Structure Determination of Ammonium Bismuth Oxalate Hydrate, Bi(NH4)(C2O4)2·xH2O
G. Vanhoyland, A. Le Bail, J. Mullens, and L. C. Van Poucke
pp 785 - 789; DOI:
10.1021/ic034509h
PDF
The Pd4(dppm)4(H)22+ Cluster: A Precatalyst for the Homogeneous Hydrogenation of Alkynes
David Evrard, Katherine Groison, Yves Mugnier, and Pierre D. Harvey
pp 790 - 796; DOI:
10.1021/ic0347992
PDF
Ga(2,2'-bipy)(HPO4)(H2PO4): First Layered Inorganic-Organic Hybrid Gallium Phosphate with a Neutral Framework
Zhi-En Lin, Jie Zhang, Yan-Qiong Sun, and Guo-Yu Yang
pp 797 - 801; DOI:
10.1021/ic034336w
PDF
Synthesis of Linear and Cyclic Carbophosphazenes via an Oxidative Chlorination Strategy
Eric Rivard, Alan J. Lough, Tristram Chivers, and Ian Manners
pp 802 - 811; DOI:
10.1021/ic034954c
PDF
Syntheses, Luminescence Behavior, and Assembly Reaction of Tetraalkynylplatinate(II) Complexes: Crystal Structures of [Pt(tBu3trpy)(CCC5H4N)Pt(tBu3trpy)](PF6)3 and [Pt2Ag4(CCCCC6H4CH3-4)8(THF)4]
Vivian Wing-Wah Yam, Chi-Kuen Hui, Shu-Yan Yu, and Nianyong Zhu
pp 812 - 821; DOI:
10.1021/ic034877l
PDF
Synergic Nitrogen Source Route to Inorganic Fullerene-like Boron Nitride with Vessel, Hollow Sphere, Onion, and Peanut Nanostructures
Fen Xu, Yi Xie, Xu Zhang, Shuyuan Zhang, Xianming Liu, and Xiaobo Tian
pp 822 - 829; DOI:
10.1021/ic0348751
PDF
Syntheses, Structures, Photoluminescence, and Theoretical Studies of d10 Metal Complexes of 2,2'-Dihydroxy-[1,1']binaphthalenyl-3,3'-dicarboxylate
Shao-Liang Zheng, Jin-Hua Yang, Xiao-Lan Yu, Xiao-Ming Chen, and Wing-Tak Wong
pp 830 - 838; DOI:
10.1021/ic034847i
PDF

Issue 3


Unprecedented Low Cu-N(azide)-Cu Angles in End-On Double Azido Bridged Copper(II) Complex
Subratanath Koner, Sandip Saha, Tallal Mallah, and Ken-Ichi Okamoto
pp 840 - 842; DOI:
10.1021/ic034347p
PDF
Formation of Trinuclear Palladium Orthometalated Complexes with Unprecedented Asymmetrical (3-S)(3-X) Bridges (X = OH, SR, O2CR) from 2-Hydroxo Dimeric Complexes and CS2
Pablo Espinet, Celia Hernández, José M. Martín-Alvarez, and Jesús A. Miguel
pp 843 - 845; DOI:
10.1021/ic0351085
PDF
Encapsulation of Cationic Ruthenium Complexes into a Chiral Self-Assembled Cage
Dorothea Fiedler, Daniela Pagliero, Julia L. Brumaghim, Robert G. Bergman, and Kenneth N. Raymond
pp 846 - 848; DOI:
10.1021/ic035105s
PDF
Slow Magnetic Relaxation in a Mixed-Valence Mn(II/III) Complex: [MnII2(bispicen)2(3-Cl)2MnIII(Cl4Cat)2MnIII(Cl4Cat)2(H2O)2]
Nizamuddin Shaikh, Anangamohan Panja, Sanchita Goswami, Pradyot Banerjee, Pavel Vojtíek, Yuan-Zhu Zhang, Gang Su, and Song Gao
pp 849 - 851; DOI:
10.1021/ic035072g
PDF
[Cu(L)Mn(N3)2]n: The First Complex Containing Both Macrocyclic Oxamido and Alternate (-1,1 and -1,3) Azido Bridges
Shi-bin Wang, Guang-ming Yang, Dai-zheng Liao, and Li-cun Li
pp 852 - 854; DOI:
10.1021/ic030085f
PDF
Synthesis and Characterization of N-Heterocyclic Carbene Complexes of Uranium(III)
Hidetaka Nakai, Xile Hu, Lev N. Zakharov, Arnold L. Rheingold, and Karsten Meyer
pp 855 - 857; DOI:
10.1021/ic035142j
PDF
Calculated Volume and Energy Profiles for Water Exchange on t2g6 Rhodium(III) and Iridium(III) Hexaaquaions: Conclusive Evidence for an Ia Mechanism
David De Vito, Jacques Weber, and André E. Merbach
pp 858 - 864; DOI:
10.1021/ic035096n
PDF
Mechanistic Changeover for the Water Substitution on fac-[(CO)3Re(H2O)3]+ Revealed by High-Pressure NMR
Pascal V. Grundler, Bernadette Salignac, Sonia Cayemittes, Roger Alberto, and André E. Merbach
pp 865 - 873; DOI:
10.1021/ic034969a
PDF
New Insights into the Structural and Dynamical Features of Lithium Hexaoxometalates Li7MO6 (M = Nb, Ta, Sb, Bi)
Claus Mühle, Robert E. Dinnebier, Leo van Wüllen, Georg Schwering, and Martin Jansen
pp 874 - 881; DOI:
10.1021/ic030208w
PDF
On the Noble-Gas-Induced Intersystem Crossing for the CUO Molecule: Experimental and Theoretical Investigations of CUO(Ng)n (Ng = Ar, Kr, Xe; n = 1, 2, 3, 4) Complexes in Solid Neon
Binyong Liang, Lester Andrews, Jun Li, and Bruce E. Bursten
pp 882 - 894; DOI:
10.1021/ic035206q
PDF
Characterization of the Thermally Induced Topochemical Solid-State Transformation of NH4[N(CN)2] into NCN=C(NH2)2 by Means of X-ray and Neutron Diffraction as Well as Raman and Solid-State NMR Spectroscopy
Bettina V. Lotsch, Jürgen Senker, and Wolfgang Schnick
pp 895 - 904; DOI:
10.1021/ic034984f
PDF
Biologically Active Platinum Complexes Containing 8-Thiotheophylline and 8-(Methylthio)theophylline
A. Romerosa, P. Bergamini, V. Bertolasi, A. Canella, M. Cattabriga, R. Gavioli, S. Mañas, N. Mantovani, and L. Pellacani
pp 905 - 913; DOI:
10.1021/ic034868c
PDF
Structural Study of the T#2-LixCoO2 (0.52 < x 0.72) Phase
D. Carlier, L. Croguennec, G. Ceder, M. Ménétrier, Y. Shao-Horn, and C. Delmas
pp 914 - 922; DOI:
10.1021/ic026285t
PDF
Enzymatic Mechanism of Fe-Only Hydrogenase: Density Functional Study on H-H Making/Breaking at the Diiron Cluster with Concerted Proton and Electron Transfers
Taijin Zhou, Yirong Mo, Aimin Liu, Zhaohui Zhou, and K. R. Tsai
pp 923 - 930; DOI:
10.1021/ic0342301
PDF
Coordination Polymers Assembled from Angular Dipyridyl Ligands and CuII, CdII, CoII Salts: Crystal Structures and Properties
Zheng Huang, Hai-Bin Song, Miao Du, Shen-Tan Chen, Xian-He Bu, and Joan Ribas
pp 931 - 944; DOI:
10.1021/ic034999d
PDF
Monomeric, Tetrameric, and Polymeric Copper Di-tert-butyl Phosphate Complexes Containing Pyridine Ancillary Ligands
Ramaswamy Murugavel, Malaichamy Sathiyendiran, Ramasamy Pothiraja, Mrinalini G. Walawalkar, Talal Mallah, and Eric Riviére
pp 945 - 953; DOI:
10.1021/ic0349508
PDF
Novel Double Layer Salts of Copper(I) Bromide with N-Substituted Ethylenediammonium Cations
Roger D. Willett and Brendan Twamley
pp 954 - 957; DOI:
10.1021/ic030260s
PDF
Hydrothermal Synthesis, Structure, and Magnetic Properties of the Mixed-Valent Np(IV)/Np(V) Selenite Np(NpO2)2(SeO3)3
Philip M. Almond, Richard E. Sykora, S. Skanthakumar, L. Soderholm, and Thomas E. Albrecht-Schmitt
pp 958 - 963; DOI:
10.1021/ic035241x
PDF
Synthesis, Structure, and Characterization of Two New Layered Mixed-Metal Phosphates, BaTeMO4(PO4) (M = Nb5+ or Ta5+)
Kang Min Ok, Joseph Orzechowski, and P. Shiv Halasyamani
pp 964 - 968; DOI:
10.1021/ic0350335
PDF
Problem of a Wide Variety of Products in the Cu(hfac)2-Nitroxide System
Sergei Fokin, Victor Ovcharenko, Galina Romanenko, and Vladimir Ikorskii
pp 969 - 977; DOI:
10.1021/ic034964d
PDF
Palladium(II) Complexes of Bowls, Pinwheels, Cages, and N,C,N-Pincers of Starburst Ligands 1,3,5-Tris(di-2-pyridylamino)benzene and 2,4,6-Tris(di-2-pyridylamino)-1,3,5-triazene
Corey Seward, Wen-li Jia, Rui-Yao Wang, and Suning Wang
pp 978 - 985; DOI:
10.1021/ic034934a
PDF
Insertion Reactions of [M(SR)3(PMe2Ph)2] with CS2 (M = Ru, Os; R = C6F4H-4, C6F5). X-ray Structures of [Ru(S2CSC6F4H-4)2(PMe2Ph)2], trans-Thiolates [M(SR)2(S2CSR)(PMe2Ph)2] (M = Ru; R = C6F5 and M = Os; R = C6F4H-4), and trans-Thiolate-Phosphine [Os(SC6F5)2(S2CSC6F5)(PMe2Ph)2]
Maribel Arroyo, Sylvain Bernès, Joaquín Cerón, Jordi Rius, and Hugo Torrens
pp 986 - 992; DOI:
10.1021/ic034125r
PDF
Insertion Reactions of trans-Mo(dmpe)2(H)(NO) with Imines
Fupei Liang, Helmut W. Schmalle, and Heinz Berke
pp 993 - 999; DOI:
10.1021/ic030139l
PDF
Evidence for the Blue 10 S62+ Dication in Solutions of S8(AsF6)2: A Computational Study Including Solvation Energies
Ingo Krossing and Jack Passmore
pp 1000 - 1011; DOI:
10.1021/ic0207303
PDF
Electrochemical and Spectroelectrochemical Characterization of Ru24+ and Ru23+ Complexes under a CO Atmosphere
Karl M. Kadish, Tuan D. Phan, Lingamallu Giribabu, Jianguo Shao, Li-Lun Wang, Antoine Thuriere, Eric Van Caemelbecke, and John L. Bear
pp 1012 - 1020; DOI:
10.1021/ic035026g
PDF
Self-Assembly of CuII and NiII [2 × 2] Grid Complexes and a Binuclear CuII Complex with a New Semiflexible Substituted Pyrazine Ligand: Multiple Anion Encapsulation and Magnetic Properties
Dilovan S. Cati, Joan Ribas, Jordi Ribas-Ariño, and Helen Stoeckli-Evans
pp 1021 - 1030; DOI:
10.1021/ic030174s
PDF
Oxidation in Nonclassical Organolanthanide Chemistry: Synthesis, Characterization, and X-ray Crystal Structures of Cerium(III) and -(IV) Amides
Peter B. Hitchcock, Alexander G. Hulkes, and Michael F. Lappert
pp 1031 - 1038; DOI:
10.1021/ic035100v
PDF
The Mechanism of NO Formation from the Decomposition of Dialkylamino Diazeniumdiolates: Density Functional Theory and CBS-QB3 Predictions
Andrew S. Dutton, Jon M. Fukuto, and K. N. Houk
pp 1039 - 1045; DOI:
10.1021/ic0349609
PDF
X-ray Absorption Spectroscopic Studies of Chromium(V/IV/III)- 2-Ethyl-2-hydroxybutanoato(2-/1-) Complexes
Aviva Levina, Rachel Codd, Garry J. Foran, Trevor W. Hambley, Thomas Maschmeyer, Anthony F. Masters, and Peter A. Lay
pp 1046 - 1055; DOI:
10.1021/ic030239r
PDF
Stepwise Synthesis of [Ru(trpy)(L)(X)]n+ (trpy = 2,2':6',2' '-Terpyridine; L = 2,2'-Dipyridylamine; X = Cl-, H2O, NO2-, NO+, O2-). Crystal Structure, Spectral, Electron-Transfer, and Photophysical Aspects
Nripen Chanda, Shaikh M. Mobin, Vedavati G. Puranik, Anindya Datta, Mark Niemeyer, and Goutam Kumar Lahiri
pp 1056 - 1064; DOI:
10.1021/ic034902n
PDF
Auto-ionization in Lutetium Iodide Complexes: Effect of the Ionic Radius on Lanthanide-Iodide Binding
Garth R. Giesbrecht, John C. Gordon, David L. Clark, and Brian L. Scott
pp 1065 - 1070; DOI:
10.1021/ic035090y
PDF
Structural, Spectroscopic, and Electrochemical Studies of the Complexes [Ni2(-CNR)(CNR)2(-dppm)2]n+ (n = 0, 1, 2): Unusual Examples of Nickel(0)-Nickel(I) and Nickel(0)-Nickel(II) Mixed Valency
Gregory M. Ferrence, Eugenio Simón-Manso, Brian K. Breedlove, Leah Meeuwenberg, and Clifford P. Kubiak
pp 1071 - 1081; DOI:
10.1021/ic035021j
PDF
Syntheses, Structure, and Selected Physical Properties of CsLnMnSe3 (Ln = Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Y) and AYbZnQ3 (A = Rb, Cs; Q = S, Se, Te)
Kwasi Mitchell, Fu Qiang Huang, El'ad N. Caspi, Adam D. McFarland, Christy L. Haynes, Rebecca C. Somers, James D. Jorgensen, Richard P. Van Duyne, and James A. Ibers
pp 1082 - 1089; DOI:
10.1021/ic030232+
PDF
Linear Hybrid Aminoborane/Phosphinoborane Chains: Synthesis, Proton-Hydride Interactions, and Thermolysis Behavior
Cory A. Jaska, Alan J. Lough, and Ian Manners
pp 1090 - 1099; DOI:
10.1021/ic034938f
PDF
Dinuclear Asymmetric Ruthenium Complexes with 5-Cyano-1,10-phenanthroline as a Bridging Ligand
María G. Mellace, Florencia Fagalde, Néstor E. Katz, Irma G. Crivelli, Alvaro Delgadillo, Ana María Leiva, Bárbara Loeb, María Teresa Garland, and Ricardo Baggio
pp 1100 - 1107; DOI:
10.1021/ic035198d
PDF
Divalent Molybdenum Complexes of the Dipyrrolide Ligand System. Isolation of a Mo2 Unit with a 45 Twist Angle
Guohua Gao, Ilia Korobkov, and Sandro Gambarotta
pp 1108 - 1115; DOI:
10.1021/ic0350739
PDF
Density Functional Theory Study of the d10 Series (H3P)3M(1-SO2) and (MenPh3-nP)3M(1-SO2) (M = Ni, Pd, Pt; n = 0-3): SO2 Pyramidality and M-S Bond Dissociation Energies
Daniel J. Brust and Thomas M. Gilbert
pp 1116 - 1121; DOI:
10.1021/ic030229q
PDF
Syntheses, Structures, and Physical Properties of Nickel Bis(dithiolene) Complexes Containing Tetrathiafulvalene (TTF) Units
Emiko Fujiwara, Akiko Kobayashi, Hideki Fujiwara, and Hayao Kobayashi
pp 1122 - 1129; DOI:
10.1021/ic034670s
PDF
Two-, Three-, and Four-Coordinate Ag(I) Coordination Polymers Formed by the Novel Phosphinite PPh2(3-OCH2C5H4N)
Kevin K. Klausmeyer, Rodney P. Feazell, and Joseph H. Reibenspies
pp 1130 - 1136; DOI:
10.1021/ic035168a
PDF
Bacterial Iron Transport: Coordination Properties of Azotobactin, the Highly Fluorescent Siderophore of Azotobacter vinelandii
Tania Palanché, Sylvie Blanc, Christophe Hennard, Mohamed A. Abdallah, and Anne-Marie Albrecht-Gary
pp 1137 - 1152; DOI:
10.1021/ic034862n
PDF
Cation and Pressure Effects on the Electrochemistry of 12-Tungstocobaltate and 12-Tungstophosphate Ions in Acidic Aqueous Solution
Mitsuru Matsumoto, Nancy I. Neuman, and Thomas W. Swaddle
pp 1153 - 1158; DOI:
10.1021/ic030160m
PDF
Synthesis and Characterization of Binucleating Bis(amidinate) Ligands and Their Dialuminum Complexes
Bronya Clare, Niladri Sarker, Richard Shoemaker, and John R. Hagadorn
pp 1159 - 1166; DOI:
10.1021/ic035035p
PDF
Synthesis, Structure, and Magnetochemical Analysis of Selected First-Row Transition-Metal Anilino- and Anisolesquarate Compounds
Patrice M. T. Piggot, Lincoln A. Hall, Andrew J. P. White, David J. Williams, and Laurence K. Thompson
pp 1167 - 1174; DOI:
10.1021/ic035193g
PDF
Effect of Equatorial Ligands of Dirhodium(II,II) Complexes on the Efficiency and Mechanism of Transcription Inhibition in Vitro
Helen T. Chifotides, Patty K.-L. Fu, Kim R. Dunbar, and Claudia Turro
pp 1175 - 1183; DOI:
10.1021/ic034438m
PDF
Molecular Structures of Alumina Nanoballs and Nanotubes: A Theoretical Study
Mikko Linnolahti and Tapani A. Pakkanen
pp 1184 - 1189; DOI:
10.1021/ic0349353
PDF
Effect of Amine Ligand Bulk on the Interaction of Methionine with Platinum(II) Diamine Complexes
Kevin M. Williams, Carrie Rowan, and Jeremiah Mitchell
pp 1190 - 1196; DOI:
10.1021/ic035212m
PDF
Luminescent Heterotrinuclear Complexes with Pt(diimine)(dithiolate) and Metal Diphosphine as Components
Yan-Dan Chen, Yong-Hai Qin, Li-Yi Zhang, Lin-Xi Shi, and Zhong-Ning Chen
pp 1197 - 1205; DOI:
10.1021/ic034848a
PDF
Fine-Tuning the Weak-Link Approach: Effect of Ligand Electron Density on the Formation of Rhodium(I) and Iridium(I) Metallomacrocycles
Martin S. Masar III, Maxim V. Ovchinnikov, Chad A. Mirkin, Lev N. Zakharov, and Arnold L. Rheingold:
pp 1206 - 1206; DOI:
10.1021/ic030336k
PDF

Issue 4


The Theoretical 77Se Chemical Shift as a Probe of Selenium State in Selenoproteins and Their Mimics
Craig A. Bayse
pp 1208 - 1210; DOI:
10.1021/ic035283l
PDF
Chiral Recognition of Amino Acids and Dipeptides by a Water-Soluble Zinc Porphyrin
Hiroyasu Imai, Hiroki Munakata, Yoshio Uemori, and Naoki Sakura
pp 1211 - 1213; DOI:
10.1021/ic0302837
PDF
NaRuO2 and NaxRuO2·yH2O: New Oxide and Oxyhydrate with Two Dimensional RuO2 Layers
Masahiro Shikano, Claude Delmas, and Jacques Darriet
pp 1214 - 1216; DOI:
10.1021/ic035324d
PDF
Synthesis and Structural Characterization of a Terminal Hydroxide Containing Alumoxane via Hydrolysis of Aluminum Hydrides
Ying Peng, Guangcai Bai, Hongjun Fan, Denis Vidovic, Herbert W. Roesky, and Jörg Magull
pp 1217 - 1219; DOI:
10.1021/ic0351803
PDF
Calix[4]pyrrole Schiff Base Macrocycles. Novel Binucleating Ligands for -Oxo Iron Complexes
Jacqueline M. Veauthier, Won-Seob Cho, Vincent M. Lynch, and Jonathan L. Sessler
pp 1220 - 1228; DOI:
10.1021/ic0352001
PDF
Determination of the Antimony Valence State in Eu10Mn6Sb13
Dennis E. Brown, Charles E. Johnson, Fernande Grandjean, Raphaël P. Hermann, Susan M. Kauzlarich, Aaron P. Holm, and Gary J. Long
pp 1229 - 1234; DOI:
10.1021/ic035172m
PDF
Accurate Redetermination of the X-ray Structure and Electronic Bonding in Adenosylcobalamin
Lizhi Ouyang, Paul Rulis, W. Y. Ching, Giorgio Nardin, and Lucio Randaccio
pp 1235 - 1241; DOI:
10.1021/ic0348446
PDF
Heteroleptic Copper Dipyrromethene Complexes: Synthesis, Structure, and Coordination Polymers
Sara R. Halper, Mitchell R. Malachowski, Heather M. Delaney, and Seth M. Cohen
pp 1242 - 1249; DOI:
10.1021/ic0352295
PDF
Syntheses and Solid-State and Solution Structures of [Ba{(C5Me5)2Ti2F7}2(hmpa)] and [Ba8Ti6F30I2(C5Me5)6(hmpa)6][I3]2
Andrej Pevec
pp 1250 - 1256; DOI:
10.1021/ic035256v
PDF
Syntheses and Structural, Physical, and Theoretical Studies of the Novel Isostructural Mo9 Cluster Compounds Ag2.6CsMo9Se11, Ag4.1ClMo9Se11, and h-Mo9Se11 with Tunnel Structures
Patrick Gougeon, Michel Potel, and Régis Gautier
pp 1257 - 1263; DOI:
10.1021/ic035319+
PDF
A Novel Cadmium Aminophosphonate: X-ray Powder Diffraction Structure, Solid-State IR and NMR Spectroscopic Determination of the Fine Structure of the Organic Moieties
Ekaterina V. Bakhmutova-Albert, Naima Bestaoui, Vladimir I. Bakhmutov, Abraham Clearfield, Anna Vega Rodriguez, and Ricardo Llavona
pp 1264 - 1272; DOI:
10.1021/ic030320u
PDF
Structure, Energetics, and Bonding of First Row Transition Metal Pentazolato Complexes: A DFT Study
Athanassios C. Tsipis and Aikaterini Th. Chaviara
pp 1273 - 1286; DOI:
10.1021/ic035112g
PDF
Preparation of Acentric Porous Coordination Frameworks from an Interpenetrated Diamondoid Array through Anion-Exchange Procedures: Crystal Structures and Properties
Miao Du, Ya-Mei Guo, Shen-Tan Chen, Xian-He Bu, Stuart R. Batten, Joan Ribas, and Susumu Kitagawa
pp 1287 - 1293; DOI:
10.1021/ic0351242
PDF
New Lanthanide Complexes for Sensitized Visible and Near-IR Light Emission: Synthesis, 1H NMR, and X-ray Structural Investigation and Photophysical Properties
Silvio Quici, Giovanni Marzanni, Alessandra Forni, Gianluca Accorsi, and Francesco Barigelletti
pp 1294 - 1301; DOI:
10.1021/ic035143b
PDF
An Expanded Set of Functional Groups in Bis(dithiolene)tungsten(IV,VI) Complexes Related to the Active Sites of Tungstoenzymes, Including WIV-SR and WVI-O(SR)
Jianfeng Jiang and R. H. Holm
pp 1302 - 1310; DOI:
10.1021/ic030301k
PDF
Metal Ion-Binding Properties of (1H-Benzimidazol-2-yl-methyl)phosphonate (Bimp2-) in Aqueous Solution.
María José Sánchez-Moreno, Alfonso Fernández-Botello, Raquel B. Gómez-Coca, Rolf Griesser, Justyn Ochocki, Andrzej Kotynski, Juan Niclós-Gutiérrez, Virtudes Moreno, and Helmut Sigel
pp 1311 - 1322; DOI:
10.1021/ic030175k
PDF
First Octameric Ellipsoid Lanthanide(III) Complexes: Crystal Structure and Nonlinear Optical Absorptive and Refractive Properties
Hongwei Hou, Yongli Wei, Yinglin Song, Yaoting Fan, and Yu Zhu
pp 1323 - 1327; DOI:
10.1021/ic035244+
PDF
Preparation and Reactivity of Mixed-Ligand Iron(II) Hydride Complexes with Phosphites and Polypyridyls
Gabriele Albertin, Stefano Antoniutti, and Marco Bortoluzzi
pp 1328 - 1335; DOI:
10.1021/ic0348190
PDF
Preparation and Reactivity of Mixed-Ligand Ruthenium(II) Hydride Complexes with Phosphites and Polypyridyls
Gabriele Albertin, Stefano Antoniutti, Alessia Bacchi, Claudia D'Este, and Giancarlo Pelizzi
pp 1336 - 1349; DOI:
10.1021/ic034820z
PDF
New Complexes of Zirconium(IV) and Hafnium(IV) with Heteroscorpionate Ligands and the Hydrolysis of Such Complexes To Give a Zirconium Cluster
A. Otero, J. Fernández-Baeza, A. Antiñolo, J. Tejeda, A. Lara-Sánchez, L. Sánchez-Barba, M. Fernández-López, and I. López-Solera
pp 1350 - 1358; DOI:
10.1021/ic035067c
PDF
Structural Characterization, Magnetic Properties, and Electrospray Mass Spectrometry of Two Jahn-Teller Isomers of the Single-Molecule Magnet [Mn12O12(CF3COO)16(H2O)4]
Hanhua Zhao, Curtis P. Berlinguette, John Bacsa, Andrey V. Prosvirin, Jitendra K. Bera, Shane E. Tichy, Eric J. Schelter, and Kim R. Dunbar
pp 1359 - 1369; DOI:
10.1021/ic030144p
PDF
CS2N3--Containing Pseudohalide Species: An Experimental and Theoretical Study
Margaret-Jane Crawford, Thomas M. Klapötke, Peter Mayer, and Martin Vogt
pp 1370 - 1378; DOI:
10.1021/ic030109i
PDF
[(NH3)5Ru(1,2,4,5-tetrazine)]2+: Synthesis and Experimental and Theoretical Study of Its Solvatochromism in the Visible Spectral Region
Ivo Cacelli, Silvio Campanile, Gianfranco Denti, Alessandro Ferretti, and Milena Sommovigo
pp 1379 - 1387; DOI:
10.1021/ic034786o
PDF
Axial Ligand Exchange in Chiral Macrocyclic Ytterbium(III) Complexes
Jerzy Lisowski, Silvia Ripoli, and Lorenzo Di Bari
pp 1388 - 1394; DOI:
10.1021/ic0353918
PDF
Kinetics and Mechanism of Bromate-Bromide Reaction Catalyzed by Acetate
Carlos Eduardo S. Côrtes and Roberto B. Faria
pp 1395 - 1402; DOI:
10.1021/ic0350786
PDF
Stabilization of New Forms of the Intermetallic Phases -RENiGe2 (RE = Dy, Ho, Er, Tm, Yb, Lu) in Liquid Indium
J. R. Salvador, J. R. Gour, D. Bilc, S. D. Mahanti, and M. G. Kanatzidis
pp 1403 - 1410; DOI:
10.1021/ic035303j
PDF
Calculation of the Ground and Excited States of a Mixed Valence Compound [Fe2(OH)3(NH3)6]2+: A Class II or Class III Compound?
Yannick Carissan, Jean-Louis Heully, Fabienne Alary, and Jean-Pierre Daudey
pp 1411 - 1420; DOI:
10.1021/ic034716h
PDF
Platinum Ion Uptake by Dendrimers: An NMR and AFM Study
Perry J. Pellechia, Jinxin Gao, Yunlong Gu, Harry J. Ploehn, and Catherine J. Murphy
pp 1421 - 1428; DOI:
10.1021/ic035127e
PDF
Highly Localized Charges Control Electrostriction: Reaction Volumes for the Reduction of Mononuclear and Bridged Ruthenium Complexes
Hari C. Bajaj, Peter A. Tregloan, and Rudi van Eldik
pp 1429 - 1435; DOI:
10.1021/ic034831s
PDF
F2Al(-2:2-O2)AlF2: An Unusual, Stable Aluminum Peroxo Compound
Anton Hammerl, Barry J. Welch, and Peter Schwerdtfeger
pp 1436 - 1440; DOI:
10.1021/ic035014v
PDF
Correlation between the Magnetic g Tensors and the Local Cysteine Geometries for a Series of Reduced [2Fe-2S*] Protein Clusters. A Quantum Chemical Density Functional Theory and Structural Analysis
Serge Gambarelli and Jean-Marie Mouesca
pp 1441 - 1451; DOI:
10.1021/ic0301167
PDF
New Coordination Compounds of Cd(AsF6)2 with HF and XeF2
Gaper Tavar, Primo Benki, and Boris emva
pp 1452 - 1457; DOI:
10.1021/ic035166q
PDF
1-Ethyl-3-methylimidazolium Based Ionic Liquids Containing Cyano Groups: Synthesis, Characterization, and Crystal Structure
Yukihiro Yoshida, Koji Muroi, Akihiro Otsuka, Gunzi Saito, Masahide Takahashi, and Toshinobu Yoko
pp 1458 - 1462; DOI:
10.1021/ic035045q
PDF
Oxidative Self-Decomposition of the Nickel(III) Complex of Glycylglycyl-L-histidylglycine
Brandon J. Green, Teweldemedhin M. Tesfai, Yi Xie, and Dale W. Margerum
pp 1463 - 1471; DOI:
10.1021/ic035034x
PDF
A Geometrically Constraining Bis(benzimidazole) Ligand and Its Nearly Tetrahedral Complexes with Fe(II) and Mn(II)
Robert T. Stibrany, Maxim V. Lobanov, Harvey J. Schugar, and Joseph A. Potenza
pp 1472 - 1480; DOI:
10.1021/ic030180o
PDF
Syntheses, Structures, and Redox Properties of Dimeric Triruthenium Clusters Bridged by Bis(diphenylphosphino)acetylene and -ethylene
Jing-Lin Chen, Li-Yi Zhang, Zhong-Ning Chen, Li-Bin Gao, Masaaki Abe, and Yoichi Sasaki
pp 1481 - 1490; DOI:
10.1021/ic0344968
PDF
Organometallic Oligomers Based on 1,8-Diisocyano-p-menthane (dmb): Syntheses and Characterization of the {[M(diphos)(dmb)]BF4}n and {[Pd2(diphos)2(dmb)](ClO4)2}n Materials (M = Cu, Ag; diphos = dppe, dppp)
Eric Fournier, Stéphanie Sicard, Andreas Decken, and Pierre D. Harvey
pp 1491 - 1501; DOI:
10.1021/ic034780z
PDF
Paramagnetic 1H NMR Spectrum of the Cobalt(II) Derivative of Spinach Plastocyanin
Christopher Dennison and Katsuko Sato
pp 1502 - 1510; DOI:
10.1021/ic034861v
PDF
Steric Control of Coordination Number: A Series of Mo(VI) Dioxo Diaryloxide Complexes Bearing 4-, 5-, and 6-Coordinate Environments
Tracy A. Hanna, Amit K. Ghosh, Catalina Ibarra, Miguel A. Mendez-Rojas, Arnold L. Rheingold, and William H. Watson
pp 1511 - 1516; DOI:
10.1021/ic035129z
PDF
The Solution Structure of Rhombic Lanthanide Complexes Analyzed with a Model-Free and Crystal-Field Independent Paramagnetic NMR Method: Application to Nonaxial Trimetallic Complexes [LnxLu3-x(TACI-3H)2(H2O)6]3+ (x = 1-3)
Nadjet Ouali, Jean-Pierre Rivera, David Chapon, Pascale Delangle, and Claude Piguet
pp 1517 - 1529; DOI:
10.1021/ic035093a
PDF
Metal vs Ligand Reduction in Complexes of Dipyrido[3,2-a:2',3'-c]phenazine and Related Ligands with [(C5Me5)ClM]+ (M = Rh or Ir): Evidence for Potential Rather Than Orbital Control in the Reductive Cleavage of the Metal-Chloride Bond
Sascha Berger, Jan Fiedler, Ralf Reinhardt, and Wolfgang Kaim
pp 1530 - 1538; DOI:
10.1021/ic0351388
PDF
Synthesis, Crystal Structure, and Spectroscopic Characterization of trans-Bis[(-1,3-bis(4-pyridyl)propane)(-(3-thiopheneacetate-O))(3-thiopheneacetate-O)]dicopper(II), {[Cu2(O2CCH2C4H3S)4-(BPP)2]}n: From a Dinuclear Paddle-Wheel Copper(II) Unit to a 2-D Coordination Polymer Involving Monatomic Carboxylate Bridges
Maria Vanda Marinho, Maria Irene Yoshida, Kassilio J. Guedes, Klaus Krambrock, Adailton J. Bortoluzzi, Manfredo Hörner, Flávia C. Machado, and Wagner M. Teles
pp 1539 - 1544; DOI:
10.1021/ic035251y
PDF
Easy Preparation of the Tris(2-fluoro-6-pyridylmethyl)amine Ligand and Instantaneous Reaction of the Corresponding Dichloroferrous Complex with Molecular Dioxygen: New Access to Dinuclear Species
Ahmed Machkour, Dominique Mandon, Mohamed Lachkar, and Richard Welter
pp 1545 - 1550; DOI:
10.1021/ic034485e
PDF
Contrasting Intrastrand Photoinduced Processes in Macromolecules Containing Pendant -Re(CO)3(1,10-phenanthroline)+: Electron versus Energy Transfer
M. R. Feliz and G. Ferraudi
pp 1551 - 1557; DOI:
10.1021/ic030012w
PDF
Tetranuclear [Rh4(-PyS2)2(diolefin)4] Complexes as Building Blocks for New Inorganic Architectures: Synthesis of Coordination Polymers and Heteropolynuclear Complexes with Electrophilic d8 and d10 Metal Fragments
Miguel A. Casado, Jesús J. Pérez-Torrente, Miguel A. Ciriano, Fernando J. Lahoz, and Luis A. Oro
pp 1558 - 1567; DOI:
10.1021/ic034893i
PDF
Synthesis and Characterization of Neutral cis-Hexacoordinate Bis(-diketonate) Silicon(IV) Complexes
Chongying Xu, Thomas H. Baum, and Arnold L. Rheingold
pp 1568 - 1573; DOI:
10.1021/ic0302377
PDF
New Poly-Iron(II) Complexes of N4O Dinucleating Schiff Bases and Pseudohalides: Syntheses, Structures, and Magnetic and Mössbauer Properties
Athanassios K. Boudalis, Juan-Modesto Clemente-Juan, Françoise Dahan, and Jean-Pierre Tuchagues
pp 1574 - 1586; DOI:
10.1021/ic0351904
PDF
Cumene Oxidation by cis-[RuIV(bpy)2(py)(O)]2+, Revisited
Jasmine R. Bryant, Takashi Matsuo, and James M. Mayer
pp 1587 - 1592; DOI:
10.1021/ic035298j
PDF

Issue 5


Hydrothermal Synthesis of Prismatic NaHoF4 Microtubes and NaSmF4 Nanotubes
Lifang Liang, Huifang Xu, Qiang Su, Hiromi Konishi, Yingbin Jiang, Mingmei Wu, Yifeng Wang, and Deying Xia
pp 1594 - 1596; DOI:
10.1021/ic034833c
PDF
Rapid Phosphine Exchange on 1.5-nm Gold Nanoparticles
Janet Petroski, Mei H. Chou, and Carol Creutz
pp 1597 - 1599; DOI:
10.1021/ic035304b
PDF
Synthesis and Characterization of Two Novel Lanthanide Coordination Polymers with an Open Framework Based on an Unprecedented [Ln7(3-OH)8]13+ Cluster
Xiang-Jun Zheng, Lin-Pei Jin, and Song Gao
pp 1600 - 1602; DOI:
10.1021/ic0352699
PDF
Assembling Process of Charged Nonanuclear Cationic Lanthanide(III) Clusters Assisted by Dichromium Decacarbonyl Hydride
Maurizio Addamo, Gabriella Bombieri, Elisabetta Foresti, M. Domenica Grillone, and Maurizio Volpe
pp 1603 - 1605; DOI:
10.1021/ic034700r
PDF
Raising the Spin-Reversal Barrier in Cyano-Bridged Single-Molecule Magnets: Linear MnIII2MIII(CN)6 (M = Cr, Fe) Species Incorporating [(5-Brsalen)Mn]+ Units
Hye Jin Choi, Jennifer J. Sokol, and Jeffrey R. Long
pp 1606 - 1608; DOI:
10.1021/ic035327q
PDF
Diastereoselective Formation of Metallamacrocyclic (Arene)RuII and Cp*RhIII Complexes
Marie-Line Lehaire, Rosario Scopelliti, Lorenz Herdeis, Kurt Polborn, Peter Mayer, and Kay Severin
pp 1609 - 1617; DOI:
10.1021/ic035328i
PDF
Structures and Ligand Exchange of N-Confused Porphyrin Dimer Complexes with Group 12 Metals
Hiroyuki Furuta, Tatsuki Morimoto, and Atsuhiro Osuka
pp 1618 - 1624; DOI:
10.1021/ic035294e
PDF
Nature of the Oxomolybdenum-Thiolate -Bond: Implications for Mo-S Bonding in Sulfite Oxidase and Xanthine Oxidase
Rebecca L. McNaughton, Matthew E. Helton, Michele Mader Cosper, John H. Enemark, and Martin L. Kirk
pp 1625 - 1637; DOI:
10.1021/ic034206n
PDF
Spectroscopic and Electrochemical Characterization of an Aqua Ligand Exchange and Oxidatively Induced Deprotonation in Diiron Complexes
Sylvie Chardon-Noblat, Olivier Horner, Barbara Chabut, Frédéric Avenier, Noëlle Debaecker, Peter Jones, Jacques Pécaut, Lionel Dubois, Claudine Jeandey, Jean-Louis Oddou, Alain Deronzier, and Jean-Marc Latour
pp 1638 - 1648; DOI:
10.1021/ic030192+
PDF
Nickel Complexes with New Bidentate P,N Phosphinitooxazoline and -Pyridine Ligands: Application for the Catalytic Oligomerization of Ethylene
Fredy Speiser, Pierre Braunstein, Lucien Saussine, and Richard Welter
pp 1649 - 1658; DOI:
10.1021/ic035132i
PDF
Preparation and Characterization of the Argentates: [Ag{P(CF3)2}2]-, [Ag{(-P(CF3)2)M(CO)5}2]- (M = Cr, W), and [Ag{(-P(C6F5)2)W(CO)5}2]-: X-ray Crystal Structure of [K(18-crown-6)][Ag{(-P(CF3)2)Cr(CO)5}2]
Berthold Hoge, Christoph Thösen, Tobias Herrmann, and Ashwani Vij
pp 1659 - 1666; DOI:
10.1021/ic034936v
PDF
Probing the Electronic Structures of Ternary Perovskite and Pyrochlore Oxides Containing Sn4+ or Sb5+
Hiroshi Mizoguchi, Hank W. Eng, and Patrick M. Woodward
pp 1667 - 1680; DOI:
10.1021/ic034551c
PDF
Functionalized Macrocycles from Functionalized Tetra-Amines: Pendent-Arm Macrocycles Derived from Dichloropivalic Acid
Paul V. Bernhardt, Jack M. Harrowfield, Yang Kim, George A. Koutsantonis, Young Hoon Lee, and Pierre Thuéry
pp 1681 - 1688; DOI:
10.1021/ic034913g
PDF
Stereochemistry in Functionalized Macrocycle Complexes: Control of Hydroxyl Substituent Orientation
Jack M. Harrowfield, Yang Kim, George A. Koutsantonis, Young Hoon Lee, and Pierre Thuéry
pp 1689 - 1696; DOI:
10.1021/ic034912o
PDF
Organometallic Complexes as Hole-Transporting Materials in Organic Light-Emitting Diodes
Xiaofan Ren, Bert D. Alleyne, Peter I. Djurovich, Chihaya Adachi, Irina Tsyba, Robert Bau, and Mark E. Thompson
pp 1697 - 1707; DOI:
10.1021/ic035183f
PDF
Hydrolytic Reaction by Zinc Finger Mutant Peptides: Successful Redesign of Structural Zinc Sites into Catalytic Zinc Sites
Akiko Nomura and Yukio Sugiura
pp 1708 - 1713; DOI:
10.1021/ic034931y
PDF
The Unexpected Preference for the fac-Isomer with the Tris(5-ester-substituted-2,2'-bipyridine) Complexes of Ruthenium(II)
E. A. P. Armstrong, R. T. Brown, M. S. Sekwale, N. C. Fletcher, X.-Q. Gong, and P. Hu
pp 1714 - 1722; DOI:
10.1021/ic0350281
PDF
Excited-State Characters and Dynamics of [W(CO)5(4-cyanopyridine)] and [W(CO)5(piperidine)] Studied by Picosecond Time-Resolved IR and Resonance Raman Spectroscopy and DFT Calculations: Roles of W L and W CO MLCT and LF Excited States Revised
Stanislav Záli, Michael Busby, Tomá Kotrba, Pavel Matousek, Mike Towrie, and Antonín Vlek, Jr.
pp 1723 - 1734; DOI:
10.1021/ic035089z
PDF
Synthesis and Characterization of Bis(di-2-pyridylmethanamine)ruthenium(II)
Jin Chang, Susan Plummer, Elena S. F. Berman, Durwin Striplin, and David Blauch
pp 1735 - 1742; DOI:
10.1021/ic030242a
PDF
Structure-Activity Studies on the Cleavage of an RNA Analogue by a Potent Dinuclear Metal Ion Catalyst: Effect of Changing the Metal Ion
Olga Iranzo, John P. Richard, and Janet R. Morrow
pp 1743 - 1750; DOI:
10.1021/ic035120x
PDF
Synthesis and Characterization of Cu2(I,I), Cu2(I,II), and Cu2(II,II) Compounds Supported by Two Phthalazine-Based Ligands: Influence of a Hydrophobic Pocket
Jane Kuzelka, Sumitra Mukhopadhyay, Bernhard Spingler, and Stephen J. Lippard
pp 1751 - 1761; DOI:
10.1021/ic035009r
PDF
Experimental and Computational Studies of the Metal-Metal Stretching Vibration in X3MMX3 Compounds (X = Alkoxide, Alkyl, Amide)
Thomas M. Gilbert, John C. Littrell, Chad E. Talley, Michael A. Vance, Richard F. Dallinger, and Robin D. Rogers
pp 1762 - 1769; DOI:
10.1021/ic030246f
PDF
Outer Sphere Perturbation of Delocalized Mixed-Valence Complexes
Mousa Al-Noaimi, Glenn P. A. Yap, and Robert J. Crutchley
pp 1770 - 1778; DOI:
10.1021/ic0349454
PDF
Electron Transfer. 157. Reactions of Hypervalent Manganese Species with s2 Metal-Ion Reductants1
Olga A. Babich and Edwin S. Gould
pp 1779 - 1783; DOI:
10.1021/ic030307+
PDF
Sensitization and Stabilization of TiO2 Photoanodes with Electropolymerized Overlayer Films of Ruthenium and Zinc Polypyridyl Complexes: A Stable Aqueous Photoelectrochemical Cell
John A. Moss, John C. Yang, Jeremy M. Stipkala, Xingu Wen, Carlo A. Bignozzi, Gerald J. Meyer, and Thomas J. Meyer
pp 1784 - 1792; DOI:
10.1021/ic030081a
PDF
Synthesis and Reactivity of New Chelate-N-Heterocyclic Biscarbene Complexes of Ruthenium
Macarena Poyatos, Elena Mas-Marzá, Mercedes Sanaú, and Eduardo Peris
pp 1793 - 1798; DOI:
10.1021/ic035307o
PDF
The pH-Induced Emission Switching and Interesting DNA-Binding Properties of a Novel Dinuclear Ruthenium(II) Complex
Furong Liu, Kezhi Wang, Guangyao Bai, Yongan Zhang, and Lihua Gao
pp 1799 - 1806; DOI:
10.1021/ic035109x
PDF

Issue 6


Amino Acid Templating of Inorganic Networks: Synthesis and Structure of L-Asparagine Zinc Phosphite, C4N2O3H8·ZnHPO3
Laura E. Gordon and William T. A. Harrison
pp 1808 - 1809; DOI:
10.1021/ic0346127
PDF
Polyhapto-Aromatic Interactions in Lead(II) Coordination
Jack M. Harrowfield, Saeed Maghaminia, and Ali A. Soudi
pp 1810 - 1812; DOI:
10.1021/ic034835x
PDF
An Unusual Mixed-Valence Cu(I)-Cu(II) 3-D Framework
Hong Zhao, Zhi-Rong Qu, Qiong Ye, Xi-Sen Wang, Jing Zhang, Ren-Gen Xiong, and Xiao-Zeng You
pp 1813 - 1815; DOI:
10.1021/ic034943j
PDF
An Unprecedented Uranyl Phosphate Framework in the Structure of [(UO2)3(PO4)O(OH)(H2O)2](H2O)
Peter C. Burns, Cara M. Alexopoulos, Peter J. Hotchkiss, and Andrew J. Locock
pp 1816 - 1818; DOI:
10.1021/ic0348547
PDF
Lanthanide/ATP Interaction in Water Mediated by Luminescent Hemispherical-Shaped Complexes
Samir Mameri, Loïc J. Charbonnière, and Raymond F. Ziessel
pp 1819 - 1821; DOI:
10.1021/ic030295s
PDF
Structure of Two Azide Salts of a Copper(II) Macrocycle and Magnetic Properties of Cu(14ane)Cu(N3)4
Brooke Woodard, Roger D. Willett, Salim Haddad, Brendan Twamley, Carlos J. Gomez-Garcia, and Eugenio Coronado
pp 1822 - 1824; DOI:
10.1021/ic030272d
PDF
Axial Ligation of Fe(II)-Bleomycin Probed by XANES Spectroscopy
Grigory Smolentsev, Alexander V. Soldatov, Erik C. Wasinger, and Edward I. Solomon
pp 1825 - 1827; DOI:
10.1021/ic0350537
PDF
Spacer Flexibility in Bis(pyridyl) Ligands: Chelating Organosilicon Pyridylethynyl Ligands
Parbati Sengupta, Hongming Zhang, and David Y. Son
pp 1828 - 1830; DOI:
10.1021/ic0352405
PDF
(Salen)CrIIIX Catalysts for the Copolymerization of Carbon Dioxide and Epoxides: Role of the Initiator and Cocatalyst
Donald J. Darensbourg, Ryan M. Mackiewicz, Jody L. Rodgers, and Andrea L. Phelps
pp 1831 - 1833; DOI:
10.1021/ic0352856
PDF
Tricarbonylrhenium(I) Complexes with Thiosemicarbazone Derivatives of 2-Acetylpyridine and 2-Pyridine Formamide Showing Two Unusual Coordination Modes of Tridentate Thiosemicarbazone Ligands
Isabel Garcia Santos, Ulrich Abram, Roger Alberto, Ezequiel Vazquez Lopez, and Agustin Sanchez
pp 1834 - 1836; DOI:
10.1021/ic035367u
PDF
Alkynylxenon(II) Fluorides
Harald Schmidt, Harald Scherer, Wieland Tyrra, Josef Hahn, and Dieter Naumann
pp 1837 - 1839; DOI:
10.1021/ic035394k
PDF
The First Enantiomerically Pure Helical Noncovalent Tripod for Assembling Nine-Coordinate Lanthanide(III) Podates
Martine Cantuel, Gérald Bernardinelli, Gilles Muller, James P. Riehl, and Claude Piguet
pp 1840 - 1849; DOI:
10.1021/ic035292u
PDF
Syntheses, Structures, and Photoluminescence of a Novel Class of d10 Metal Complexes Constructed from Pyridine-3,4-dicarboxylic Acid with Different Coordination Architectures
Xinlong Wang, Chao Qin, Enbo Wang, Yangguang Li, Na Hao, Changwen Hu, and, and Lin Xu
pp 1850 - 1856; DOI:
10.1021/ic035151s
PDF
2D-3D Transformation of Layered Perovskites through Metathesis: Synthesis of New Quadruple Perovskites A2La2CuTi3O12 (A = Sr, Ca)
T. Sivakumar, K. Ramesha, S. E. Lofland, K. V. Ramanujachary, G. N. Subbanna, and J. Gopalakrishnan
pp 1857 - 1864; DOI:
10.1021/ic035358l
PDF
Intermolecular Magnetic Couplings in the Dinuclear Copper(II) Complex -Chloro--[2,5-bis(2-pyridyl)-1,3,4-thiadiazole] Aqua Chlorocopper(II) Dichlorocopper(II): Synthesis, Crystal Structure, and EPR and Magnetic Characterization
Fouad Bentiss, Michel Lagrenée, Olivier Mentré, Pierre Conflant, Hervé Vezin, Jean Pierre Wignacourt, and Elizabeth M. Holt
pp 1865 - 1873; DOI:
10.1021/ic030128s
PDF
Octanuclear and Nonanuclear Supramolecular Copper(II) Complexes with Linear "Tritopic" Ligands: Structural and Magnetic Studies
Victoria A. Milway, Virginie Niel, Tareque S. M. Abedin, Zhiqiang Xu, Laurence K. Thompson, Hilde Grove, David O. Miller, and Stewart R. Parsons
pp 1874 - 1884; DOI:
10.1021/ic030113u
PDF
Diastereoselective Assembling of 21-C-Alkylated Nickel(II) Complexes of Inverted Porphyrin on a Platinum(II) Template
Piotr J. Chmielewski and Izabela Schmidt
pp 1885 - 1894; DOI:
10.1021/ic035162l
PDF
Irreversible but Noncovalent Ru(II)-Pyridine Bond: Its Use for the Formation of [2]-Catenanes
B. X. Colasson and J.-P. Sauvage
pp 1895 - 1901; DOI:
10.1021/ic0302478
PDF
Cyanide-Melt Synthesis of Reduced Molybdenum Selenide Clusters
Carmela Magliocchi, Xiaobing Xie, and Timothy Hughbanks
pp 1902 - 1911; DOI:
10.1021/ic035050u
PDF
Synthesis and Structure of Five Sc3CuyZn18-y-Type Compositions (0 y ~2.2), 1/1 Crystalline Approximants of a New Icosahedral Quasicrystal. Direct Example of Tuning on the Basis of Size Effects and Hume-Rothery Concepts
Qisheng Lin and John D. Corbett
pp 1912 - 1919; DOI:
10.1021/ic030265p
PDF
X-ray Diffraction and NMR Studies on a Series of Binap-Based Ru(II) Hydroxyphosphine -Arene Complexes
Tilmann J. Geldbach, Frank Breher, Volker Gramlich, P. G. Anil Kumar, and Paul S. Pregosin
pp 1920 - 1928; DOI:
10.1021/ic0352147
PDF
Crystal Engineering through Face Interactions between Tetrahedral and Octahedral Building Blocks: Crystal Structure of [-Al13O4(OH)24(H2O)12]2[V2W4O19]3(OH)2·27H2O
Jung-Ho Son and Young-Uk Kwon
pp 1929 - 1932; DOI:
10.1021/ic035278h
PDF
Reactions of arachno-6,8-C2B7H12- with Electron Deficient Olefins: Syntheses of Cyano-Substituted Carboranes
Daniel E. Kadlecek, Daewon Hong, Patrick J. Carroll, and Larry G. Sneddon
pp 1933 - 1942; DOI:
10.1021/ic035357t
PDF
Experimental and Theoretical Investigation on the Relative Stability of the PdS2- and Pyrite-Type Structures of PdSe2
C. Soulard, X. Rocquefelte, P.-E. Petit, M. Evain, S. Jobic, J.-P. Itié, P. Munsch, H.-J. Koo, and M.-H. Whangbo
pp 1943 - 1949; DOI:
10.1021/ic0352396
PDF
Iridium Cyclometalated Complexes with Axial Symmetry. Synthesis and Photophysical Properties of a trans-Biscyclometalated Complex Containing the Terdentate Ligand 2,6-Diphenylpyridine
Matthew Polson, Sandro Fracasso, Valerio Bertolasi, Marcella Ravaglia, and Franco Scandola
pp 1950 - 1956; DOI:
10.1021/ic0351848
PDF
The Reaction of Dimethyltin(IV) Dichloride with Thiamine Diphosphate (H2TDP): Synthesis and Structure of [SnMe2(HTDP)(H2O)]Cl·H2O, and Possibility of a Hitherto Unsuspected Role of the Metal Cofactor in the Mechanism of Vitamin-B1-Dependent Enzymes
José S. Casas, Eduardo E. Castellano, María D. Couce, Javier Ellena, Agustín Sánchez, José L. Sánchez, José Sordo, and Carmen Taboada
pp 1957 - 1963; DOI:
10.1021/ic0351141
PDF
A Novel Organic-Inorganic Hybrid Based on an 8-Electron-Reduced Keggin Polymolybdate Capped by Tetrahedral, Trigonal Bipyramidal, and Octahedral Zinc: Synthesis and Crystal Structure of (CH3NH3)(H2bipy)[Zn4(bipy)3(H2O)2MoV8MoVI4O36(PO4)]·4H2O
Chong Lei, Jiang-Gao Mao, Yan-Qiong Sun, and Jun-Ling Song
pp 1964 - 1968; DOI:
10.1021/ic035290+
PDF
Inter-String Arrays of Bimetallic Assemblies with Alternative Cu2+-Cl-Cu2+ and Cu-NC-M (M = Co3+, Fe+3, Cr+3) Bridges: Syntheses, Crystal Structure, and Magnetic Properties
Manas K. Saha, Francesc Lloret, and Ivan Bernal
pp 1969 - 1975; DOI:
10.1021/ic034897n
PDF
Ion Chemistry of OV(OCH3)3 in the Gas Phase: Molecular Cations and Anions and Their Primary Fragmentations
Detlef Schröder, Jessica Loos, Marianne Engeser, Helmut Schwarz, Hans-Christian Jankowiak, Robert Berger, Roland Thissen, Odile Dutuit, Jens Döbler, and Joachim Sauer
pp 1976 - 1985; DOI:
10.1021/ic030264x
PDF
Ferromagnetic Ordering in Bis(benzene)chromium(+) Bis(4,5-dimethoxybenzene-1,2-dithiolato)nickel(-)
Niels Chr. Schidt, Roberta Sessoli, and Frederik C. Krebs
pp 1986 - 1991; DOI:
10.1021/ic034610m
PDF
The Role of Sequestering Agents in the Formation and Structure of Germanium Anion Cluster Polymers
Craig Downie, Jiang-Gao Mao, Hiten Parmar, and Arnold M. Guloy
pp 1992 - 1997; DOI:
10.1021/ic034704w
PDF
DFT-Based Pseudo-Jahn-Teller Coupling Studies on the Steric and Energetic Lone Pair Effect of Four- and Five-Coordinate Halide Molecules and Complexes with Central Ions from the Fifth, Sixth, and Seventh Main Groups
M. Atanasov and D. Reinen
pp 1998 - 2012; DOI:
10.1021/ic030214s
PDF
Characterization and Purification of Supramolecular Metal Complexes Using Gel-Permeation Chromatography
Christopher R. Graves, Melissa L. Merlau, Gregory A. Morris, Shih-Sheng Sun, SonBinh T. Nguyen, and Joseph T. Hupp
pp 2013 - 2017; DOI:
10.1021/ic034883h
PDF
An Improved Method for the Synthesis of [closo-B12(OH)12]-2
Michael J. Bayer and M. Frederick Hawthorne
pp 2018 - 2020; DOI:
10.1021/ic030289w
PDF
Spectroscopic Investigation of Interactions between Dipeptides and Vanadate(V) in Solution
Olivier Durupthy, Aurélie Coupé, Lawrence Tache, Marie-Noëlle Rager, Jocelyne Maquet, Thibaud Coradin, Nathalie Steunou, and Jacques Livage
pp 2021 - 2030; DOI:
10.1021/ic0301019
PDF
The Weakly Coordinating Trichloromethanesulfonate Anion: NQR Comparison of Its Coordinating Abilities via Oxygen with Those of the Chloroacetate Ions
Gary Wulfsberg, Michael Cochran, Jamie Wilcox, Tibor Koritsanszky, Debra Jones Jackson, and James C. Howard
pp 2031 - 2042; DOI:
10.1021/ic020727j
PDF
Photoswitchable Luminescence of Rhenium(I) Tricarbonyl Diimines
Oliver S. Wenger, Lawrence M. Henling, Michael W. Day, Jay R. Winkler, and Harry B. Gray
pp 2043 - 2048; DOI:
10.1021/ic030324z
PDF
Synthesis, Crystal Structure, and Physical Properties of (BEDT-TTF)[Ni(tdas)2] (BEDT-TTF = Bis(ethylenedithio)tetrathiafulvalene; tdas = 1,2,5-Thiadiazole-3,4-dithiolate): First Monomeric [Ni(tdas)2]- Monoanion
S. Curreli, P. Deplano, M. L. Mercuri, L. Pilia, A. Serpe, John A. Schlueter, Michael A. Whited, Urs Geiser, E. Coronado, C. J. Gómez-García, and E. Canadell
pp 2049 - 2056; DOI:
10.1021/ic035079y
PDF
Insertion of SO2 into a Sulfide-Bridged M-Ge Bond: Synthesis, Characterization, and Reactivity of the O-Germyl-S-sulfoxylate
Zuzanna T. Cygan, Jeff W. Kampf, and Mark M. Banaszak Holl
pp 2057 - 2063; DOI:
10.1021/ic0353155
PDF
From Calcium Interaction to Calcium Electrochemical Detection by [(C5H5)Fe(C5H4COCH=CHC6H4NEt2)] and Its Two Novel Structurally Characterized Derivatives
Jérôme Maynadié, Béatrice Delavaux-Nicot, Dominique Lavabre, Bruno Donnadieu, Jean-Claude Daran, and Alix Sournia-Saquet
pp 2064 - 2077; DOI:
10.1021/ic0345828
PDF
Substituent Effects on the Site of Electron Transfer during the First Reduction for Gold(III) Porphyrins
Zhongping Ou, Karl M. Kadish, Wenbo E, Jianguo Shao, Paul J. Sintic, Kei Ohkubo, Shunichi Fukuzumi, and Maxwell J. Crossley
pp 2078 - 2086; DOI:
10.1021/ic035070w
PDF
Head-to-Head (HH) and Head-to-Tail (HT) Conformers of cis-Bis Guanine Ligands Bound to the [Re(CO)3]+ Core
Fabio Zobi, Olivier Blacque, Helmut W. Schmalle, Bernhard Spingler, and Roger Alberto
pp 2087 - 2096; DOI:
10.1021/ic035012a
PDF
Experimental and Theoretical Investigations of Structural Trends for Selenium(IV) Imides and Oxides: X-ray Structure of Se3(NAd)2
Tiina Maaninen, Heikki M. Tuononen, Gabriele Schatte, Reijo Suontamo, Jussi Valkonen, Risto Laitinen, and Tristram Chivers
pp 2097 - 2104; DOI:
10.1021/ic034944b
PDF
Iron(II) Carboxylate Complexes Based on a Tetraimidazole Ligand as Models of the Photosynthetic Non-Heme Ferrous Sites: Synthesis, Crystal Structure, and Mössbauer and Magnetic Studies
Gilles Lemercier, Etienne Mulliez, Chantal Brouca-Cabarrecq, Françoise Dahan, and Jean-Pierre Tuchagues
pp 2105 - 2113; DOI:
10.1021/ic034907k
PDF
Coordination Complexes of Molybdenum with 3,6-Di-tert-butylcatechol. Addition Products of DMSO, Pyridine N-oxide, and Triphenylarsine Oxide to the Putative [MoVIO(3,6-DBCat)2] Monomer and Self-Assembly of the Chiral [{MoVIO(3,6-DBCat)2}4] Square
Cai-Ming Liu, Ebbe Nordlander, Derek Schmeh, Richard Shoemaker, and Cortlandt G. Pierpont
pp 2114 - 2124; DOI:
10.1021/ic0354264
PDF
Electron Transfer and CO Addition to Polynitrido Cobalt Carbonyl Clusters: Parallel Pathways for Conversion of the [Co10N2(CO)19]4- Anion to the Novel [Co11N2(CO)21]3- Anion
Alessandro Fumagalli, Paola Ulivieri, Michela Costa, Ornella Crispu, Roberto Della Pergola, Fabrizia Fabrizi de Biani, Franco Laschi, Piero Zanello, Piero Macchi, and Angelo Sironi
pp 2125 - 2131; DOI:
10.1021/ic035133a
PDF
Oxamidate-Bridged Dinuclear Five-Coordinate Nickel(II) Complexes: A Magneto-Structural Study
M. Dolores Santana, Gabriel García, Miguel Julve, Francesc Lloret, José Pérez, Malva Liu, Francisco Sanz, Joan Cano, and Gregorio López
pp 2132 - 2140; DOI:
10.1021/ic030050f
PDF
Mechanistic Studies on the Formation and Reactivity of Dioxygen Adducts of Diiron Complexes Supported by Sterically Hindered Carboxylates
Sergey V. Kryatov, Ferman A. Chavez, Anne M. Reynolds, Elena V. Rybak-Akimova, Lawrence Que, Jr., and William B. Tolman
pp 2141 - 2150; DOI:
10.1021/ic049976t
PDF
One-Dimensional Cobalt Diphosphonates Exhibiting Weak Ferromagnetism and Field-Induced Magnetic Transitions
Li-Min Zheng, Song Gao, Ping Yin, and Xin-Quan Xin
pp 2151 - 2156; DOI:
10.1021/ic034614r
PDF
(Bis(1,2,4-triazol-1-yl)methane)silver(I) Phosphino Complexes: Structures and Spectroscopic Properties of Mixed-Ligand Coordination Polymers
Effendy, Fabio Marchetti, Claudio Pettinari, Riccardo Pettinari, Massimo Ricciutelli, Brian W. Skelton, and Allan H. White
pp 2157 - 2165; DOI:
10.1021/ic0353413
PDF
Aluminum Complexes Incorporating Bidentate Amido Phosphine Ligands
Lan-Chang Liang, Mei-Hui Huang, and Chen-Hsiung Hung
pp 2166 - 2174; DOI:
10.1021/ic035373q
PDF
Toward a Catalytic Cycle for the Mn-Salen Mediated Alkene Epoxidation: A Computational Approach
Luigi Cavallo and Heiko Jacobsen
pp 2175 - 2182; DOI:
10.1021/ic0353615
PDF
Metal-Induced Coordination Inversion and Carbon-Nitrogen Bond Rearrangement. Structurally Characterized Phenyl Isocyanate Inserted into Aluminum Methyl Compounds and O- and N-Bound Aluminum Compounds
Chia-Fu Tsai, Hsing-Jen Chen, Jr-Chiuan Chang, Cheng-Hsiang Hung, Chun-Chia Lai, Ching-Han Hu, and Jui-Hsien Huang
pp 2183 - 2188; DOI:
10.1021/ic035261z
PDF
Investigation of Hydrothermal Routes to Mixed-Metal Cerium Titanium Oxides and Metal Oxidation State Assignment Using XANES
Christopher S. Wright, Richard I. Walton, David Thompsett, and Janet Fisher
pp 2189 - 2196; DOI:
10.1021/ic035211u
PDF
Synthesis and Characterization of Ionic Liquids Incorporating the Nitrile Functionality
Dongbin Zhao, Zhaofu Fei, Rosario Scopelliti, and Paul J. Dyson
pp 2197 - 2205; DOI:
10.1021/ic034801p
PDF
First Characterization of the Ammine-Ammonium Complex [{NH4(NH3)4}2(-NH3)2]2+ in the Crystal Structure of [NH4(NH3)4][B(C6H5)4]·NH3 and the [NH4(NH3)4]+ Complex in [NH4(NH3)4][Ca(NH3)7]As3S6·2NH3 and [NH4(NH3)4][Ba(NH3)8]As3S6·NH3
Thomas Rossmeier, Markus Reil, and Nikolaus Korber
pp 2206 - 2212; DOI:
10.1021/ic035175z
PDF
Carbene Complexes of Rhodium and Iridium from Tripodal N-Heterocyclic Carbene Ligands: Synthesis and Catalytic Properties
Elena Mas-Marzá, Macarena Poyatos, Mercedes Sanaú, and Eduardo Peris
pp 2213 - 2219; DOI:
10.1021/ic035317p
PDF
Stabilization of Duplex DNA Structure and Suppression of Transcription in Vitro by Bis(quinone diimine) Complexes of Rh(III) and Ru(II)
Patty K.-L. Fu, Patricia M. Bradley, and Claudia Turro:
pp 2220 - 2220; DOI:
10.1021/ic0400179
PDF
An Unusual Mixed-Valence Cu(I)-Cu(II) 3-D Framework
Hong Zhao, Zhi-Rong Qu, Qiong Ye, Xi-Sen Wang, JingZhang, Ren-Gen Xiong, and Xiao-Zeng You:
pp 2220 - 2220; DOI:
10.1021/ic040024x
PDF

Issue 7


Synthesis, Structure, and Magnetism of a Ferric 24-Azametallacrown-8 Complex
Shen Lin, Shi-Xiong Liu, Zhong Chen, Bi-Zhou Lin, and Song Gao
pp 2222 - 2224; DOI:
10.1021/ic035145w
PDF
Syntheses, Structural Characterization, and Host-Guest Chemistry of Ethynylcrown Ether Containing Polynuclear Gold(I) Complexes
Xiao-Xia Lu, Chi-Kwan Li, Eddie Chung-Chin Cheng, Nianyong Zhu, and Vivian Wing-Wah Yam
pp 2225 - 2227; DOI:
10.1021/ic0499603
PDF
Transformation between Diphosphinoamines and Iminobiphosphines: a Reversible P-N-P N=P-P Rearrangement Triggered by Protonation/Deprotonation
Zhaofu Fei, Nermin Biricik, Dongbin Zhao, Rosario Scopelliti, and Paul J. Dyson
pp 2228 - 2230; DOI:
10.1021/ic049850w
PDF
Exploring the Localized-to-Delocalized Boundary in Mixed-Valence Systems Using Infrared Spectroelectrochemistry
Reginaldo C. Rocha and Andrew P. Shreve
pp 2231 - 2233; DOI:
10.1021/ic0354771
PDF
mer-[FeIII(bpca)(CN)3]-: A New Low-Spin Iron(III) Complex to Build Heterometallic Ladder-like Chains
Rodrigue Lescouëzec, Jacqueline Vaissermann, Luminita Marilena Toma, Rosa Carrasco, Francesc Lloret, and Miguel Julve
pp 2234 - 2236; DOI:
10.1021/ic030284z
PDF
Cooling of Melts: Kinetic Stabilization and Polymorphic Transitions in the KInSnSe4 System
Seong-Ju Hwang, Ratnasabapathy G. Iyer, Pantelis N. Trikalitis, Andrew G. Ogden, and Mercouri G. Kanatzidis
pp 2237 - 2239; DOI:
10.1021/ic0351545
PDF
[Ag6(PMo10V2O40)](CH3COO)·8H2O: A 3D Macrocationic Polyoxometallic Keggin Complex
Feng-Xian Liu, Catherine Marchal-Roch, Philippe Bouchard, Jérôme Marrot, Jean-Pierre Simonato, Gilbert Hervé, and Francis Sécheresse
pp 2240 - 2242; DOI:
10.1021/ic035313k
PDF
Toward a Photochemical and Thermal Molecular Machine: Reversible Ligand Dissociation and Binding in a Ruthenium(II)-2,2'-bipyridine Complex with Tris(2-pyridylmethyl)amine
Takahiko Kojima, Taisuke Sakamoto, and Yoshihisa Matsuda
pp 2243 - 2245; DOI:
10.1021/ic035137f
PDF
Investigation of the Origin of the Empirical Relationship between Refractive Index and Density on the Basis of First Principles Calculations for the Refractive Indices of Various TiO2 Phases
Xavier Rocquefelte, Fabrice Goubin, Hyun-Joo Koo, Myung-Hwan Whangbo, and Stéphane Jobic
pp 2246 - 2251; DOI:
10.1021/ic035383r
PDF
Chlorides, Oxochlorides, and Oxoacids of 1,8-Diphosphanaphthalene: A System with Imposed Close P···P Interaction
Petr Kilian, Heather L. Milton, Alexandra M. Z. Slawin, and J. Derek Woollins
pp 2252 - 2260; DOI:
10.1021/ic035364h
PDF
A New Route for Preparing Coordination Polymers from Hydrothermal Reactions Involving in Situ Ligand Synthesis
Xi-Xue Hu, Ji-Qing Xu, Peng Cheng, Xiao-Yan Chen, Xiao-Bing Cui, Jiang-Feng Song, Guang-Di Yang, and Tie-Gang Wang
pp 2261 - 2266; DOI:
10.1021/ic0351646
PDF
Systematic Preparation of Mo24+ Building Blocks for Supramolecular Assemblies
F. Albert Cotton, Chun Y. Liu, and Carlos A. Murillo
pp 2267 - 2276; DOI:
10.1021/ic035433s
PDF
An Efficient Synthesis of Acetylide/Trimetal/Acetylide Molecular Wires
John F. Berry, F. Albert Cotton, Carlos A. Murillo, and Brian K. Roberts
pp 2277 - 2283; DOI:
10.1021/ic0354320
PDF
First Isolated Active Titanium Peroxo Complex: Characterization and Theoretical Study
Oxana A. Kholdeeva, Tatiana A. Trubitsina, Raisa I. Maksimovskaya, Anatolii V. Golovin, Wade A. Neiwert, Boris A. Kolesov, Xavier López, and Josep M. Poblet
pp 2284 - 2292; DOI:
10.1021/ic0354466
PDF
Self-Assembly of Lanthanide Helicate Coordination Polymers into 3D Metal-Organic Framework Structures
Sujit K. Ghosh and Parimal K. Bharadwaj
pp 2293 - 2298; DOI:
10.1021/ic034982v
PDF
On the Nature of the Lowest Triplet Excited State of the [Rh2(1,3-diisocyanopropane)4]2+ Ion
Irina V. Novozhilova, Anatoliy V. Volkov, and P. Coppens
pp 2299 - 2307; DOI:
10.1021/ic035243h
PDF
Sandwich-Type Germanotungstates: Structure and Magnetic Properties of the Dimeric Polyoxoanions [M4(H2O)2(GeW9O34)2]12- (M = Mn2+, Cu2+, Zn2+, Cd2+)
Ulrich Kortz, Saritha Nellutla, Ashley C. Stowe, Naresh S. Dalal, Urs Rauwald, Welbeck Danquah, and Didier Ravot
pp 2308 - 2317; DOI:
10.1021/ic0354421
PDF
The Geometry of Nonmetal Hydrides and the Ligand Radius of Hydrogen
E. A. Robinson and R. J. Gillespie
pp 2318 - 2323; DOI:
10.1021/ic030290v
PDF
N,N-Coordinated Radical Anions of S-Methyl-1-phenyl-isothiosemicarbazide in Two Five-Coordinate Ferric Complexes [FeIII(LMe)2X] (X = CH3S-, Cl-)
Sebastien Blanchard, Eckhard Bill, Thomas Weyhermüller, and Karl Wieghardt
pp 2324 - 2329; DOI:
10.1021/ic030285r
PDF
Poly[(2,2'-bipyridine)tetrakis(imidazolato)diiron(II)]: Structural and Spin-State Phase Transitions and Low-Temperature Magnetic Ordering in a Unique 2-Dimensional Material
Brian O. Patrick, William M. Reiff, Victor Sáncheza, Alan Storr, and Robert C. Thompson
pp 2330 - 2339; DOI:
10.1021/ic030170n
PDF
Lattice Energies of Apatites and the Estimation of Hf(PO43-, g)
Natalie J. Flora, Claude H. Yoder, and H. Donald Brooke Jenkins
pp 2340 - 2345; DOI:
10.1021/ic030255o
PDF
Sparkle Model for AM1 Calculation of Lanthanide Complexes: Improved Parameters for Europium
Gerd B. Rocha, Ricardo O. Freire, Nivan B. da Costa, Jr., Gilberto F. de Sá, and Alfredo M. Simas
pp 2346 - 2354; DOI:
10.1021/ic034882p
PDF
Mononuclear and Dinuclear Complexes of Dibenzoeilatin: Synthesis, Structure, and Electrochemical and Photophysical Properties
Sheba D. Bergman, Israel Goldberg, Andrea Barbieri, Francesco Barigelletti, and Moshe Kol
pp 2355 - 2367; DOI:
10.1021/ic0354062
PDF
Density Functional Investigation of Metal-Metal Interactions in d4d4 Face-Shared [M2Cl9]3- (M = Mn, Tc, Re) Systems
Germán Cavigliasso and Robert Stranger
pp 2368 - 2378; DOI:
10.1021/ic0349611
PDF
Reaction of Tin Porphyrins with Vicinal Diols
Guodong Du, Arkady Ellern, and L. Keith Woo
pp 2379 - 2386; DOI:
10.1021/ic035123+
PDF
The Organometallic fac-[(CO)3Mn(H2O)3]+ Aquaion: Base-Hydrolysis and Kinetics of H2O-Substitution
Ulrich Prinz, Ulrich Koelle, Stefan Ulrich, André E. Merbach, Oliver Maas, and Kaspar Hegetschweiler
pp 2387 - 2391; DOI:
10.1021/ic0352809
PDF
A Thiazole-containing Tripodal Ligand: Synthesis, Characterization, and Interactions with Metal Ions and Matrix Metalloproteinases
Hongshan He, Douglas P. Linder, Kenton R. Rodgers, Indrani Chakraborty, and Atta M. Arif
pp 2392 - 2401; DOI:
10.1021/ic034811q
PDF
Proton Control of Oxidation and Spin State in a Series of Iron Tripodal Imidazole Complexes
Cynthia Brewer, Greg Brewer, Charles Luckett, Gwen S. Marbury, Carol Viragh, Alicia M. Beatty, and W. Robert Scheidt
pp 2402 - 2415; DOI:
10.1021/ic0351747
PDF
Ambivalent Intercalators for DNA: L-Shaped Platinum(II) Complexes
Matteo Cusumano, Maria Letizia Di Pietro, Antonino Giannetto, Francesco Nicolò, Bengt Nordén, and Per Lincoln
pp 2416 - 2421; DOI:
10.1021/ic035016f
PDF
Structure of the UO22+-SO42- Ion Pair in Aqueous Solution
J. Neuefeind, S. Skanthakumar, and L. Soderholm
pp 2422 - 2426; DOI:
10.1021/ic035177j
PDF
Crystal Structure and Magnetic Interactions in Nickel(II) Dibridged Complexes Formed by Two Azide Groups or by Both Phenolate Oxygen-Azide, -Thiocyanate, -Carboxylate, or -Cyanate Groups
Subrata Kumar Dey, Nijhuma Mondal, M. Salah El Fallah, Ramon Vicente, Albert Escuer, Xavier Solans, M. Font-Bardía, T. Matsushita, V. Gramlich, and Samiran Mitra
pp 2427 - 2434; DOI:
10.1021/ic0352553
PDF
Base-Induced Dismutation of POCl3 and POBr3: Synthesis and Structure of Ligand-Stabilized Dioxophosphonium Cations
Pavel Rovnaník, Libor Kapika, Jan Taraba, and Milo erník
pp 2435 - 2442; DOI:
10.1021/ic0354163
PDF
Hydrogen Bonded Framework Structures Constructed from 2-(Pyridyl N-oxide) Methylphosphonic Acid Ligands and Erbium(III)
Xin-min Gan, Iris Binyamin, Brian M. Rapko, Jesse Fox, Eileen N. Duesler, and Robert T. Paine
pp 2443 - 2448; DOI:
10.1021/ic0351850
PDF

Issue 8


Direct DNA Photocleavage by a New Intercalating Dirhodium(II/II) Complex: Comparison to Rh2(-O2CCH3)4
Patricia M. Bradley, Alfredo M. Angeles-Boza, Kim R. Dunbar, and Claudia Turro
pp 2450 - 2452; DOI:
10.1021/ic035424j
PDF
Synthesis and Characterization of AU2Se6 (A = K, Cs)
Benny C. Chan, Zeric Hulvey, Kent D. Abney, and Peter K. Dorhout
pp 2453 - 2455; DOI:
10.1021/ic0353209
PDF
Fast Autoxidation of Ethyl Linoleate Catalyzed by [Mn(acac)3] and Bipyridine: A Possible Drying Catalyst for Alkyd Paints
Remy van Gorkum, Elisabeth Bouwman, and Jan Reedijk
pp 2456 - 2458; DOI:
10.1021/ic0354217
PDF
Crystallographic Evidence for Chromium-Platinum Interaction
Thomas A. Scott, Besma Abbaoui, and Hong-Cai Zhou
pp 2459 - 2461; DOI:
10.1021/ic049968c
PDF
Bulk Synthesis of Single-Crystalline Magnesium Oxide Nanotubes
Jinhua Zhan, Yoshio Bando, Junqing Hu, and Dmitri Golberg
pp 2462 - 2464; DOI:
10.1021/ic0351489
PDF
A Prussian-Blue Type Ferrimagnet Na[MnCr(CN)6]: Single Crystal Structure and Magnetic Properties
Wen Dong, Li-Na Zhu, Hai-Bin Song, Dai-Zheng Liao, Zong-Hui Jiang, Shi-Ping Yan, Peng Cheng, and Song Gao
pp 2465 - 2467; DOI:
10.1021/ic0352710
PDF
The Synthesis and X-ray Structure of the First Cobalt Carbonyl-NHC Dimer. Implications for the Use of NHCs in Hydroformylation Catalysis
Hendrik van Rensburg, Robert P. Tooze, Douglas F. Foster, and Alexandra M. Z. Slawin
pp 2468 - 2470; DOI:
10.1021/ic049917f
PDF
Ba2AuTl7: An Intermetallic Compound with a Novel Condensed Structure
Shengfeng Liu and John D. Corbett
pp 2471 - 2473; DOI:
10.1021/ic035399h
PDF
Correlation between 19F Environment and Isotropic Chemical Shift in Barium and Calcium Fluoroaluminates
M. Body, G. Silly, C. Legein, and J.-Y. Buzaré
pp 2474 - 2485; DOI:
10.1021/ic049956r
PDF
Synthesis and Structural Evolution of RuSb3, a New Metastable Skutterudite Compound
Arwyn L. E. Smalley, Michael L. Jespersen, and David C. Johnson
pp 2486 - 2490; DOI:
10.1021/ic030209o
PDF
Cube-Type Nitrido Complexes Containing Titanium and Alkali/Alkaline-Earth Metals
Avelino Martín, Miguel Mena, Adrián Pérez-Redondo, and Carlos Yélamos
pp 2491 - 2498; DOI:
10.1021/ic035493y
PDF
Cs2Pd3(P2O7)2 and Cs2Pd3(As2O7)2: A 3D Palladium Phosphate with a Tunnel Structure and a 2D Palladium Arsenate Containing Strings of Palladium Atoms
Kwang-Hwa Lii, Sue-Lein Wang, and Fen-Ling Liao
pp 2499 - 2502; DOI:
10.1021/ic035438p
PDF
A Structural and Electrochemical Investigation of 1-Alkyl-3-methylimidazolium Salts of the Nitratodioxouranate(VI) Anions [{UO2(NO3)2}2(4-C2O4)]2-, [UO2(NO3)3]-, and [UO2(NO3)4]2-
Antonia E. Bradley, Christopher Hardacre, Mark Nieuwenhuyzen, William R. Pitner, David Sanders, Kenneth R. Seddon, and Robert C. Thied
pp 2503 - 2514; DOI:
10.1021/ic035350b
PDF
Nickel-Manganese Sulfido Carbonyl Cluster Complexes. Synthesis, Structure, and Properties of the Unusual Paramagnetic Complexes Cp2Ni2Mn(CO)3(3-E)2, E = S, Se
Richard D. Adams, Shaobin Miao, Mark D. Smith, Horatio Farach, Charles Edwin Webster, Josiah Manson, and Michael B. Hall
pp 2515 - 2525; DOI:
10.1021/ic0354419
PDF
Main Group Element Nets to a T
Andrea Ienco, Davide M. Proserpio, and Roald Hoffmann
pp 2526 - 2540; DOI:
10.1021/ic0353211
PDF
Structural Analysis of Five-Coordinate Transition Metal Boryl Complexes with Different d-Electron Configurations
King Chung Lam, Wai Han Lam, Zhenyang Lin, Todd B. Marder, and Nicholas C. Norman
pp 2541 - 2547; DOI:
10.1021/ic035248e
PDF
A Luminescent Platinum(II) 2,6-Bis(N-pyrazolyl)pyridine Complex
Stuart A. Willison, Hershel Jude, Ryan M. Antonelli, Jeffrey M. Rennekamp, Nathan A. Eckert, Jeanette A. Krause Bauer, and William B. Connick
pp 2548 - 2555; DOI:
10.1021/ic035066k
PDF
Two-Dimensional Metallic Chain Compounds Y5M2Te2 (M = Fe, Co, Ni) That Are Related to Gd3MnI3. The Hydride Derivative Y5Ni2Te2D0.4
Paul A. Maggard and John D. Corbett
pp 2556 - 2563; DOI:
10.1021/ic0303136
PDF
Metamagnetism in Cobalt Phosphates with Pillared Layer Structures: [Co3(pyz)(HPO4)2F2] and [Co3(4,4'-bpy)(HPO4)2F2xH2O
Wei-Kuo Chang, Ray-Kuang Chiang, Yau-Chen Jiang, Sue-Lein Wang, Shang-Fan Lee, and Kwang-Hwa Lii
pp 2564 - 2568; DOI:
10.1021/ic0353460
PDF
Ionic Pair Complexes with Well-Separated Columnar Stack Structure Based on [Pt(mnt)2]- Ions Showing Unusual Magnetic Transition: Syntheses, Crystal Structures, and Magnetic Properties
X. M. Ren, H. Okudera, R. K. Kremer, Y. Song, C. He, Q. J. Meng, and P. H. Wu
pp 2569 - 2576; DOI:
10.1021/ic035405+
PDF
Secondary Deuterium Kinetic Isotope Effect for Aquation, Solvolysis, and Isomerization Reactions of trans-[Co(en)2(OSMe2)N3]2+, and the Resolution of a Mechanistic Anomaly
W. G. Jackson
pp 2577 - 2584; DOI:
10.1021/ic030271l
PDF
The 1,4-Diphosphabuta-1,3-diene Ligand for Coordination of Divalent Group 13 and 14 Elements: A Density Functional Study
Wolfgang W. Schoeller and Dirk Eisner
pp 2585 - 2589; DOI:
10.1021/ic030234u
PDF
Coordination Polymers Based on Cobridging of Rigid and Flexible Spacer Ligands: Syntheses, Crystal Structures, and Magnetic Properties of [Mn(bpy)(H2O)(C4H4O4)]·0.5bpy, Mn(bpy)(C5H6O4), and Mn(bpy)(C6H8O4)
Y.-Q. Zheng, J.-L. Lin, and Z.-P. Kong
pp 2590 - 2596; DOI:
10.1021/ic0301268
PDF
DFT and Metal-Metal Bonding: A Dys-Functional Treatment for Multiply Charged Complexes?
Simon Petrie and Robert Stranger
pp 2597 - 2610; DOI:
10.1021/ic034525e
PDF
Adenosylcobinamide Plus Exogenous, Sterically Hindered, Putative Axial Bases: A Reinvestigation into the Cause of Record Levels of Co-C Heterolysis
Kenneth M. Doll and Richard G. Finke
pp 2611 - 2623; DOI:
10.1021/ic030141c
PDF
Synthesis and Characterization of Zinc Sensors Based on a Monosubstituted Fluorescein Platform
Elizabeth M. Nolan, Shawn C. Burdette, Jessica H. Harvey, Scott A. Hilderbrand, and Stephen J. Lippard
pp 2624 - 2635; DOI:
10.1021/ic035158+
PDF
Synthesis, Structure, and Magnetic Properties of Amine-Templated Open-Framework Nickel(II) Sulfates
J. N. Behera, K. V. Gopalkrishnan, and C. N. R. Rao
pp 2636 - 2642; DOI:
10.1021/ic035488u
PDF
Synthetic and Structural Investigations of Monomeric Dilithium Boraamidinates and Bidentate NBNCN Ligands with Bulky N-Bonded Groups
T. Chivers, C. Fedorchuk, and M. Parvez
pp 2643 - 2653; DOI:
10.1021/ic0352755
PDF
Electronic Structure and Spectra of Linkage Isomers of Bis(bipyridine)(1,2-dihydroxy-9,10-anthraquinonato)ruthenium(II) and Their Redox Series
Antonietta DelMedico, Elaine S. Dodsworth, A. B. P. Lever, and William J. Pietro
pp 2654 - 2671; DOI:
10.1021/ic035370d
PDF
Donor Ligand Effect on the Nature of the Oxygenating Species in MnIII(salen)-Catalyzed Epoxidation of Olefins: Experimental Evidence for Multiple Active Oxidants
James P. Collman, Li Zeng, and John I. Brauman
pp 2672 - 2679; DOI:
10.1021/ic035360c
PDF
NMR Spectroscopic and X-ray Crystallographic Study of Methylcobalt(III) Compounds with Saturated Amine Ligands
Pauli Kofod and Pernille Harris
pp 2680 - 2688; DOI:
10.1021/ic0302682
PDF
A New Heptanuclear Cobalt(II) Cluster Encapsulated in a Novel Heteropolyoxometalate Topology: Synthesis, Structure, and Magnetic Properties of [Co7(H2O)2(OH)2P2W25O94]16-
Juan M. Clemente-Juan, Eugenio Coronado, Alicia Forment-Aliaga, José R. Galán-Mascarós, Carlos Giménez-Saiz, and Carlos J. Gómez-García
pp 2689 - 2694; DOI:
10.1021/ic0354872
PDF
Platinum-Rhodium Carbonyl Clusters: New Structures and New Types of Dynamical Activity
Richard D. Adams, Burjor Captain, Perry J. Pellechia, and Jack L. Smith, Jr.
pp 2695 - 2702; DOI:
10.1021/ic0353920
PDF
[C6N2H14]0.5·[MnAl3(PO4)4(H2O)2]: A Manganese(II)-Substituted Aluminophosphate with AFN Topology
Lei Shi, Jiyang Li, Jihong Yu, Yi Li, Hong Ding, and Ruren Xu
pp 2703 - 2707; DOI:
10.1021/ic035329a
PDF
Toward Rational Control of Metal Stoichiometry in Heterobimetallic Coordination Complexes: Synthesis and Characterization of Pb(Hsal)2(Cu(salen*))2, [Pb(NO3)(Cu(salen*))2](NO3), Pb(OAc)2(Cu(salen*)), and [Pb(OAc)(Ni(salen*))2](OAc)
John H. Thurston, Christopher G.-Z. Tang, Daniel W. Trahan, and Kenton H. Whitmire
pp 2708 - 2713; DOI:
10.1021/ic035427w
PDF
Novel Synthesis of Trifluoromethylnitrate, CF3ONO2
Malisa S. Chiappero, Maximiliano A. Burgos Paci, Gustavo A. Argüello, and Timothy J. Wallington
pp 2714 - 2716; DOI:
10.1021/ic035425b
PDF
Oxidation of Chlorine(III) by Hypobromous Acid: Kinetics and Mechanism
Zsuzsanna Tóth and István Fábián
pp 2717 - 2723; DOI:
10.1021/ic0354318
PDF
The Decamethylferrocene(+/0) Electrode Reaction in Organic Solvents at Variable Pressure and Temperature
Mitsuru Matsumoto and Thomas W. Swaddle
pp 2724 - 2735; DOI:
10.1021/ic030326j
PDF
Synthesis, Structures, and Magnetic Properties of Novel Mononuclear, Tetranuclear, and 1D Chain MnIII Complexes Involving Three Related Asymmetrical Trianionic Ligands
Jean-Pierre Costes, Françoise Dahan, Bruno Donnadieu, Maria-Jesus Rodriguez Douton, Maria-Isabel Fernandez Garcia, Azzedine Bousseksou, and Jean-Pierre Tuchagues
pp 2736 - 2744; DOI:
10.1021/ic0348796
PDF
Are Gas-Phase Reactions of Five-Coordinate Divalent Metal Ion Complexes Affected by Coordination Geometry?
Marianny Y. Combariza, Justin T. Fermann, and Richard W. Vachet
pp 2745 - 2753; DOI:
10.1021/ic0354668
PDF
Synthesis and Structural Characterization of 0D Vanadium Borophosphate [Co(en)3]2[V3P3BO19][H2PO4]·4H2O and 1D Vanadium Oxides [Co(en)3][V3O9]·H2O and [Co(dien)2][V3O9]· H2O Templated by Cobalt Complexes: Cooperative Organization of the Complexes and the Inorganic Networks
Yu Wang, Jihong Yu, Qinhe Pan, Yu Du, Yongchun Zou,and, and Ruren Xu:
pp 2754 - 2754; DOI:
10.1021/ic0400383
PDF

Issue 9


Effect of Inhibitors on the Catalyzed Dehydration of HCO3- by Copper(II) Complexes Re-Evaluated
Rudi van Eldik
pp 2756 - 2758; DOI:
10.1021/ic0353561
PDF
Ferromagnetic Exchange in Two Dicopper(II) Complexes Using a -Alkoxo--7-azaindolate Bridge
Yi-Chian Chou, Shu-Fei Huang, Rajesh Koner, Gene-Hsiang Lee, Yu Wang, Sasankasekhar Mohanta, and Ho-Hsiang Wei
pp 2759 - 2761; DOI:
10.1021/ic035322t
PDF
APSe6 (A = K, Rb, and Cs): Polymeric Selenophosphates with Reversible Phase-Change Properties
In Chung, Junghwan Do, Christian G. Canlas, David P. Weliky, and Mercouri G. Kanatzidis
pp 2762 - 2764; DOI:
10.1021/ic035448q
PDF
A New, Convenient Synthesis of the Linear Phosphazene Salt [Cl3P=N=PCl3]Cl: Preparation of Higher Linear Homologues [Cl3P=N-(PCl2=N)x=PCl3]Cl (x = 1-3) and the 16-Membered Macrocycle [NCCl(NPCl2)3]2
Eric Rivard, Alan J. Lough, and Ian Manners
pp 2765 - 2767; DOI:
10.1021/ic049955z
PDF
Spin Control in Ladderlike Hexanuclear Copper(II) Complexes with Metallacyclophane Cores
Emilio Pardo, Kevin Bernot, Miguel Julve, Francesc Lloret, Joan Cano, Rafael Ruiz-García, Fernando S. Delgado, Catalina Ruiz-Pérez, Xavier Ottenwaelder, and Yves Journaux
pp 2768 - 2770; DOI:
10.1021/ic049875v
PDF
Binding of 9-Methylguanine to [cis-Ru(2,2'-bpy)2]2+: First X-ray Structure of a cis-Bis Purine Complex of Ruthenium
Fabio Zobi, Michael Hohl, Iwan Zimmermann, and Roger Alberto
pp 2771 - 2772; DOI:
10.1021/ic0354623
PDF
Synthesis and Crystal Structure of Barium Thioborate Ba7(BS3)4S
Youngsik Kim and Steve W. Martin
pp 2773 - 2775; DOI:
10.1021/ic035454m
PDF
The Synthesis and Crystal Structures of Two-Dimensional Coordination Polymers of Ph2P(O)-CH2CH2-P(O)Ph2 and Ph2P(O)-C5H3N-P(O)Ph2 with Praseodymium
Zdenek Spichal, Marek Necas, Jiri Pinkas, and Josef Novosad
pp 2776 - 2778; DOI:
10.1021/ic0499648
PDF
Photochromic Dithienylethene Derivatives Containing Ru(II) or Os(II) Metal Units. Sensitized Photocyclization from a Triplet State
Ron T. F. Jukes, Vincenzo Adamo, Frantiek Hartl, Peter Belser, and Luisa De Cola
pp 2779 - 2792; DOI:
10.1021/ic035334e
PDF
A Systematic Evaluation of Molecular Recognition Phenomena. 4. Selective Binding of Dicarboxylic Acids to Hexaazamacrocyclic Ligands Based on Molecular Flexibility
Carmen Anda, Antoni Llobet, Arthur E. Martell, Joseph Reibenspies, Emanuela Berni, and Xavier Solans
pp 2793 - 2802; DOI:
10.1021/ic035121p
PDF
Hydrogen Bonding in the Crystal Structures of the Ionic Liquid Compounds Butyldimethylimidazolium Hydrogen Sulfate, Chloride, and Chloroferrate(II,III)
Philipp Kölle and Richard Dronskowski
pp 2803 - 2809; DOI:
10.1021/ic035237l
PDF
Cyclophosphazenes as Nodal Ligands in Coordination Polymers
Philip I. Richards and Alexander Steiner
pp 2810 - 2817; DOI:
10.1021/ic035455e
PDF
Synthesis of Heteroleptic Bis(diimine)carbonylchlororuthenium(II) Complexes from Photodecarbonylated Precursors
Christopher M. Kepert, Glen B. Deacon, Norma Sahely, Leone Spiccia, Gary D. Fallon, Brian W. Skelton, and Allan H. White
pp 2818 - 2827; DOI:
10.1021/ic0351895
PDF
NO Binding to Cobalamin: Influence of the Metal Oxidation State
Cenk Selçuki, Rudi van Eldik, and Timothy Clark
pp 2828 - 2833; DOI:
10.1021/ic0347945
PDF
Exchange Coupling of Paramagnetic Ions in a Polyoxometalate Matrix: Density Functional Study of Diiron(III) Substituted -Silicotungstates
Ekaterina M. Zueva, Henry Chermette, and Serguei A. Borshch
pp 2834 - 2844; DOI:
10.1021/ic035161t
PDF
Solution Dynamics and Stability of Lanthanide(III) (S)-2-(p-Nitrobenzyl)DOTA Complexes
Mark Woods, Zoltan Kovacs, Robert Kiraly, Ernö Brücher, Shanrong Zhang, and A. Dean Sherry
pp 2845 - 2851; DOI:
10.1021/ic0353007
PDF
Crystal Structures of Artificial Metalloproteins: Tight Binding of FeIII(Schiff-Base) by Mutation of Ala71 to Gly in Apo-Myoglobin
Takafumi Ueno, Masataka Ohashi, Masaharu Kono, Kazuyoshi Kondo, Atsuo Suzuki, Takashi Yamane, and Yoshihito Watanabe
pp 2852 - 2858; DOI:
10.1021/ic0498539
PDF
Synthesis and Oxygenation of a Nickel(II) and Zinc(II) Dithiolate: An Experimental and Theoretical Comparison
Craig A. Grapperhaus, Christopher S. Mullins, Pawel M. Kozlowski, and Mark S. Mashuta
pp 2859 - 2866; DOI:
10.1021/ic035205y
PDF
Preparation and Characterization of [99TcO] Apcitide: A Technetium Labeled Peptide
Lynn C. Francesconi, Yongyong Zheng, Judit Bartis, Michael Blumenstein, Catherine Costello, and Mark A. De Rosch
pp 2867 - 2875; DOI:
10.1021/ic035473w
PDF
Structural Changes upon Reduction of Dipyrido[2,3-a:3',2'-c]phenazine Probed by Vibrational Spectroscopy, ab Initio Calculations, and Deuteration Studies
Sarah L. Howell, Benjamin J. Matthewson, Matthew I. J. Polson, Anthony K. Burrell, and Keith C. Gordon
pp 2876 - 2887; DOI:
10.1021/ic030225l
PDF
Synthesis, Structural Characterization, and Thermal Stability of a New Layered Germanate Structure, Na4Ge16O28(OH)12
Annemieke W. C. van den Berg, Govert Baak, Hendrikus van Koningsveld, Jacobus C. Jansen, and Thomas Maschmeyer
pp 2888 - 2894; DOI:
10.1021/ic035272s
PDF
pH-Specific Synthesis of a Dinuclear Vanadium(V)-Peroxo-Citrate Complex in Aqueous Solutions: pH-Dependent Linkage, Spectroscopic and Structural Correlations with Other Aqueous Vanadium(V)-Peroxo-Citrate and Non-Peroxo Species
M. Kaliva, C. P. Raptopoulou, A. Terzis, and A. Salifoglou
pp 2895 - 2905; DOI:
10.1021/ic034283i
PDF
Metallic Macrocycle with a 1,3-Alternate Calix[4]arene Phosphorus Ligand
Sanghoon Kim, Jong Seung Kim, Ok Jae Shon, Shim Sung Lee, Ki-Min Park, Sang Ook Kang, and Jaejung Ko
pp 2906 - 2913; DOI:
10.1021/ic030221g
PDF
Solvothermal Syntheses, Crystal Structures, and Thermal Properties of New Manganese Thioantimonates(III): The First Example of the Thermal Transformation of an Amine-Rich Thioantimonate into an Amine-Poorer Thioantimonate
Michael Schaefer, Christian Näther, Nicolai Lehnert, and Wolfgang Bensch
pp 2914 - 2921; DOI:
10.1021/ic034970+
PDF
Tetradentate Bis(o-iminobenzosemiquinonate(1-)) Radical Ligands and Their o-Aminophenolate(1-) Derivatives in Complexes of Nickel(II), Palladium(II), and Copper(II)
Kil Sik Min, Thomas Weyhermüller, Eberhard Bothe, and Karl Wieghardt
pp 2922 - 2931; DOI:
10.1021/ic0302480
PDF
Variable -Bonding in Iron(II) Porphyrinates with Nitrite, CO, and tert-Butyl Isocyanide: Characterization of [Fe(TpivPP)(NO2)(CO)]-
Habib Nasri, Mary K. Ellison, Maoyu Shang, Charles E. Schulz, and W. Robert Scheidt
pp 2932 - 2942; DOI:
10.1021/ic035119y
PDF
NMR Spectroscopic Characterization of Copper(II) and Zinc(II) Complexes of Indomethacin
Saadallah Ramadan, Trevor W. Hambley, Brendan J. Kennedy, and Peter A. Lay
pp 2943 - 2946; DOI:
10.1021/ic0352811
PDF
Isomerization Dynamics in Homo- and Heterochiral Atropoisomer Copper(I) Diimine Complexes: A 2D EXSY NMR Study
Isabelle Pianet and Jean-Marc Vincent
pp 2947 - 2953; DOI:
10.1021/ic0353108
PDF
Experimental and Theoretical Characterization of Arsenite in Water: Insights into the Coordination Environment of As-O
Alejandro Ramírez-Solís, Rita Mukopadhyay, Barry P. Rosen, and Timothy L. Stemmler
pp 2954 - 2959; DOI:
10.1021/ic0351592
PDF
Low Melting Inorganic Salts of Alkyl-, Fluoroalkyl-, Alkyl Ether-, and Fluoroalkyl Ether-Substituted Oxazolidine and Morpholine
Jinwi Kim, Rajendra P. Singh, and Jean'ne M. Shreeve
pp 2960 - 2966; DOI:
10.1021/ic049916n
PDF
Crystal Structures and Magnetic Properties of Two Low-Dimensional Materials Constructed from [MnIII(salen)H2O]+ and [M(CN)8]3-/4- (M = Mo or W) Precursors
Pawe Przychodze, Krzysztof Lewiski, Maria Baanda, Robert Peka, Micha Rams, Tadeusz Wasiutyski, Carine Guyard-Duhayon, and Barbara Sieklucka
pp 2967 - 2974; DOI:
10.1021/ic035464n
PDF
Phosphorus-Based p-tert-Butylcalix[5]arene Ligands
Paul Sood, Mohan Koutha, Maomian Fan, Yaroslav Klichko, Hongming Zhang, and Michael Lattman
pp 2975 - 2980; DOI:
10.1021/ic035359d
PDF
Structural Effects of the Lone Pair on Lead(II), and Parallels with the Coordination Geometry of Mercury(II). Does the Lone Pair on Lead(II) Form H-Bonds? Structures of the Lead(II) and Mercury(II) Complexes of the Pendant-Donor Macrocycle DOTAM (1,4,7,10-Tetrakis(carbamoylmethyl)-1,4,7,10-tetraazacyclododecane)
Robert D. Hancock, Joseph H. Reibenspies, and Hulisani Maumela
pp 2981 - 2987; DOI:
10.1021/ic030277a
PDF
Reactions of NO with Mn(II) and Mn(III) Centers Coordinated to Carboxamido Nitrogen: Synthesis of a Manganese Nitrosyl with Photolabile NO
Kaushik Ghosh, Aura A. Eroy-Reveles, Belem Avila, Theodore R. Holman, Marilyn M. Olmstead, and Pradip K. Mascharak
pp 2988 - 2997; DOI:
10.1021/ic030331n
PDF
Synthesis, Crystal Structures, and Optical Properties of Two New Layered Quaternary Tantalum Thiophosphates and the Thermal Conversion of Cs4Ta4P4S24 into Cs2Ta2P2S12
Andreas Gutzmann, Christian Näther, and Wolfgang Bensch
pp 2998 - 3004; DOI:
10.1021/ic035273k
PDF
Kinetics and Equilibria of the Interactions of Hydroxamic Acids with Gallium(III) and Indium(III)
Lauretta Morroni, Fernando Secco, Marcella Venturini, Begoña Garcia, and José Maria Leal
pp 3005 - 3012; DOI:
10.1021/ic034781r
PDF
Magnetic Studies on Hexahalorhenate(IV) Salts of Ferrocenium Cations [Fe(C5R5)2]2[ReX6] (R = H, CH3; X = Cl, Br, I)
Ricardo González, Raúl Chiozzone, Carlos Kremer, Francesca Guerra, Giovanni De Munno, Francesc Lloret, Miguel Julve, and Juan Faus
pp 3013 - 3019; DOI:
10.1021/ic030302c
PDF
Tri- and Pentanuclear Tungsten-(-S)-M Clusters (M = W, Cu, Ag)
Wenjian Zhang, Axel Behrens, Jessica Gätjens, Martin Ebel, Xintao Wu, and Dieter Rehder
pp 3020 - 3023; DOI:
10.1021/ic0302783
PDF
Equilibrium of Low- and High-Spin States of Ni(II) Complexes Controlled by the Donor Ability of the Bidentate Ligands
Hideki Ohtsu and Koji Tanaka
pp 3024 - 3030; DOI:
10.1021/ic035486+
PDF

Issue 10


Preparation of Re(I)- and 99mTc(I)-Metallocarboranes in Water under Weakly Basic Reaction Conditions
Oyebola O. Sogbein, Patricia Merdy, Pierre Morel, and John F. Valliant
pp 3032 - 3034; DOI:
10.1021/ic049887g
PDF
The Observation of the First Vibrational Overtone of Dihydrogen in the Luminescence of Zeolites at Low Temperatures
Ray L. Sweany, Jason M. Bono, and Kevin J. Boyd
pp 3035 - 3037; DOI:
10.1021/ic049957j
PDF
Using Model Complexes To Augment and Advance Metalloproteinase Inhibitor Design
Faith E. Jacobsen and Seth M. Cohen
pp 3038 - 3047; DOI:
10.1021/ic035388o
PDF
The Ammine, Thiosulfato, and Mixed Ammine/Thiosulfato Complexes of Silver(I) and Gold(I)
W. Nimal Perera and Gamini Senanayake
pp 3048 - 3056; DOI:
10.1021/ic035301z
PDF
Dyads Containing Iridium(III) Bis-terpyridine as Photoactive Center: Synthesis and Electron Transfer Study
Etienne Baranoff, Isabelle M. Dixon, Jean-Paul Collin, Jean-Pierre Sauvage, Barbara Ventura, and Lucia Flamigni
pp 3057 - 3066; DOI:
10.1021/ic0351038
PDF
A Structural and Mössbauer Study of Complexes with Fe2(-O(H))2 Cores: Stepwise Oxidation from FeII(-OH)2FeII through FeII(-OH)2FeIII to FeIII(-O)(-OH)FeIII
Audria Stubna, Du-Hwan Jo, Miquel Costas, William W. Brenessel, Hanspeter Andres, Emile L. Bominaar, Eckard Münck, and Lawrence Que, Jr.
pp 3067 - 3079; DOI:
10.1021/ic030296k
PDF
Structural and Thermodynamic Properties of Group 13 Imidometallanes and Their Heavier Analogues
Alexey Y. Timoshkin and Henry F. Schaefer III
pp 3080 - 3089; DOI:
10.1021/ic030266h
PDF
Synthesis, Structure, and Dynamics of Nickelacarboranes Incorporating the [nido-7,9-C2B9H11]2- Ligand
Bruce E. Hodson, Thomas D. McGrath, and F. Gordon A. Stone
pp 3090 - 3097; DOI:
10.1021/ic035458r
PDF
Proton Transfer to Nickel-Thiolate Complexes. 1. Protonation of [Ni(SC6H4R-4)2(Ph2PCH2CH2PPh2)] (R = Me, MeO, H, Cl, or NO2)
Valerie Autissier, William Clegg, Ross W. Harrington, and Richard A. Henderson
pp 3098 - 3105; DOI:
10.1021/ic030322e
PDF
Proton Transfer to Nickel-Thiolate Complexes. 2. Rate-Limiting Intramolecular Proton Transfer in the Reactions of [Ni(SC6H4R-4)(PhP{CH2CH2PPh2}2)]+ (R = NO2, Cl, H, Me, or MeO)
Valerie Autissier, Pedro Martin Zarza, Athinoula Petrou, Richard A. Henderson, Ross W. Harrington, and William C. Clegg
pp 3106 - 3115; DOI:
10.1021/ic0303237
PDF
Complex Formation of Vanadium(IV) with 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol and Related Ligands
Bernd Morgenstern, Stefan Steinhauser, Kaspar Hegetschweiler, Eugenio Garribba, Giovanni Micera, Daniele Sanna, and László Nagy
pp 3116 - 3126; DOI:
10.1021/ic0352046
PDF
Preparation and Solid-State Characterization of Mixed-Ligand Coordination/Organometallic Oligomers and Polymers of Copper(I) and Silver(I) Using Diphosphine and Mono- and Diisocyanide Ligands
Éric Fournier, Frédéric Lebrun, Marc Drouin, Andreas Decken, and Pierre D. Harvey
pp 3127 - 3135; DOI:
10.1021/ic034806m
PDF
Unexpected Reactivity of PdCl2 and PtCl2 Complexes of the Unsaturated Diphosphine o-Me2TTF(PPh2)2 toward Chloride Abstraction with Thallium Triflate
Thomas Devic, Patrick Batail, Marc Fourmigué, and Narcis Avarvari
pp 3136 - 3141; DOI:
10.1021/ic035447y
PDF
Assignment of the Electronic Spectra of [Mo(CN)8]4- and [W(CN)8]4- by Ab Initio Calculations
M. F. A. Hendrickx, V. S. Mironov, L. F. Chibotaru, and A. Ceulemans
pp 3142 - 3150; DOI:
10.1021/ic035282t
PDF
Electron Delocalization in Nickel Metallic Wires: A DFT Investigation of Ni3(dpa)4Cl2 and [Ni3(dpa)4]3+ (dpa = Dipyridylamide) and Extension to Higher Nuclearity Chains
Pascal Kiehl, Marie-Madeleine Rohmer, and Marc Bénard
pp 3151 - 3158; DOI:
10.1021/ic040011j
PDF
Synthesis and Characterization of a New Three-Dimensional Lanthanide Carboxyphosphonate: Ln4(H2O)7[O2C-C5H10N-CH2-PO3]4(H2O)5
Christian Serre, Norbert Stock, Thomas Bein, and Gérard Férey
pp 3159 - 3163; DOI:
10.1021/ic035363p
PDF
Defect-Induced Acceleration of a Solid-State Chemical Reaction in Zinc Alkoxide Single Crystals
Eva Schön, Dietmar A. Plattner, and Peter Chen
pp 3164 - 3169; DOI:
10.1021/ic030341o
PDF
Distorted Equatorial Coordination Environments and Weakening of U=O Bonds in Uranyl Complexes Containing NCN and NPN Ligands
Mark J. Sarsfield, Madeleine Helliwell, and James Raftery
pp 3170 - 3179; DOI:
10.1021/ic035349c
PDF
Carbon-Sulfur Bond Cleavage in Bis(N-alkyldithiocarbamato)cadmium(II) Complexes: Heterolytic Desulfurization Coupled to Topochemical Proton Transfer
Laura H. van Poppel, Thomas L. Groy, and M. Tyler Caudle
pp 3180 - 3188; DOI:
10.1021/ic035135v
PDF
Methyl Tin(IV) Derivatives of HOTeF5 and HN(SO2CF3)2: A Solution Multinuclear NMR Study and the X-ray Crystal Structures of (CH3)2SnCl(OTeF5) and [(CH3)3Sn(H2O)2][N(SO2CF3)2]
Ashwani Vij, William W. Wilson, Vandana Vij, Robert C. Corley, Fook S. Tham, Michael Gerken, Ralf Haiges, Stefan Schneider, Thorsten Schroer, and Ross I. Wagner
pp 3189 - 3199; DOI:
10.1021/ic049785q
PDF
Dendrimers with a Copper(I) Bis(phenanthroline) Core: Synthesis, Electronic Properties, and Kinetics
Elzbieta Gumienna-Kontecka, Yannick Rio, Cyril Bourgogne, Mourad Elhabiri, Rémy Louis, Anne-Marie Albrecht-Gary, and Jean-François Nierengarten
pp 3200 - 3209; DOI:
10.1021/ic049945y
PDF
Crystallographic, Electronic, and Magnetic Studies of 2-GaM (M = Cr, Mn or Fe): Trends in Itinerant Magnetism
Olivier Gourdon, Sergey L. Bud'ko, Darrick Williams, and Gordon J. Miller
pp 3210 - 3218; DOI:
10.1021/ic035419f
PDF
On the Road to a Termolecular Complex with Acetone: A Heterometallic Supramolecular Network {[Rh2(O2CCF3)42-OCMe2·[Cu4(O2CCF3)4]}
Evgeny V. Dikarev, Kristian W. Andreini, and Marina A. Petrukhina
pp 3219 - 3224; DOI:
10.1021/ic030340w
PDF
An Evaluation by Density Functional Theory of M-M Interactions in Organometallic Clusters with the [Fe3MoS3]2+ Cores
Paola Nava, Jaehong Han, Reinhart Ahlrichs, and Dimitri Coucouvanis
pp 3225 - 3229; DOI:
10.1021/ic0499392
PDF
Unusually High Chemical Compressibility of Normally Rigid Type-I Clathrate Framework: Synthesis and Structural Study of Sn24P19.3BrxI8-x Solid Solution, the Prospective Thermoelectric Material
Kirill A. Kovnir, Julia V. Zaikina, Lyudmila N. Reshetova, Andrei V. Olenev, Evgeny V. Dikarev, and Andrei V. Shevelkov
pp 3230 - 3236; DOI:
10.1021/ic035097f
PDF
The Bis-Phenyltin-Substituted, Lone-Pair-Containing Tungstoarsenate [(C6H5Sn)2As2W19O67(H2O)]8-
Firasat Hussain, Ulrich Kortz, and Ronald J. Clark
pp 3237 - 3241; DOI:
10.1021/ic049797b
PDF
Synthesis of [NH4]MnCl2(OAc) and [NH4]2MnCl4(H2O)2 by Solvothermal Dehydration and Structure/Property Correlations in a One-Dimensional Antiferromagnet
James D. Martin, Ryan F. Hess, and Paul D. Boyle
pp 3242 - 3247; DOI:
10.1021/ic049881r
PDF
An Electron Localization Function Study of the Geometry of d0 Molecules of the Period 4 Metals Ca to Mn
Ronald J. Gillespie, Stéphane Noury, Julien Pilmé, and Bernard Silvi
pp 3248 - 3256; DOI:
10.1021/ic0354015
PDF
Multi-Iron Wells-Dawson Heteropolytungstates. Electrochemical Probing of Siderophoric Behavior in Sandwich-Type Complexes
Bineta Keita, Israel Martyr Mbomekalle, Louis Nadjo, Travis M. Anderson, and Craig L. Hill
pp 3257 - 3263; DOI:
10.1021/ic035495i
PDF
Ternary Rare Earth Osmium Aluminides R7+xOs12Al61+y Belonging to a Structural Family with Layered Topology
Jens Niermann and Wolfgang Jeitschko
pp 3264 - 3270; DOI:
10.1021/ic0303035
PDF
Cyano-Bridged 2D CuII-CrIII Coordination Polymers: Structural Evidence for Formation of a Polymeric Macrocyclic Metallic Compound
Hui-Zhong Kou, Yun-Bo Jiang, Bei Chuan Zhou, and Ru-Ji Wang
pp 3271 - 3276; DOI:
10.1021/ic049857d
PDF
A Hybrid Density Functional Study of O-O Bond Cleavage and Phenyl Ring Hydroxylation for a Biomimetic Non-Heme Iron Complex
Tomasz Borowski, Arianna Bassan, and Per E. M. Siegbahn
pp 3277 - 3291; DOI:
10.1021/ic035395c
PDF
Electrochemical Investigations of the [Tris(2-(diphenylphosphino)thiaphenolato)ruthenate(II)] Monoanion Reveal Metal- and Ligand-Centered Events: Radical, Reactivity, and Rate
Craig A. Grapperhaus and Selma Poturovic
pp 3292 - 3298; DOI:
10.1021/ic035085u
PDF
Toward a General Strategy for the Synthesis of Heterobimetallic Coordination Complexes for Use as Precursors to Metal Oxide Materials: Synthesis, Characterization, and Thermal Decomposition of Bi2(Hsal)6·M(Acac)3 (M = Al, Co, V, Fe, Cr)
John H. Thurston, Daniel Trahan, Teyeb Ould-Ely, and Kenton H. Whitmire
pp 3299 - 3305; DOI:
10.1021/ic035284d
PDF
Low-Coordinate Iron(II) Amido Complexes of -Diketiminates: Synthesis, Structure, and Reactivity
Nathan A. Eckert, Jeremy M. Smith, Rene J. Lachicotte, and Patrick L. Holland
pp 3306 - 3321; DOI:
10.1021/ic035483x
PDF
A Geometrically-Constraining Bis(benzimidazole) Ligand and Its Nearly Tetrahedral Complexes with Fe(II) and Mn(II)
Robert T. Stibrany, Maxim V. Lobanov, Harvey J. Schugar,and, and Joseph A. Potenza:
pp 3322 - 3322; DOI:
10.1021/ic040050v
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Issue 11


A Monomeric Nickel-Dioxygen Adduct Derived from a Nickel(I) Complex and O2
Koyu Fujita, Ralph Schenker, Weiwei Gu, Thomas C. Brunold, Stephen P. Cramer, and Charles G. Riordan
pp 3324 - 3326; DOI:
10.1021/ic049876n
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Synthesis of the New, Cubane-like W3S4Co Cluster Core. Completion of the Homologous Series [(5-Cp')3M3S4Co(CO)] (M = Cr, Mo, W)
Konrad Herbst, Lutz Dahlenburg, and Michael Brorson
pp 3327 - 3328; DOI:
10.1021/ic049742+
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Supramolecular Stereocontrol of Octahedral Metal-Centered Chirality. Ligand Modulation
Jonathan J. Jodry, Richard Frantz, and Jérôme Lacour
pp 3329 - 3331; DOI:
10.1021/ic049661d
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Synthesis and Structure of Heterospin Compounds Based on the [Mn6(O)2Piv10]-Cluster Unit and Nitroxide
Victor Ovcharenko, Elena Fursova, Galina Romanenko, and Vladimir Ikorskii
pp 3332 - 3334; DOI:
10.1021/ic049859y
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A New Class of (-2:2-Disulfido)dicopper Complexes: Synthesis, Characterization, and Disulfido Exchange
Eric C. Brown, Nermeen W. Aboelella, Anne M. Reynolds, Gabriel Aullón, Santiago Alvarez, and William B. Tolman
pp 3335 - 3337; DOI:
10.1021/ic049811k
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X-ray Structure of Physiological Copper(II)-Bis(L-histidinato) Complex
Patrick Deschamps, Prasad P. Kulkarni, and Bibudhendra Sarkar
pp 3338 - 3340; DOI:
10.1021/ic035413q
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H2 Activation in Aqueous Solution: Formation of trans-[Fe(DMeOPrPE)2H(H2)]+ via the Heterolysis of H2 in Water
John D. Gilbertson, Nathaniel K. Szymczak, and David R. Tyler
pp 3341 - 3343; DOI:
10.1021/ic0498642
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Structural Analysis of the Conformational Flexibility of Tris(pyrazolyl)borate Ligands and Their Analogues
Heather De Bari and Marc Zimmer
pp 3344 - 3348; DOI:
10.1021/ic0498992
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Photoelectron Spectroscopic and Electronic Structure Studies of CH2O Bonding and Reactivity on ZnO Surfaces: Steps in the Methanol Synthesis Reaction
P. M. Jones, J. A. May, J. B. Reitz, and Edward I. Solomon
pp 3349 - 3370; DOI:
10.1021/ic035252q
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Synthesis, Structure, and Bonding of Lu7Z2Te2 (Z = Ni, Pd, Ru). Linking Typical Tricapped Trigonal Prisms in Metal-Rich Compounds
Ling Chen and John D. Corbett
pp 3371 - 3376; DOI:
10.1021/ic030261k
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Synthesis and Properties of Dimetallic M1[Pz]-M2[Schiff Base] Complexes
Min Zhao, Chang Zhong, Charlotte Stern, Anthony G. M. Barrett, and Brian M. Hoffman
pp 3377 - 3385; DOI:
10.1021/ic035402x
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Complex Formation of Isocytosine Tautomers with PdII and PtII
Deepali Gupta, Markus Huelsekopf, Marta Morell Cerdà, Ralf Ludwig, and Bernhard Lippert
pp 3386 - 3393; DOI:
10.1021/ic0353965
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Dynamic Structural Change of a Twisted Hexaporphyrin Complex by Highly Specific Molecular Recognition
Hiroaki Kitagishi, Akiharu Satake, and Yoshiaki Kobuke
pp 3394 - 3405; DOI:
10.1021/ic049645g
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The First (Ferrocenylmethyl)imidazolium and (Ferrocenylmethyl)triazolium Room Temperature Ionic Liquids
Ye Gao, Brendan Twamley, and Jean'ne M. Shreeve
pp 3406 - 3412; DOI:
10.1021/ic049961v
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Honeycomb Nets with Interpenetrating Frameworks Involving Iminodiacetato-Copper(II) Blocks and Bipyridine Spacers: Syntheses, Characterization, and Magnetic Studies
Suman Mukhopadhyay, Pabitra Baran Chatterjee, Debdas Mandal, Golam Mostafa, Andrea Caneschi, Joris van Slageren, Timothy J. R. Weakley, and Muktimoy Chaudhury
pp 3413 - 3420; DOI:
10.1021/ic035422z
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The Course of (R2R'SiO)3TaCl2 (R = tBu, R' = H, Me, Ph, tBu (silox); R = iPr, R' = tBu, iPr) Reduction Is Dependent on Siloxide Size
Andrew R. Chadeayne, Peter T. Wolczanski, and Emil B. Lobkovsky
pp 3421 - 3432; DOI:
10.1021/ic035407u
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Synthesis, Characterization, and Solution Behavior of Optically Active cis Organocobalt Salen Complexes with L-Amino Acids
Renata Dreos, Giorgio Nardin, Lucio Randaccio, Patrizia Siega, and Giovanni Tauzher
pp 3433 - 3440; DOI:
10.1021/ic035059w
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Photocatalytic Synthesis of Copper Colloids from Cu(II) by the Ferrihydrite Core of Ferritin
Daniel Ensign, Mark Young, and Trevor Douglas
pp 3441 - 3446; DOI:
10.1021/ic035415a
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Ionic Liquids Based upon Metal Halide/Substituted Quaternary Ammonium Salt Mixtures
Andrew P. Abbott, Glen Capper, David L. Davies, and Raymond Rasheed
pp 3447 - 3452; DOI:
10.1021/ic049931s
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Lithiation of (tBuNH)3PNSiMe3 and Formation of Tetraimidophosphate Complexes Containing M3O3 Rings (M = Li, K): X-ray Structure of the Stable Radical {(Me3SiN)P(3-NtBu)3[3-Li(THF)]3(OtBu)}
Andrea Armstrong, Tristram Chivers, Masood Parvez, Gabriele Schatte, and René T. Boeré
pp 3453 - 3460; DOI:
10.1021/ic035377v
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Rational Syntheses, Structure, and Properties of the First Bismuth(II) Carboxylate
Evgeny V. Dikarev and Bo Li
pp 3461 - 3466; DOI:
10.1021/ic049937h
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Syntheses of Functionalized Ferratricarbadecaboranyl Complexes
Bhaskar M. Ramachandran, Patrick J. Carroll, and Larry G. Sneddon
pp 3467 - 3474; DOI:
10.1021/ic049827a
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Structure and Dynamics of a Dihydrogen/Hydride Ansa Molybdenocene Complex
Vincent Pons, Stephen L. J. Conway, Malcolm L. H. Green, Jennifer C. Green, Benjamin J. Herbert, and D. Michael Heinekey
pp 3475 - 3483; DOI:
10.1021/ic0496875
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Luminescent AgI-CuI Heterometallic Hexa-, Octa-, and Hexadecanuclear Alkynyl Complexes
Qiao-Hua Wei, Gang-Qiang Yin, Li-Yi Zhang, Lin-Xi Shi, Zong-Wan Mao, and Zhong-Ning Chen
pp 3484 - 3491; DOI:
10.1021/ic0499244
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Diimine-Acetylide Compounds of Ruthenium: The Structural and Spectroscopic Effects of Oxidation
Christopher J. Adams and Simon J. A. Pope
pp 3492 - 3499; DOI:
10.1021/ic035181v
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Light-Induced Metastable States in Oxalatenitrosylruthenium(II) and Terpyridinenitrosylruthenium(II) Complexes
Sylvie Ferlay, Helmut W. Schmalle, Giancarlo Francese, Helen Stoeckli-Evans, Mirco Imlau, Dominik Schaniel, and Theo Woike
pp 3500 - 3506; DOI:
10.1021/ic0350178
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Sterically Hindered and Robust Pnictogen Ligands Derived from Carboranes: Synthesis and X-ray Structure Determination of Tris(1'-methyl(1,2-dicarba-closo-dodecaboran-1-yl))phosphine, Tris(1'-methyl(1,2-dicarba-closo-dodecaboran-1-yl))arsine and Chloro(Tris(1'-methyl(1,2-dicarba-closo-dodecaboran-1-yl))phosphine)gold(I)
Arienne S. King, George Ferguson, James F. Britten, and John F. Valliant
pp 3507 - 3513; DOI:
10.1021/ic049947i
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Functionalization of Polyoxometalates: From Lindqvist to Keggin Derivatives. 1. Synthesis, Solution Studies, and Spectroscopic and ESI Mass Spectrometry Characterization of the Rhenium Phenylimido Tungstophosphate [PW11O39{ReNC6H5}]4-
Céline Dablemont, Anna Proust, René Thouvenot, Carlos Afonso, Françoise Fournier, and Jean-Claude Tabet
pp 3514 - 3520; DOI:
10.1021/ic0499042
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{trans-1,4-Bis[(4-pyridyl)ethenyl]benzene}(2,2'-bipyridine)ruthenium(II) Complexes and Their Supramolecular Assemblies with -Cyclodextrin
Sergio H. Toma, Miriam Uemi, Sofia Nikolaou, Daniela M. Tomazela, Marcos N. Eberlin, and Henrique E. Toma
pp 3521 - 3527; DOI:
10.1021/ic0352250
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Hydrothermal Syntheses, Crystal Structures, and Characteristics of a Series of Cd-btx Coordination Polymers (btx = 1,4-Bis(triazol-1-ylmethyl)benzene)
Xiangru Meng, Yinglin Song, Hongwei Hou, Huayun Han, Bo Xiao, Yaoting Fan, and Yu Zhu
pp 3528 - 3536; DOI:
10.1021/ic0354670
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Molecular Structure and Conformations of 2,2-Di-tert-butyl-1,3-diaza-2-silacyclopentane: Gas Electron Diffraction and Quantum Chemical Calculations
Heinz Oberhammer, Georgiy V. Girichev, Nina I. Giricheva, Alexander V. Krasnov, and Uwe Klingebiel
pp 3537 - 3542; DOI:
10.1021/ic0497836
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Structure of the Hydrated and Dimethyl Sulfoxide Solvated Rubidium Ions in Solution
Paola D'Angelo and Ingmar Persson
pp 3543 - 3549; DOI:
10.1021/ic030310t
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New Poly-Iron(II) Complexes of N4O Dinucleating Schiff Bases and Pseudohalides: Syntheses, Structures, and Magnetic and Mössbauer Properties
Athanassios K. Boudalis, Juan-Modesto Clemente-Juan, Françoise Dahan, and Jean-Pierre Tuchagues:
pp 3550 - 3550; DOI:
10.1021/ic040062g
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Issue 12


Molecular Wheel B82- as a New Inorganic Ligand. Photoelectron Spectroscopy and ab Initio Characterization of LiB8-
Anastassia N. Alexandrova, Hua-Jin Zhai, Lai-Sheng Wang, and Alexander I. Boldyrev
pp 3552 - 3554; DOI:
10.1021/ic049706a
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Microwave Assisted Stereoselective Synthesis of Cis-Substituted TinIV Phthalocyanine Dicarboxylates. Application as Corrosion Inhibitors
Hiram I. Beltrán, Raquel Esquivel, Arturo Sosa-Sánchez, Jose L. Sosa-Sánchez, Herbert Höpfl, Victor Barba, Norberto Farfán, Monica Galicia García, Octavio Olivares-Xometl, and Luis S. Zamudio-Rivera
pp 3555 - 3557; DOI:
10.1021/ic049634n
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Low Temperature Induced Synthesis of TiN Nanocrystals
Xin Feng, Yu-Jun Bai, Bo Lü, Cheng-Guo Wang, Yong-Xin Qi, Yu-Xian Liu, Gui-Li Geng, and Li Li
pp 3558 - 3560; DOI:
10.1021/ic049841n
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Structure and Dynamics of Dinuclear Zirconium(IV) Complexes
Weiqing Zhong, John A. Parkinson, Simon Parsons, Iain D. H. Oswald, Robert A. Coxall, and Peter J. Sadler
pp 3561 - 3572; DOI:
10.1021/ic049932k
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A Detailed Study of the Vapochromic Behavior of {Tl[Au(C6Cl5)2]}n
Eduardo J. Fernández, José M. López-de-Luzuriaga, Miguel Monge, Manuel Montiel, M. Elena Olmos, Javier Pérez, Antonio Laguna, Fernando Mendizabal, Ahmed A. Mohamed, and John P. Fackler, Jr.
pp 3573 - 3581; DOI:
10.1021/ic0499446
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Synthesis, Structure, and Characterization of a Cubic Thallium Cluster Phase of the Bergman Type, Na13(Cd~0.70Tl~0.30)27
Bin Li and John D. Corbett
pp 3582 - 3587; DOI:
10.1021/ic0400033
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Arachno, Nido, and Closo Aromatic Isomers of the Li6B6H6 Molecule
Anastassia N. Alexandrova and Alexander I. Boldyrev
pp 3588 - 3592; DOI:
10.1021/ic049835r
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Electron-Transfer Chemistry of Ru-Linker-(Heme)-Modified Myoglobin: Rapid Intraprotein Reduction of a Photogenerated Porphyrin Cation Radical
Chad E. Immoos, Angel J. Di Bilio, Michael S. Cohen, Wytze Van der Veer, Harry B. Gray, and Patrick J. Farmer
pp 3593 - 3596; DOI:
10.1021/ic049741h
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Dawson Type Heteropolyanions. 3.
Roland Contant, Mostefa Abbessi, René Thouvenot, and Gilbert Hervé
pp 3597 - 3604; DOI:
10.1021/ic049885w
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Investigation of Transition Metal-Imido Bonding in M(NBut)2(dpma)
James T. Ciszewski, James F. Harrison, and Aaron L. Odom
pp 3605 - 3617; DOI:
10.1021/ic049644o
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Eclipsed M2X6 Compounds Exhibiting Very Short Metal-Metal Triple Bonds
David R. Manke, Zhi-Heng Loh, and Daniel G. Nocera
pp 3618 - 3624; DOI:
10.1021/ic049795r
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Synthesis of Carbaalane Halogen Derivatives
Andreas Stasch, Herbert W. Roesky, Denis Vidovic, Jörg Magull, Hans-Georg Schmidt, and Mathias Noltemeyer
pp 3625 - 3630; DOI:
10.1021/ic035460i
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Alkaline Side-Coordination Strategy for the Design of Nickel(II) and Nickel(III) Bis(1,2-diselenolene) Complex Based Materials
Xavi Ribas, João C. Dias, Jorge Morgado, Klaus Wurst, Isabel C. Santos, Manuel Almeida, José Vidal-Gancedo, Jaume Veciana, and Concepció Rovira
pp 3631 - 3641; DOI:
10.1021/ic049860x
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Hydrocarbyl Ligand "Tuning" of the PtII/IV Redox Potential
Andrei N. Vedernikov, Maren Pink, and Kenneth G. Caulton
pp 3642 - 3646; DOI:
10.1021/ic034731m
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Terminal Ligand Influence on the Electronic Structure and Intrinsic Redox Properties of the [Fe4S4]2+ Cubane Clusters
You-Jun Fu, Xin Yang, Xue-Bin Wang, and Lai-Sheng Wang
pp 3647 - 3655; DOI:
10.1021/ic0495261
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[Mn2(AsS4)4]8- and [Cd2(AsS4)2(AsS5)2]8-: Discrete Clusters with High Negative Charge from Alkali Metal Polythioarsenate Fluxes
Ratnasabapathy G. Iyer and Mercouri G. Kanatzidis
pp 3656 - 3662; DOI:
10.1021/ic049905u
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Coordination Polymers with Carborane Anions: Silver Dinitrile Complexes
Aleema Westcott, Nina Whitford, and Michaele J. Hardie
pp 3663 - 3672; DOI:
10.1021/ic049849x
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Electrochemical, Spectroscopic, and Structural Evidence for the Mild Hydrolysis of Tetracyanoethylene, TCNE, To Form the 2,3,3-Tricyanoacrylamidate Ligand: Isolation of an Unexpected Quadruply-Bonded Polymeric Material [Mo2(O2CCMe3)3((NC)2CC(CN)CONH)]
Françoise Conan, Benoît Le Gall, Jean-Michel Kerbaol, Sylvie Le Stang, Jean Sala-Pala, Yves Le Mest, John Bacsa, Xiang Ouyang, Kim R. Dunbar, and Charles F. Campana
pp 3673 - 3681; DOI:
10.1021/ic0351186
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Organometallic Early Lanthanide Clusters: Syntheses and X-ray Structures of New Monocyclopentadienyl Complexes
Fanny Bonnet, Marc Visseaux, Denise Barbier-Baudry, Abderrafia Hafid, Estelle Vigier, and Marek M. Kubicki
pp 3682 - 3690; DOI:
10.1021/ic035444l
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DFT Study of the Geometry and Energy Order of the Low Singlet and Triplet States of [d4-5-CpMo(CO)2X] 16-Electron Complexes (X = Halogen, CN, H, and CH3)
Faraj Hasanayn, Marie-Zabel Markarian, and Rasha Al-Rifai
pp 3691 - 3696; DOI:
10.1021/ic0354973
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Crystal Structure and Spectroscopic Properties of CsVO2SO4
S. B. Rasmussen, S. Boghosian, K. Nielsen, K. M. Eriksen, and R. Fehrmann
pp 3697 - 3701; DOI:
10.1021/ic030314y
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Chalcogen-Chalcogen Bonds in Edge-Sharing Square-Planar d8 Complexes. Are They Possible?
Gabriel Aullón, Mohamed Hamidi, Agustí Lledós, and Santiago Alvarez
pp 3702 - 3714; DOI:
10.1021/ic034906s
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Linkage Isomerism in Nitrite Reduction by Cytochrome cd1 Nitrite Reductase
Radu Silaghi-Dumitrescu
pp 3715 - 3718; DOI:
10.1021/ic035403p
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A Convenient Synthesis of New Isolable Phosphaalkenes Using the Base-Induced Rearrangement of Secondary Vinylphosphines
Mandy Yam, Chi-Wing Tsang, and Derek P. Gates
pp 3719 - 3723; DOI:
10.1021/ic049796j
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Electronic Spectroscopy, Photophysical Properties, and Emission Quenching Studies of an Oxidatively Robust Perfluorinated Platinum Porphyrin
Siu-Wai Lai, Yuan-Jun Hou, Chi-Ming Che, Hei-Leung Pang, Kwok-Yin Wong, Chi K. Chang, and Nianyong Zhu
pp 3724 - 3732; DOI:
10.1021/ic049902h
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Density Functional Theory Investigation of the Active Site of Fe-Hydrogenases. Systematic Study of the Effects of Redox State and Ligands Hardness on Structural and Electronic Properties of Complexes Related to the [2Fe]H Subcluster
Maurizio Bruschi, Piercarlo Fantucci, and Luca De Gioia
pp 3733 - 3741; DOI:
10.1021/ic035326y
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The Reactions of Tellurium Tetrahalides with Triphenylphosphine under Ambient Conditions
Sari M. Närhi, Raija Oilunkaniemi, Risto S. Laitinen, and Markku Ahlgrén
pp 3742 - 3750; DOI:
10.1021/ic049789v
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Anion Binding with a Tripodal Amine
Md. Alamgir Hossain, Jennifer Ann Liljegren, Douglas Powell, and Kristin Bowman-James
pp 3751 - 3755; DOI:
10.1021/ic049762b
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Dimeric (Tris(tert-butyl)silyl)phosphanyl (Tris(tert-butyl)silyl)phosphanediyl Gallane: A Molecule with a Ga-P-Ga Heteroallyl System
Sabine Weinrich, Holger Piotrowski, Martin Vogt, Axel Schulz, and Matthias Westerhausen
pp 3756 - 3762; DOI:
10.1021/ic0303284
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Issue 13


K2Ag6Sn3S10: A Quaternary Sulfide Composed of Silver Sulfide Layers Pillared by Zigzag Chains [SnS3]2-
Menghe Baiyin, Yonglin An, Xin Liu, Min Ji, Cuiying Jia, and Guiling Ning
pp 3764 - 3765; DOI:
10.1021/ic035474o
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Synthesis of an Unprecedented Bicapped Adamantoid [Cu6(2-I)(3-I)4(4-I)(m-tolyl3P)4(CH3CN)2] Cluster
Tarlok S. Lobana, Parminderjit Kaur, and Takanori Nishioka
pp 3766 - 3767; DOI:
10.1021/ic049903+
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A Novel TGS-like Inorganic-Organic Hybrid and a Preliminary Investigation of Its Possible Ferroelectric Behavior
Yong-Hua Li, Zhi-Rong Qu, Hong Zhao, Qiong Ye, Li-Xin Xing, Xi-Sen Wang, Ren-Gen Xiong, and Xiao-Zeng You
pp 3768 - 3770; DOI:
10.1021/ic034672c
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Structure of Discrete (H2O)12 Clusters Present in the Cavity of Polymeric Interlinked Metallocycles of Nd(III) or Gd(III) and a Podand Ligand
Subhadip Neogi, G. Savitha, and Parimal K. Bharadwaj
pp 3771 - 3773; DOI:
10.1021/ic0495618
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Photochromism of Metal Complexes Composed of Diarylethene Ligands and ZnCl2
Kenji Matsuda, Yoshihiro Shinkai, and Masahiro Irie
pp 3774 - 3776; DOI:
10.1021/ic049686c
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Redox-Triggered Molecular Movement in a Multicomponent Metal Complex in Solution and in the Solid State
Christophe Bucher, Jean-Claude Moutet, Jacques Pécaut, Guy Royal, Eric Saint-Aman, and Fabrice Thomas
pp 3777 - 3779; DOI:
10.1021/ic049684s
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Ferrimagnetic Ordering Due to Fe(III) d and Donor Spins in (Ethylenedithiotetrathiafulvalenoquinone-1,3-dithiolemethide)2·FeBr4
Takuya Matsumoto, Toyonari Sugimoto, Hiroko Aruga Katori, Satoru Noguchi, and Takekazu Ishida
pp 3780 - 3782; DOI:
10.1021/ic049851o
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The Outer-Sphere Oxidation of Nitrosyliron(II)hemoglobin by Peroxynitrite Leads to the Release of Nitrogen Monoxide
Susanna Herold
pp 3783 - 3785; DOI:
10.1021/ic035340a
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An Addition to the Oxoacid Family: H2B12(OH)12
Daniel J. Stasko, Kevin J. Perzynski, Mark A. Wasil, Julia K. Brodbeck, Kristin Kirschbaum, Yong Wah Kim, and Cora Lind
pp 3786 - 3788; DOI:
10.1021/ic049564k
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[TcI(CN)3(CO)3]2- and [ReI(CN)3(CO)3]2-: Case Studies for the Binding Properties of CN- and CO
Philipp Kurz, Bernhard Spingler, Thomas Fox, and Roger Alberto
pp 3789 - 3791; DOI:
10.1021/ic049774x
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From Eilatin to Isoeilatin: A Skeletal Rearrangement Strongly Influences -Stacking of Ru(II) Complex
Sheba D. Bergman, Dvora Reshef, Limor Frish, Yoram Cohen, Israel Goldberg, and Moshe Kol
pp 3792 - 3794; DOI:
10.1021/ic049806g
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Clioquinol, a Drug for Alzheimer's Disease Specifically Interfering with Brain Metal Metabolism: Structural Characterization of Its Zinc(II) and Copper(II) Complexes
Massimo Di Vaira, Carla Bazzicalupi, Pierluigi Orioli, Luigi Messori, Bruno Bruni, and Paolo Zatta
pp 3795 - 3797; DOI:
10.1021/ic0494051
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A Well-Resolved uudd Cyclic Water Tetramer in the Crystal Host of [Cu(adipate)(4,4-bipyridine)]·(H2O)2
La-Sheng Long, Yan-Rong Wu, Rong-Bin Huang, and Lan-Sun Zheng
pp 3798 - 3800; DOI:
10.1021/ic0494354
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Mixed Carboxylate-Bridged Dimanganese(II/III) Compounds Prepared by an O2-Dependent Oxidative Cleavage of Ketones
Kenneth Bendix Jensen, Edel Johansen, Frank Bartnik Larsen, and Christine J. McKenzie
pp 3801 - 3803; DOI:
10.1021/ic0498135
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Structure and Magnetism of a Spin Ladder System: (C5H9NH3)2CuBr4
Roger D. Willett, Calin Galeriu, Christopher P. Landee, Mark M. Turnbull, and Brendan Twamley
pp 3804 - 3811; DOI:
10.1021/ic030317a
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Supramolecular Mn(II) and Mn(II)/Mn(III) Grid Complexes with [Mn9(2-O)12] Core Structures. Structural, Magnetic, and Redox Properties and Surface Studies
Liang Zhao, Zhiqiang Xu, Hilde Grove, Victoria A. Milway, Louise N. Dawe, Tareque S. M. Abedin, Laurence K. Thompson, Timothy L. Kelly, Rosemary G. Harvey, David O. Miller, Laura Weeks, Joseph G. Shapter, and Kenneth J. Pope
pp 3812 - 3824; DOI:
10.1021/ic030319v
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Tuning the Coordination Geometry of Silver in Bis(pyrazolyl)alkane Complexes
Daniel L. Reger, James R. Gardinier, and Mark D. Smith
pp 3825 - 3832; DOI:
10.1021/ic0497174
PDF
Synthesis, Characterization, and Luminescent Properties of Dinuclear Gold(I) Xanthate Complexes: X-ray Structure of [Au2(nBu-xanthate)2]
Ahmed A. Mohamed, Ibrahim Kani, Anna O. Ramirez, and John P. Fackler, Jr.
pp 3833 - 3839; DOI:
10.1021/ic0349858
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Gas Phase, Solution, and Solid State Alkali Ion Binding by the [NbE8]3- (E = As, Sb) Complexes: Synthesis, Structure, and Spectroscopy
Banu Kesanli, James Fettinger, Brian Scott, and Bryan Eichhorn
pp 3840 - 3846; DOI:
10.1021/ic035397x
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Myoglobin as an Efficient Electrocatalyst for Nitromethane Reduction
Jean Boutros and Mekki Bayachou
pp 3847 - 3853; DOI:
10.1021/ic035173e
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Ligand Displacement and Oxidation Reactions of Methyl(oxo)rhenium(V) Complexes
Xiaopeng Shan, Arkady Ellern, Ilia A. Guzei, and James H. Espenson
pp 3854 - 3862; DOI:
10.1021/ic049772c
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Synthesis, Structural Characterization, Solution Chemistry, and Preliminary Biological Studies of the Ruthenium(III) Complexes [TzH][trans-RuCl4(Tz)2] and [TzH][trans-RuCl4(DMSO)(Tz)]·(DMSO), the Thiazole Analogues of Antitumor ICR and NAMI-A
Pasquale Mura, Mercedes Camalli, Luigi Messori, Francesca Piccioli, Piero Zanello, and Maddalena Corsini
pp 3863 - 3870; DOI:
10.1021/ic0354116
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Rotational Spectra, Structures, Hyperfine Constants, and the Nature of the Bonding of KrCuF and KrCuCl
Julie M. Michaud, Stephen A. Cooke, and Michael C. L. Gerry
pp 3871 - 3881; DOI:
10.1021/ic040009s
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Two- and Three-Dimensional Cadmium-Organic Frameworks with Trimesic Acid and 4,4'-Trimethylenedipyridine
Filipe A. Almeida Paz and Jacek Klinowski
pp 3882 - 3893; DOI:
10.1021/ic049523o
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First Bivalent Palladium and Platinum Cyanoximates: Synthesis, Characterization, and Biological Activity
Daniel Eddings, Charles Barnes, Nikolay Gerasimchuk, Paul Durham, and Konstantin Domasevich
pp 3894 - 3909; DOI:
10.1021/ic0303439
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Hydrothermal Synthesis and Characterization of Two Organically Templated Cadmium Borophosphates with Novel Structures
Wei Liu, Minghui Ge, Xinxin Yang, Haohong Chen, Manrong Li, and Jingtai Zhao
pp 3910 - 3914; DOI:
10.1021/ic0498034
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First Structurally Characterized Palladium(II)-Substituted Polyoxoanion: [Cs2Na(H2O)10Pd3(-SbIIIW9O33)2]9-
Li-Hua Bi, Markus Reicke, Ulrich Kortz, Bineta Keita, Louis Nadjo, and Ronald J. Clark
pp 3915 - 3920; DOI:
10.1021/ic049736d
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Dinuclear Ruthenium and Iron Complexes Containing Palladium and Platinum with Tri-tert-Butylphosphine Ligands: Synthesis, Structures, and Bonding
Richard D. Adams, Burjor Captain, Wei Fu, Michael B. Hall, Mark D. Smith, and Charles Edwin Webster
pp 3921 - 3929; DOI:
10.1021/ic049675j
PDF
A New High-Spin Iron(III) Complex with a Pentadentate Macrocyclic Amidopyridine Ligand: A Change from Slow Single-Ion Paramagnetic Relaxation to Long-Range Antiferromagnetic Order in a Hydrogen-Bonded Network
Ivan V. Korendovych, Richard J. Staples, William M. Reiff, and Elena V. Rybak-Akimova
pp 3930 - 3941; DOI:
10.1021/ic0351601
PDF
Gas-Phase Structure, Conformation, and Sulfur 2p Photoelectron Spectroscopy of Pentafluorosulfur Fluorosulfonate, SF5OSO2F
Christiane Leibold, Heinz Oberhammer, T. Darrah Thomas, Leif J. Saethre, Rolf Winter, and Gary L. Gard
pp 3942 - 3947; DOI:
10.1021/ic035439h
PDF
Synthesis and Characterization of a Novel Cadmium-Organic Framework with Trimesic Acid and 1,2-Bis(4-pyridyl)ethane
Filipe A. Almeida Paz and Jacek Klinowski
pp 3948 - 3954; DOI:
10.1021/ic049794z
PDF
Insights into the Thermal Fragmentation of Intramolecularly Coordinated Gallanes. A Matrix-Isolation FTIR Study
Eliza Gemel and Jens Müller
pp 3955 - 3964; DOI:
10.1021/ic035496a
PDF
Luminescent Ruthenium(II) Bipyridine-Calix[4]arene Complexes as Receptors for Lanthanide Cations
Paul D. Beer, Fridrich Szemes, Paolo Passaniti, and Mauro Maestri
pp 3965 - 3975; DOI:
10.1021/ic0499401
PDF
Stereoelectronic Influence of the Type of Bifunctional ansa-Monocyclopentadienyldimethylsilylamido Ligand on the Molecular Structures Displayed by Zirconium Dichloride and 1,4-Diphenylbutadiene Complexes
Leonie F. Braun, Thorsten Dreier, Matthew Christy, and Jeffrey L. Petersen
pp 3976 - 3987; DOI:
10.1021/ic040001i
PDF
NMR Studies of Mononuclear Octahedral Ni(II) Complexes Supported by Tris((2-pyridyl)methyl)amine-Type Ligands
Ewa Szajna, Piotr Dobrowolski, Amy L. Fuller, Atta M. Arif, and Lisa M. Berreau
pp 3988 - 3997; DOI:
10.1021/ic040002a
PDF
Synthesis and Structure of Alkaline Earth Silicon Nitrides: BaSiN2, SrSiN2, and CaSiN2
Zoltán A. Gál, Phillip M. Mallinson, Heston J. Orchard, and Simon J. Clarke
pp 3998 - 4006; DOI:
10.1021/ic049901p
PDF
Reexamination of the Magnetic Properties of Cu2(dca)4(2,5-me2pyz) {dca = Dicyanamide; me2pyz = Dimethylpyrazine}: Isolated Spin-1/2 Dimers versus Long-Range Magnetic Ordering
J. L. Manson, J. A. Schlueter, H.-J. Koo, and M.-H. Whangbo
pp 4007 - 4011; DOI:
10.1021/ic0354769
PDF
Bonding in Tetrahedral Cu4(3-X)4L4 Copper(I) Clusters: A DFT Investigation
Andrés Vega and Jean-Yves Saillard
pp 4012 - 4018; DOI:
10.1021/ic035262r
PDF
Effect of Dissolved Oxygen on the Oxidation of Dithionate Ion. Extremely Unusual Kinetic Traces
Gábor Lente and István Fábián
pp 4019 - 4025; DOI:
10.1021/ic0499087
PDF
Investigation of the Incommensurate and Commensurate Magnetic Superstructures of LiCuVO4 and CuO on the Basis of the Isotropic Spin Exchange and Classical Spin Approximations
D. Dai, H.-J. Koo, and M.-H. Whangbo
pp 4026 - 4035; DOI:
10.1021/ic035314c
PDF
Multielectron Atom Transfer Reactions of Perchlorate and Other Substrates Catalyzed by Rhenium Oxazoline and Thiazoline Complexes: Reaction Kinetics, Mechanisms, and Density Functional Theory Calculations
Lee D. McPherson, Markus Drees, Saeed I. Khan, Thomas Strassner, and Mahdi M. Abu-Omar
pp 4036 - 4050; DOI:
10.1021/ic0498945
PDF
Time-Resolved Photoacoustics Study of the Ruthenium(II) Bis(2,2'-bipyridine)(4,4'-dicarboxy-2,2'-bipyridine) Complex
Jaroslava Mikovská and Randy W. Larsen
pp 4051 - 4055; DOI:
10.1021/ic035095v
PDF
Metal-Metal Bonded Homo- and Heterobimetallic Compounds of Pt(I) and Pd(I) Supported by a Bridging-N,P:N',P' Moiety of a Potentially Hexadentate Ligand
Nathan D. Jones, S. Jo Ling Foo, Brian O. Patrick, and Brian R. James
pp 4056 - 4063; DOI:
10.1021/ic040019t
PDF
Fluorocarbonyl Trifluoromethanesulfonate, FC(O)OSO2CF3: Structure and Conformational Properties in the Gaseous and Condensed Phases
Carlos O. Della Védova, Anthony J. Downs, Vladimir P. Novikov, Heinz Oberhammer, Simon Parsons, Rosana M. Romano, and Alex Zawadski
pp 4064 - 4071; DOI:
10.1021/ic049865u
PDF
Synthesis, Structure, and Catalytic Oxidation Chemistry from the First Oxo-Imido Schiff Base Metal Complexes
Ramkrishna Ramnauth, Salih Al-Juaid, Majid Motevalli, Bernardetta C. Parkin, and Alice C. Sullivan
pp 4072 - 4079; DOI:
10.1021/ic035318h
PDF
Role of Solvation in the Reduction of the Uranyl Dication by Water: A Density Functional Study
Lyudmila V. Moskaleva, Sven Krüger, Andreas Spörl, and Notker Rösch
pp 4080 - 4090; DOI:
10.1021/ic035450h
PDF
Coordination Complexes of 2-(4-Quinolyl)nitronyl Nitroxide with M(hfac)2 [M = Mn(II), Co(II), and Cu(II)]: Syntheses, Crystal Structures, and Magnetic Characterization
Hongmei Wang, Zhiliang Liu, Caiming Liu, Deqing Zhang, Zhengliang Lü,, Hua Geng, Zhigang Shuai, and Daoben Zhu
pp 4091 - 4098; DOI:
10.1021/ic049946q
PDF

Issue 14


Spin Canting in the 3D Anionic Dicyanamide Structure (SPh3)Mn(dca)3 (Ph = Phenyl, dca = Dicyanamide)
John A. Schlueter, Jamie L. Manson, Kylee A. Hyzer, and Urs Geiser
pp 4100 - 4102; DOI:
10.1021/ic035398p
PDF
Spin Crossover in a Tetranuclear Cr(III)-Fe(III)3 Complex
Radovan Herchel, Roman Boa, Milan Gembick, Jozef Koíek, and Franz Renz
pp 4103 - 4105; DOI:
10.1021/ic035374i
PDF
[C6H5NH(CH3)2]2Te2I10: Secondary I···I Bonds Build up a 3D Network
Jacqueline M. Ryan and Zhengtao Xu
pp 4106 - 4108; DOI:
10.1021/ic049443k
PDF
Ozonic Acid and Its Ionic Salts: Ab Initio Probing of the O42- Dianion
Ben M. Elliott and Alexander I. Boldyrev
pp 4109 - 4111; DOI:
10.1021/ic049418e
PDF
Formation of High Concentrations of BrO2 in Acidic Bromate Solutions
Wagner A. Alves, Carlos E. S. Côrtes, and Roberto B. Faria
pp 4112 - 4114; DOI:
10.1021/ic049488l
PDF
Solvent Effects on the Conversion of Dicopper(II) -2:2-Peroxo to Bis--oxo Dicopper(III) Complexes: Direct Probing of the Solvent Interaction
Hong-Chang Liang, Mark J. Henson, Lanying Q. Hatcher, Michael A. Vance, Christiana Xin Zhang, David Lahti, Susan Kaderli, Roger D. Sommer, Arnold L. Rheingold, Andreas D. Zuberbühler, Edward I. Solomon, and Kenneth D. Karlin
pp 4115 - 4117; DOI:
10.1021/ic0498283
PDF
Iron and Copper Complexes of Tetraphenyl-m-benziporphyrin: Reactivity of the Internal C-H Bond
Chen-Hsiung Hung, Fei-Chien Chang, Cheng-Yu Lin, Krystyna Rachlewicz, Marcin Stpie, Lechosaw Latos-Grayski, Gene-Hsiang Lee, and Shie-Ming Peng
pp 4118 - 4120; DOI:
10.1021/ic049821l
PDF
Functionalized Thiosemicarbazone Clusters of Copper(I) and Silver(I)
Laura J. Ashfield, Andrew R. Cowley, Jonathan R. Dilworth, and Paul S. Donnelly
pp 4121 - 4123; DOI:
10.1021/ic035451+
PDF
1-D Cobalt(II) Spin Transition Compound with Strong Interchain Interaction: [Co(pyterpy)Cl2]·X
Shinya Hayami, Koichiro Hashiguchi, Gergely Juhász, Masaaki Ohba, Hisashi kawa, Yonezo Maeda, Kenichi Kato, Keiichi Osaka, Masaki Takata, and Katsuya Inoue
pp 4124 - 4126; DOI:
10.1021/ic049509b
PDF
Quantum Mechanical Models of the Resting State of the Vanadium-Dependent Haloperoxidase
Giuseppe Zampella, Joslyn Yudenfreund Kravitz, Charles Edwin Webster, Piercarlo Fantucci, Michael B. Hall, Heather A. Carlson, Vincent L. Pecoraro, and Luca De Gioia
pp 4127 - 4136; DOI:
10.1021/ic0353256
PDF
Synthesis, Structure, and Magnetic Properties of a Mn21 Single-Molecule Magnet
E. Carolina Sañudo, Wolfgang Wernsdorfer, Khalil A. Abboud, and George Christou
pp 4137 - 4144; DOI:
10.1021/ic0353864
PDF
Modeling Novel Radiopharmaceuticals: Mono-C6-Substituted PnAO Ligands (PnAO = 3,3,9,9-Tetramethyl-4,8-diazaundecane-2,10-dione Dioxime)
Paul S. Walker, Paul M. Bergin, Martin C. Grossel, and Peter N. Horton
pp 4145 - 4153; DOI:
10.1021/ic0497634
PDF
Supramolecular Spin-Crossover Iron Complexes Based on Imidazole-Imidazolate Hydrogen Bonds
Yukinari Sunatsuki, Hiromi Ohta, Masaaki Kojima, Yuichi Ikuta, Yoshiyuki Goto, Naohide Matsumoto, Seiichiro Iijima, Haruo Akashi, Sumio Kaizaki, Françoise Dahan, and Jean-Pierre Tuchagues
pp 4154 - 4171; DOI:
10.1021/ic0498384
PDF
Stable, Chloride-Induced Monohapto-Bonding Mode for an Allyl Ligand in a Pd(II) Complex Bearing a New Bidentate Phosphonite-Oxazoline Ligand
Jing Zhang, Pierre Braunstein, and Richard Welter
pp 4172 - 4177; DOI:
10.1021/ic035479l
PDF
Imidazole and Imidazolate Iron Complexes: On the Way for Tuning 3D-Structural Characteristics and Reactivity. Redox Interconversions Controlled by Protonation State
François Lambert, Clotilde Policar, Stephanie Durot, Michèle Cesario, Lu Yuwei, Hafsa Korri-Youssoufi, Bineta Keita, and Louis Nadjo
pp 4178 - 4188; DOI:
10.1021/ic0498687
PDF
Correlation of Structure and Function in Oligonuclear Zinc(II) Model Phosphatases
Bernhard Bauer-Siebenlist, Franc Meyer, Etelka Farkas, Denis Vidovic, Jose Antonio Cuesta-Seijo, Regine Herbst-Irmer, and Hans Pritzkow
pp 4189 - 4202; DOI:
10.1021/ic035491d
PDF
Synthesis, Structure, and Magnetic Properties of a [Mn22] Wheel-like Single-Molecule Magnet
Muralee Murugesu, James Raftery, Wolfgang Wernsdorfer, George Christou, and Euan K. Brechin
pp 4203 - 4209; DOI:
10.1021/ic049620h
PDF
Exchange Interactions and Theoretical Analysis of 31P NMR Spectra in VO(HPO4)·0.5H2O
Sébastien Petit, Serguei A. Borshch, and Vincent Robert
pp 4210 - 4215; DOI:
10.1021/ic035437x
PDF
Amphiphilic Ruthenium Sensitizers and Their Applications in Dye-Sensitized Solar Cells
C. Klein, Md. K. Nazeeruddin, D. Di Censo, P. Liska, and Michael Grätzel
pp 4216 - 4226; DOI:
10.1021/ic049906m
PDF
Electron Delocalization in a Ruthenium(II) Bis(2,2':6',2' '-terpyridyl) Complex
Andrew C. Benniston, Glen Chapman, Anthony Harriman, Maryam Mehrabi, and Craig A. Sams
pp 4227 - 4233; DOI:
10.1021/ic035380e
PDF
Dinuclear Nickel Complexes with Bidentate N,O Ligands: Synthesis, Structure, and Catalytic Oligomerization of Ethylene
Fredy Speiser, Pierre Braunstein, and Lucien Saussine
pp 4234 - 4240; DOI:
10.1021/ic049921r
PDF
Cyclopentadienyl Ruthenium, Rhodium, and Iridium Vertices in Metallaboranes: Geometry and Chemical Bonding
R. B. King
pp 4241 - 4247; DOI:
10.1021/ic030279v
PDF
Asymmetric Cationic Coordination Environments in New Oxide Materials: Synthesis and Characterization of Pb4Te6M10O41 (M = Nb5+ or Ta5+)
Kang Min Ok and P. Shiv Halasyamani
pp 4248 - 4253; DOI:
10.1021/ic049534h
PDF
Crystal Growth, Observation, and Characterization of the Low-Temperature Structure of the Fluorite-Related Ruthenates: Sm3RuO7 and Eu3RuO7
William R. Gemmill, Mark D. Smith, and Hans-Conrad zur Loye
pp 4254 - 4261; DOI:
10.1021/ic049700l
PDF
cis-[Ru(2,2':6',2' '-terpyridine)(DMSO)Cl2]: Useful Precursor for the Synthesis of Heteroleptic Terpyridine Complexes under Mild Conditions
Raymond Ziessel, Vincent Grosshenny, Muriel Hissler, and Christophe Stroh
pp 4262 - 4271; DOI:
10.1021/ic049822d
PDF
Lead and Thallium Tetrakis(imidazolyl)borates: Modifying Structure by Varying Metal and Anion
Barton H. Hamilton and Christopher J. Ziegler
pp 4272 - 4277; DOI:
10.1021/ic0497984
PDF
Copper(II) Complexes of a Series of Alkoxy Diazine Ligands: Mononuclear, Dinuclear, and Tetranuclear Examples with Structural, Magnetic, and DFT Studies
Hilde Grove, Timothy L. Kelly, Laurence K. Thompson, Liang Zhao, Zhiqiang Xu, Tareque S. M. Abedin, David O. Miller, Andrés E. Goeta, Claire Wilson, and Judith A. K. Howard
pp 4278 - 4288; DOI:
10.1021/ic040036i
PDF
Molecular Structure and Vibrational Spectra of Spin-Crossover Complexes in Solution and Colloidal Media: Resonance Raman and Time-Resolved Resonance Raman Studies
Clare Brady, Philip L. Callaghan, Zbigniew Ciunik, Colin G. Coates, Anders Dssing, Alan Hazell, John J. McGarvey, Sabine Schenker, Hans Toftlund, Alfred X. Trautwein, Heiner Winkler, and Juliusz A. Wolny
pp 4289 - 4299; DOI:
10.1021/ic049809t
PDF
Influence of the [2.1.1]-(2,6)-Pyridinophane Macrocycle Ring Size Constraint on the Structure and Reactivity of Copper Complexes
A. N. Vedernikov, M. Pink, and K. G. Caulton
pp 4300 - 4305; DOI:
10.1021/ic049886o
PDF
A Nonacoordinated Bridging Selenide in a Tricapped Trigonal Prismatic Geometry Identified in Undecanuclear Copper Clusters: Syntheses, Structures, and DFT Calculations
C. W. Liu, Chiu-Mine Hung, Bidyut Kumar Santra, Yi-Hua Chu, Ju-Chun Wang, and Zhenyang Lin
pp 4306 - 4314; DOI:
10.1021/ic049589j
PDF
(Salen)Tin Complexes: Syntheses, Characterization, Crystal Structures, and Catalytic Activity in the Formation of Propylene Carbonate from CO2 and Propylene Oxide
Huanwang Jing, Smita K. Edulji, Julianne M. Gibbs, Charlotte L. Stern, Hongying Zhou, and SonBinh T. Nguyen
pp 4315 - 4327; DOI:
10.1021/ic034855z
PDF
Modification of Binuclear Pt-Tl Bonded Complexes by Attaching Bipyridine Ligands to the Thallium Site
Guibin Ma, Mikael Kritikos, Mikhail Maliarik, and Julius Glaser
pp 4328 - 4340; DOI:
10.1021/ic034571e
PDF
NMR and EPR Spectroscopic and Structural Studies of Low-Spin, (dxz,dyz)4(dxy)1 Ground State Fe(III) Bis-tert-Butylisocyanide Complexes of Dodecasubstituted Porphyrins
Liliya A. Yatsunyk and F. Ann Walker
pp 4341 - 4352; DOI:
10.1021/ic035242p
PDF
Synthesis and Reactivity of Tris(imido)rhenium Complexes Containing Rhenium-Main Group Element Bonds. Silicon-Carbon Bond Activations of PhSiH3 by Silyl Complexes
John Gavenonis and T. Don Tilley
pp 4353 - 4362; DOI:
10.1021/ic030282e
PDF
Spectroscopic and Structural Study of Metal-Metal Bonded Metalloporphyrinic Derivatives: the Case of Rhodium-Indium
D. Daphnomili, C. Raptopoulou, A. Terzis, J.-H. Agondanou, S. Bénazeth, and A. G. Coutsolelos
pp 4363 - 4371; DOI:
10.1021/ic035155x
PDF
Six-Membered Metalla-coronands. Synthesis and Crystal Packing: Columns, Compartments, and 3D-Networks
Rolf W. Saalfrank, Christian Deutscher, Stefan Sperner, Takayuki Nakajima, Ayuk M. Ako, Eveline Uller, Frank Hampel, and Frank W. Heinemann
pp 4372 - 4382; DOI:
10.1021/ic049799w
PDF
Unusual Enlargment of Magnetic Interactions in the Lowest Excited States of Nitroxide Radical Chromium(III) Complexes as Revealed by Magnetic Circular Dichroism and Luminescence
Yasunori Tsukahara, Hiroyasu Nakata, and Sumio Kaizaki
pp 4383 - 4386; DOI:
10.1021/ic035226s
PDF
Silver Coordination Chemistry of a New Versatile "Janus"-type N2,O2-Bichelating Donor, Formation of an Unprecedented Supramolecular Network of Binuclear Silver Building Blocks Containing a Five-Coordinate -Diketonate, and Isolation of Unexpected Silver-Tin-Silver Heterotrimetallic Complexes from Silver Metathesis Reactions
Augusto Cingolani, Effendy, Fabio Marchetti, Claudio Pettinari, Riccardo Pettinari, Brian W. Skelton, and Allan H. White
pp 4387 - 4399; DOI:
10.1021/ic0497376
PDF
Zr7Sb4: A New Binary Zirconium-Rich Antimonide
Andriy V. Tkachuk and Arthur Mar
pp 4400 - 4405; DOI:
10.1021/ic040034y
PDF
Sulfur-Bridged CoIIIPtIICoIII Trinuclear Complexes with Mixed Aliphatic and Aromatic Thiolate Ligands: Effect of Nonbridging Ligands on the Homochiral Linkage of Cobalt(III) Octahedrons by Platinum(II)
Masakazu Hirotsu, Ryota Endo, Takashi Yoshimura, and Takumi Konno
pp 4406 - 4414; DOI:
10.1021/ic0303338
PDF
Controlled Redox Conversion of New X-ray-Characterized Mono- and Dinuclear Heptacoordinated Mn(II) Complexes into Di--oxo-dimanganese Core Complexes
Christelle Hureau, Sébastien Blanchard, Martine Nierlich, Guillaume Blain, Eric Rivière, Jean-Jacques Girerd, Elodie Anxolabéhère-Mallart, and Geneviève Blondin
pp 4415 - 4426; DOI:
10.1021/ic035332u
PDF
Catalytic Oxidative Ring Opening of THF Promoted by a Carboxylate-Bridged Diiron Complex, Triarylphosphines, and Dioxygen
Rayane F. Moreira, Edit Y. Tshuva, and Stephen J. Lippard
pp 4427 - 4434; DOI:
10.1021/ic049460+
PDF
A Series of Trinuclear CuIILnIIICuII Complexes Derived from 2,6-Di(acetoacetyl)pyridine: Synthesis, Structure, and Magnetism
Takuya Shiga, Masaaki Ohba, and Hisashi kawa
pp 4435 - 4446; DOI:
10.1021/ic034998l
PDF
Stabilization of Calcium- and Terbium-Carboxylate Bonds by NH···O Hydrogen Bonds in a Mononuclear Complex: A Functional Model of the Active Site of Calcium-Binding Proteins
Akira Onoda, Yusuke Yamada, Yoshiki Nakayama, Kazuyuki Takahashi, Hiroshi Adachi, Taka-aki Okamura, Akira Nakamura, Hitoshi Yamamoto, Norikazu Ueyama, Drahomir Vyprachticky, and Yoshi Okamoto
pp 4447 - 4455; DOI:
10.1021/ic035075t
PDF
Possible Role of Relativistic Effects in the Plasticity of the Coordination Geometry of Cadmium(II). A Voltammetric Study of the Stability of the Complexes of Cadmium(II) with 12-Crown-4,15-Crown-5 and 18-Crown-6 in Aqueous Solution and the Structures of [Cd(benzo-18-crown-6)(NCS)2] and [K(18-crown-6)][Cd(SCN)3]
James M. Harrington, S. Bart Jones, Peter H. White, and Robert D. Hancock
pp 4456 - 4463; DOI:
10.1021/ic049831m
PDF
New Halide-Centered Discrete AgI8 Cubic Clusters Containing Diselenophosphate Ligands, {Ag8(X)[Se2P(OR)2]6}(PF6) (X = Cl, Br; R = Et, Pr, iPr): Syntheses, Structures, and DFT Calculations
C. W. Liu, Hsien-Chung Haia, Chiu-Mine Hung, Bidyut Kumar Santra, Ben-Jie Liaw, Zhenyang Lin, and Ju-Chun Wang
pp 4464 - 4470; DOI:
10.1021/ic049533p
PDF
Energy Transfer Pathways in Dinuclear Heteroleptic Polypyridyl Complexes: Through-Space vs Through-Bond Interaction Mechanisms
Frances Weldon, Leif Hammarström, Emad Mukhtar, Ronald Hage, Eric Gunneweg, Jaap G. Haasnoot, Jan Reedijk, Wesley R. Browne, Adrian L. Guckian, and Johannes G. Vos
pp 4471 - 4481; DOI:
10.1021/ic049896p
PDF
Molecular Structures of Magnesium Dichloride Sheets and Nanoballs
Tommi N. P. Luhtanen, Mikko Linnolahti, and Tapani A. Pakkanen
pp 4482 - 4486; DOI:
10.1021/ic0499143
PDF
Photolabile Ruthenium Nitrosyls with Planar Dicarboxamide Tetradentate N4 Ligands: Effects of In-Plane and Axial Ligand Strength on NO Release
Apurba K. Patra, Michael J. Rose, Karen A. Murphy, Marilyn M. Olmstead, and Pradip K. Mascharak
pp 4487 - 4495; DOI:
10.1021/ic040030t
PDF
Electrochemistry of Metal Phthalocyanines in Organic Solvents at Variable Pressure
Bazhang Yu, A. B. P. Lever, and Thomas W. Swaddle
pp 4496 - 4504; DOI:
10.1021/ic040032d
PDF
Reduction and Oxidation of Hydroperoxo Rhodium(III) Complexes by Halides and Hypobromous Acid
Kelemu Lemma and Andreja Bakac
pp 4505 - 4510; DOI:
10.1021/ic049819u
PDF
Ruthenium Tris(pyrazolyl)borate Diazo Complexes: Preparation of Aryldiazenido, Aryldiazene, and Hydrazine Derivatives
Gabriele Albertin, Stefano Antoniutti, Marco Bortoluzzi, Jesus Castro-Fojo, and Soledad Garcia-Fontán
pp 4511 - 4522; DOI:
10.1021/ic0497275
PDF
Rhenium-to-Benzoylpyridine and Rhenium-to-Bipyridine MLCT Excited States of fac-[Re(Cl)(4-benzoylpyridine)2(CO)3] and fac-[Re(4-benzoylpyridine)(CO)3(bpy)]+: A Time-Resolved Spectroscopic and Spectroelectrochemical Study
Michael Busby, Pavel Matousek, Michael Towrie, Ian P. Clark, Majid Motevalli, Frantiek Hartl, and Antonín Vlek, Jr.
pp 4523 - 4530; DOI:
10.1021/ic049659m
PDF

Issue 15


Structural and Functional Analogue of the Active Site of Polysulfide Reductase from Wolinella succinogenes
Kowliki Nagarajan, Hemant K. Joshi, Pradeep K. Chaudhury, Kuntal Pal, J. Jon A. Cooney, John H. Enemark, and Sabyasachi Sarkar
pp 4532 - 4533; DOI:
10.1021/ic049665i
PDF
Structure and Magnetic Properties of the Ferromagnetic Cu3Cl126- Trimer in [(NH3C2H4)3NH]2Cu3Cl14
Mingyi Wei, Roger D. Willett, and Carlos J. Gómez-García
pp 4534 - 4536; DOI:
10.1021/ic040020s
PDF
Layered Organic-Based Metal Iodide-Polyiodide with Unique Mixed-Valent Gold(I/III) Iodide Chains
Laura M. Castro-Castro and Arnold M. Guloy
pp 4537 - 4539; DOI:
10.1021/ic049766g
PDF
Self-Assembly of High-Nuclearity Metal Clusters: Programmed Expansion of a Metallasiloxane Cage to an Octacopper(II) Cluster
Gian Luca Abbati, Andrea Cornia, Andrea Caneschi, Antonio C. Fabretti, and Cecilia Mortalò
pp 4540 - 4542; DOI:
10.1021/ic049898+
PDF
Hydrothermal Route to InAs Semiconductor Nanocrystals
Jun Lu, Shuo Wei, Weichao Yu, Houbo Zhang, and Yitai Qian
pp 4543 - 4545; DOI:
10.1021/ic049740p
PDF
Chelating of Titanium by Lactic Acid in the Water-Soluble Diammonium Tris(2-hydroxypropionato)titanate(IV)
M. Kakihana, K. Tomita, V. Petrykin, M. Tada, S. Sasaki, and Y. Nakamura
pp 4546 - 4548; DOI:
10.1021/ic040031l
PDF
An Unusual 3D Coordination Polymer Based on Bridging Interactions of the Nucleobase Adenine
Juan P. García-Terán, Oscar Castillo, Antonio Luque, Urko García-Couceiro, Pascual Román, and Luis Lezama
pp 4549 - 4551; DOI:
10.1021/ic049512v
PDF
[CoAu2(CN)4(NITpPy)2(H2O)2]n: A New 2-D Interdigitating Complex Containing Dicyanoaurate(I) Anion, a Radical, and Cobalt(II) Ion Incorporating Gold···Gold and Hydrogen Bonding Interactions
Hui-Bo Zhou, Shu-Ping Wang, Wen Dong, Zhan-Quan Liu, Qing-Lun Wang, Dai-Zheng Liao, Zong-Hui Jiang, Shi-Ping Yan, and Peng Cheng
pp 4552 - 4554; DOI:
10.1021/ic049751i
PDF
7Li PGSE Diffusion Measurements on LiPPh2: A Solvent Dependence of the Structure
Ignacio Fernández, Eloísa Martínez-Viviente, and Paul S. Pregosin
pp 4555 - 4557; DOI:
10.1021/ic049703y
PDF
Dicopper-Dioxygen Complex Supported by Asymmetric Pentapyridine Dinucleating Ligand
Yoshimitsu Tachi, Kazuki Aita, Shinichi Teramae, Fumito Tani, Yoshinori Naruta, Shunichi Fukuzumi, and Shinobu Itoh
pp 4558 - 4560; DOI:
10.1021/ic049524g
PDF
Supramolecular and Coordination Polymer Complexes Supported by a Tripodal Tripyridine Ligand Containing a 1,3,5-Triethylbenzene Spacer
Hiromi Ohi, Yoshimitsu Tachi, and Shinobu Itoh
pp 4561 - 4563; DOI:
10.1021/ic049468j
PDF
Structure and Bonding in the Omnicapped Truncated Tetrahedral Au20 Cluster: Analogies between Gold and Carbon Cluster Chemistry
R. Bruce King, Zhongfang Chen, and Paul von Ragué Schleyer
pp 4564 - 4566; DOI:
10.1021/ic049628r
PDF
Triethanolamine Zinc Phosphite, (C6H13NO3)Zn2(HPO3): A Templated Network or a Network of Clusters?
Jillian A. Johnstone and William T. A. Harrison
pp 4567 - 4569; DOI:
10.1021/ic0495012
PDF
[Ru(bpy)2(L)]Cl2: Luminescent Metal Complexes That Bind DNA Base Mismatches
Eva Rüba, Jonathan R. Hart, and Jacqueline K. Barton
pp 4570 - 4578; DOI:
10.1021/ic0499291
PDF
Determination by X-ray Absorption Spectroscopy of the Fe-Fe Separation in the Oxidized Form of the Hydroxylase of Methane Monooxygenase Alone and in the Presence of MMOD
Deanne Jackson Rudd, Matthew H. Sazinsky, Maarten Merkx, Stephen J. Lippard, Britt Hedman, and Keith O. Hodgson
pp 4579 - 4589; DOI:
10.1021/ic049716b
PDF
An Unprecedented Trinuclear Structure Involving Two High-Spin and One Spin-Crossover Iron(II) Centers
George Psomas, Nicolas Bréfuel, Françoise Dahan, and Jean-Pierre Tuchagues
pp 4590 - 4594; DOI:
10.1021/ic049877f
PDF
Syntheses of the 47 Electron Clusters [(Cp*Fe)3(3-X)2] (X = S, Se) and the First Fe/Sn/Se Heterocubane Cluster [(Cp*Fe)3(SnCl3)(3-Se)4]·DME by the Use of Chalcogenostannate Salts
Christian Zimmermann, Christopher E. Anson, Amanda L. Eckermann, Markus Wunder, Gerda Fischer, Ilka Keilhauer, Erik Herrling, Bernd Pilawa, Oliver Hampe, Florian Weigend, and Stefanie Dehnen
pp 4595 - 4603; DOI:
10.1021/ic034876t
PDF
Composition-Structure Relationships in Polar Intermetallics: Experimental and Theoretical Studies of LaNi1+xAl6-x (x = 0.44)
Delphine Gout, Evan Benbow, Olivier Gourdon, and Gordon J. Miller
pp 4604 - 4609; DOI:
10.1021/ic0497331
PDF
Hydrothermal Synthesis and Characterization of New Pillared Layered Ethylenediphosphonates of Molybdenum(VI), A2[Mo2O5(O3PCH2CH2PO3)] (A = NH4, Tl, Cs, Rb) and K(H3O)[Mo2O5(O3PCH2CH2PO3)]
K. Prabhakara Rao, Vidyavathy Balraj, M. P. Minimol, and K. Vidyasagar
pp 4610 - 4614; DOI:
10.1021/ic035081p
PDF
Perovskite-like Metal Formates with Weak Ferromagnetism and as Precursors to Amorphous Materials
Xin-Yi Wang, Lin Gan, Shi-Wei Zhang, and Song Gao
pp 4615 - 4625; DOI:
10.1021/ic0498081
PDF
Attachment of an Electron-Withdrawing Fluorophore to a Cryptand for Modulation of Fluorescence Signaling
Bamaprasad Bag and Parimal K. Bharadwaj
pp 4626 - 4630; DOI:
10.1021/ic049725k
PDF
Two Polymorphs of Cobalt(II) Imidazolate Polymers Synthesized Solvothermally by Using One Organic Template N,N-Dimethylacetamide
Yun-Qi Tian, Zhen-Xia Chen, Lin-Hong Weng, Hui-Bin Guo, Song Gao, and Dong Yuan Zhao
pp 4631 - 4635; DOI:
10.1021/ic049713z
PDF
Preparation and Characterization of 6-Molybdocobaltate and 6-Molybdoaluminate Cobalt Salts. Evidence of a New Heteropolymolybdate Structure
Catherine Martin, Carole Lamonier, Michel Fournier, Olivier Mentré, Virginie Harlé, Denis Guillaume, and Edmond Payen
pp 4636 - 4644; DOI:
10.1021/ic0354365
PDF
The Coordination Chemistry of "[BP3]NiX" Platforms: Targeting Low-Valent Nickel Sources as Promising Candidates to L3Ni=E and L3NiE Linkages
Cora E. MacBeth, J. Christopher Thomas, Theodore A. Betley, and Jonas C. Peters
pp 4645 - 4662; DOI:
10.1021/ic049936p
PDF
The Activation of Tertiary Carboxamides in Metal Complexes: An Experimental and Theoretical Study on the Methanolysis of Acylated Bispicolylamine Copper(II) Complexes
Nicole Niklas, Frank W. Heinemann, Frank Hampel, Tim Clark, and Ralf Alsfasser
pp 4663 - 4673; DOI:
10.1021/ic0496774
PDF
Cobalt Chemistry with Mixed Aminotroponiminate Salicylaldiminate Ligands: Synthesis, Characterization, and Nitric Oxide Reactivity
Scott A. Hilderbrand and Stephen J. Lippard
pp 4674 - 4682; DOI:
10.1021/ic049776h
PDF
Model of the Iron Hydrogenase Active Site Covalently Linked to a Ruthenium Photosensitizer: Synthesis and Photophysical Properties
Sascha Ott, Magnus Borgström, Mikael Kritikos, Reiner Lomoth, Jonas Bergquist, Björn Åkermark, Leif Hammarström, and Licheng Sun
pp 4683 - 4692; DOI:
10.1021/ic0303385
PDF
Binuclear Copper(I) Macrocycles Synthesized via the Weak-Link Approach
Martin S. Masar III, Chad A. Mirkin, Charlotte L. Stern, Lev N. Zakharov, and Arnold L. Rheingold
pp 4693 - 4701; DOI:
10.1021/ic049658u
PDF
Sensing of Sulfur Dioxide by Base Metal Thiolates: Structures and Properties of Molecular NiN2S2/SO2 Adducts
Melissa L. Golden, Jason C. Yarbrough, Joseph H. Reibenspies, and Marcetta Y. Darensbourg
pp 4702 - 4707; DOI:
10.1021/ic049387n
PDF
XAFS and LIBD Investigation of the Formation and Structure of Colloidal Pu(IV) Hydrolysis Products
Jörg Rothe, Clemens Walther, Melissa A. Denecke, and Th. Fanghänel
pp 4708 - 4718; DOI:
10.1021/ic049861p
PDF
Crescent-Shaped Rhodium(I) Complexes with Bis(o-carboxymethylphenyl)triazenide
Cristina Tejel, Miguel A. Ciriano, Gustavo Ríos-Moreno, Isabel T. Dobrinovitch, Fernando J. Lahoz, Luis A. Oro, and Miguel Parra-Hake
pp 4719 - 4726; DOI:
10.1021/ic049691g
PDF
Syntheses and Structures of Ag(I)-Containing Coordination Polymers and Co(II)-Containing Supramolecular Complex Based on Novel Fulvene Ligands
Yu-Bin Dong, Peng Wang, Ru-Qi Huang, and Mark D. Smith
pp 4727 - 4739; DOI:
10.1021/ic0495517
PDF
The First Slipped Pseudo-Quadruple-Decker Complex of Phthalocyanines
Hongchuan Zhang, Rongmin Wang, Peihua Zhu, Zefeng Lai, Juan Han, Chi-Fung Choi, Dennis K. P. Ng, Xuegui Cui, Changqin Ma, and Jianzhuang Jiang
pp 4740 - 4742; DOI:
10.1021/ic049705i
PDF
Synthesis, Structures, and Physical Properties of Copper(II)-Gadolinium(III) Complexes Combining Ferromagnetic Coupling and Quadratic Nonlinear Optical Properties
Olivier Margeat, Pascal G. Lacroix, Jean Pierre Costes, Bruno Donnadieu, Christine Lepetit, and Keitaro Nakatani
pp 4743 - 4750; DOI:
10.1021/ic049801j
PDF
Phase Stability in the Systems AeAl2-xMgx (Ae = Ca, Sr, Ba): Electron Concentration and Size Controlled Variations on the Laves Phase Structural Theme
Shahrad Amerioun, Tadahiro Yokosawa, Sven Lidin, and Ulrich Häussermann
pp 4751 - 4760; DOI:
10.1021/ic0400235
PDF
Oxidative DNA Strand Scission Induced by a Trinuclear Copper(II) Complex
Chao Tu, Ying Shao, Ning Gan, Qiang Xu, and Zijian Guo
pp 4761 - 4766; DOI:
10.1021/ic049731g
PDF
Novel One-Dimensional Polymers Generated from p-Ferrocenylbenzoate: Syntheses, Structures, and Magnetic Properties
Hongwei Hou, Linke Li, Yu Zhu, Yaoting Fan, and Yuqin Qiao
pp 4767 - 4774; DOI:
10.1021/ic049728x
PDF

Issue 16


Construction of a Novel Mo/Cu/S Cluster with a Closed Double-Cubane-like Polyhedron and a Chain Polymer of W/Cu/S Clusters
Zhihua Li, Shaowu Du, and Xintao Wu
pp 4776 - 4777; DOI:
10.1021/ic049587z
PDF
Control of Oxygen Atom Chirality and Chelate Ring Conformation by Protected/Free Sugar Hydroxyl Groups in Glucose-Pendant Dipicolylamine-Copper(II) Complexes
Yuji Mikata, Yuko Sugai, and Shigenobu Yano
pp 4778 - 4780; DOI:
10.1021/ic0496323
PDF
Structural Characterization and Luminescence Behavior of a Silver(I) 1D Polymeric Chain Constructed via a Bridge with Unusual 4,5-Diazospirobifluorene and Perchlorate
Chih-Chieh Wang, Cheng-Han Yang, Shih-Min Tseng, Sue-Yi Lin, Ti-Yu Wu, Ming-Ren Fuh, Gene-Hsiang Lee, Ken-Tsung Wong, Ruei-Tang Chen, Yi-Ming Cheng, and Pi-Tai Chou
pp 4781 - 4783; DOI:
10.1021/ic0351794
PDF
[NH4]2Mn3(H2O)4[Mo(CN)7]2·4H2O: Tuning Dimensionality and Ferrimagnetic Ordering Temperature by Cation Substitution
Xavier F. Le Goff, Stéphanie Willemin, Claude Coulon, Joulia Larionova, Bruno Donnadieu, and Rodolphe Clérac
pp 4784 - 4786; DOI:
10.1021/ic049513n
PDF
A Novel 4-Oxo Bridged Copper Tetrahedron Derived by Self-Assembly: First Example of Double Helical Bis(Tridentate) Coordination of a Hexadentate Amine Phenol Ligand
Manindranath Bera, Wing Tak Wong, Guillem Aromi, Joan Ribas, and Debashis Ray
pp 4787 - 4789; DOI:
10.1021/ic049817+
PDF
A Mn12 Single-Molecule Magnet [Mn12O12(OAc)12(dpp)4] (dppH = Diphenyl Phosphate) with No Coordinating Water Molecules
Guo-Qing Bian, Takayoshi Kuroda-Sowa, Hisashi Konaka, Masaki Hatano, Masahiko Maekawa, Megumu Munakata, Hitoshi Miyasaka, and Masahiro Yamashita
pp 4790 - 4792; DOI:
10.1021/ic049306n
PDF
Comparison of Cysteine and Penicillamine Ligands in a Co(II) Maquette
Amy K. Petros, Sarah E. Shaner, Alison L. Costello, David L. Tierney, and Brian R. Gibney
pp 4793 - 4795; DOI:
10.1021/ic0497679
PDF
Synthesis of Novel Amorphous Boron Carbonitride Ceramics from the Borazine Derivative Copolymer via Hydroboration
Jong-Kyu Jeon, Yuko Uchimaru, and Dong-Pyo Kim
pp 4796 - 4798; DOI:
10.1021/ic035254a
PDF
Reaction of AgN3 with SOCl2: Evidence for the Formation of Thionyl Azide, SO(N3)2
Zeng Xiaoqing, Liu Fengyi, Sun Qiao, Ge Maofa, Zhang Jianping, Ai Xicheng, Meng Lingpeng, Zheng Shijun, and Wang Dianxun
pp 4799 - 4801; DOI:
10.1021/ic049442s
PDF
Coordination Chemistry of Diselenophosphinate Complexes: The X-ray Single-Crystal Structures of [K(Se2PPh2)(THF)2]2 and [In(Se2PPh2)3]·L (L = THF, PhMe)
Robert P. Davies, Claire V. Francis, Andrew P. S. Jurd, M. Giovanna Martinelli, Andrew J. P. White, and David J. Williams
pp 4802 - 4804; DOI:
10.1021/ic049567x
PDF
Kinetics Evidence for a Complex between Peroxynitrous Acid and Titanium(IV)
Patrick K. Wick, Reinhard Kissner, and Willem H. Koppenol
pp 4805 - 4807; DOI:
10.1021/ic049870y
PDF
Incommensurate Nature of the Multilayered Molecular Ferromagnetic Metals Based on Bis(ethylenedithio)tetrathiafulvalene and Bimetallic Oxalate Complexes
Eugenio Coronado, José R. Galán-Mascarós, Carlos J. Gómez-García, Eugenia Martínez-Ferrero, and Sander van Smaalen
pp 4808 - 4810; DOI:
10.1021/ic049424a
PDF
Grid-Type Two-Dimensional Magnetic Multinuclear Metal Complex: Strands of {[CuII(-4,4'-bpy)]2+}n Cross-Linked by Octacyanotungstate(V) Ions
Tomasz Korzeniak, Katarzyna Stadnicka, Micha Rams, and Barbara Sieklucka
pp 4811 - 4813; DOI:
10.1021/ic049402o
PDF
Unprecedented Migration of a Methyl Group in 2-(2',6'-Dimethylphenylazo)-4-methylphenol Mediated by Ruthenium
Sumon Nag, Parna Gupta, Ray J. Butcher, and Samaresh Bhattacharya
pp 4814 - 4816; DOI:
10.1021/ic049494h
PDF
Chiral Induction in a Ribose-Decorated Metallostar through Intrinsic and Interionic Diastereomeric Interactions
Edwin C. Constable, Richard Frantz, Catherine E. Housecroft, Jérôme Lacour, and Azad Mahmood
pp 4817 - 4819; DOI:
10.1021/ic049392r
PDF
Imine Hydrolysis and Role of a Rhodium(I)-Imine-Amine Complex in Homogeneous H2-Hydrogenation of the Imine and a Rare Example of Inequivalent NH2 Protons
Paolo Marcazzan, Chalil Abu-Gnim, Kapila N. Seneviratne, and Brian R. James
pp 4820 - 4824; DOI:
10.1021/ic040037a
PDF
Synthesis, Structural, Spectroscopic, and Electrochemical Characterization of High Oxidation State Diruthenium Complexes Containing Four Identical Unsymmetrical Bridging Ligands
Karl M. Kadish, Tuan D. Phan, Li-Lun Wang, Lingamallu Giribabu, Antoine Thuriere, Julien Wellhoff, Shurong Huang, Eric Van Caemelbecke, and John L. Bear
pp 4825 - 4832; DOI:
10.1021/ic0499594
PDF
New Compounds from Tellurocyanide Rhenium Cluster Anions and 3d-Transition Metal Cations Coordinated with Ethylenediamine
Konstantin A. Brylev, Yuri V. Mironov, Nikolai G. Naumov, Vladimir E. Fedorov, and James A. Ibers
pp 4833 - 4838; DOI:
10.1021/ic040046j
PDF
Two Series of Novel Rare Earth Complexes with Dicyanamide [Ln(dca)2(phen)2(H2O)3][dca]·(phen), (Ln = Pr, Gd, and Sm) and [Ln(dca)3(2,2'-bipy)2(H2O)]n, (Ln = Gd, Sm, and La): Syntheses, Crystal Structures, and Magnetic Properties
A-Qing Wu, Fa-Kun Zheng, Wen-Tong Chen, Li-Zhen Cai, Guo-Cong Guo, Jin-Shun Huang, Zhen-Chao Dong, and Yoshihiko Takano
pp 4839 - 4845; DOI:
10.1021/ic035470j
PDF
Mechanism of Abstraction Reactions of Dimetallenes (R2X=XR2; X = C, Si, Ge, Sn, Pb) with Halocarbons: A Theoretical Study
Ming-Der Su
pp 4846 - 4861; DOI:
10.1021/ic0303340
PDF
Theoretical Analysis of the Jahn-Teller Distortions in Tetrathiolato Iron(II) Complexes
Vladislav V. Vrajmasu, Eckard Münck, and Emile L. Bominaar
pp 4862 - 4866; DOI:
10.1021/ic0400484
PDF
Theoretical Analysis of the Three-Dimensional Structure of Tetrathiolato Iron Complexes
Vladislav V. Vrajmasu, Eckard Münck, and Emile L. Bominaar
pp 4867 - 4879; DOI:
10.1021/ic040049w
PDF
Nonexponential Relaxation of the Metastable State of the Spin-Crossover System [Fe(L)2](ClO4)2·H2O [L = 2,6-Bis(pyrazol-1-ylmethyl)pyridine]
Cristian Enachescu, Jorge Linares, François Varret, Kamel Boukheddaden, Epiphane Codjovi, Sunita Gawali Salunke, and Rabindranath Mukherjee
pp 4880 - 4888; DOI:
10.1021/ic049938+
PDF
N-Methylmonothiocarbamatopentamminecobalt(III): Restricted C-N Bond Rotation and the Acid-Catalyzed O- to S-Bonded Rearrangement
W. Gregory Jackson, Josephine Anne McKeon, and Robert J. Balahura
pp 4889 - 4896; DOI:
10.1021/ic040047b
PDF
4-Cyanoimidazolate: A New Pseudo-Cyanide?
Gregory B. Less, Jeff W. Kampf, and Paul G. Rasmussen
pp 4897 - 4902; DOI:
10.1021/ic049434b
PDF
Ytterbium and Samarium Bis(diphosphanylamides): Syntheses and Structures of Lanthanide Complexes Having Two {(Ph2P)2N}- Ligands in the Coordination Sphere
Michael T. Gamer and Peter W. Roesky
pp 4903 - 4906; DOI:
10.1021/ic049437o
PDF
Resonance Raman Detection of the Fe2+-C-N Modes in Heme-Copper Oxidases: A Probe of the Active Site
Eftychia Pinakoulaki, Magdalini Vamvouka, and Constantinos Varotsis
pp 4907 - 4910; DOI:
10.1021/ic035216r
PDF
Diruthenium Complexes [{(acac)2RuIII}2(-OC2H5)2], [{(acac)2RuIII}2(-L)](ClO4)2, and [{(bpy)2RuII}2(-L)](ClO4)4 [L = (NC5H4)2-N-C6H4-N-(NC5H4)2, acac = Acetylacetonate, and bpy = 2,2'-Bipyridine]. Synthesis, Structure, Magnetic, Spectral, and Photophysical Aspects
Sanjib Kar, Nripen Chanda, Shaikh M. Mobin, Anindya Datta, Francisco A. Urbanos, Vedavati G. Puranik, Reyes Jimenez-Aparicio, and Goutam Kumar Lahiri
pp 4911 - 4920; DOI:
10.1021/ic0498900
PDF
Chiral Bisphosphinite Metalloligands Derived from a P-Chiral Secondary Phosphine Oxide
Eddie Y. Y. Chan, Qian-Feng Zhang, Yiu-Keung Sau, Samuel M. F. Lo, Herman H. Y. Sung, Ian D. Williams, Richard K. Haynes, and Wa-Hung Leung
pp 4921 - 4926; DOI:
10.1021/ic049744u
PDF
Cobalt Half-Sandwich, Sandwich, and Mixed Sandwich Complexes with Soft Tripodal Ligands
Christopher A. Dodds, Mario-Alexander Lehmann, Jonathan F. Ojo, John Reglinski, and Mark D. Spicer
pp 4927 - 4934; DOI:
10.1021/ic0496525
PDF
Coordination of 9-Ethylguanine to the Mixed-Ligand Compound -[Ru(azpy)(bpy)Cl2] (azpy = 2-Phenylazopyridine and bpy = 2,2'-Bipyridine). An Unprecedented Ligand Positional Shift, Correlated to the Cytotoxicity of This Type of [RuL2Cl2] (with L = azpy or bpy) Complex
Anna C. G. Hotze, Erwin P. L. van der Geer, Sabrine E. Caspers, Huub Kooijman, Anthony L. Spek, Jaap G. Haasnoot, and Jan Reedijk
pp 4935 - 4943; DOI:
10.1021/ic035390f
PDF
Density Functional Study of Ammonia Activation by Late First-Row Transition Metal Cations
Maria del Carmen Michelini, Nino Russo, and Emilia Sicilia
pp 4944 - 4952; DOI:
10.1021/ic049696d
PDF
Coordination Networks through the Dimensions: From Discrete Clusters to 1D, 2D, and 3D Silver(I) Coordination Polymers with Rigid Aliphatic Amino Ligands
Alexandra L. Pickering, De-Liang Long, and Leroy Cronin
pp 4953 - 4961; DOI:
10.1021/ic049786i
PDF
Analysis of Low Oxidation State Transition Metal Clusters by Laser Desorption/Ionization Time-of-Flight Mass Spectrometry
Paul J. Dyson, Andrew K. Hearley, Brian F. G. Johnson, Patrick R. R. Langridge-Smith, and J. Scott McIndoe
pp 4962 - 4973; DOI:
10.1021/ic049458i
PDF
Investigation of the Electronic and Structural Properties of Potassium Hexaboride, KB6, by Transport, Magnetic Susceptibility, EPR, and NMR Measurements, Temperature-Dependent Crystal Structure Determination, and Electronic Band Structure Calculations
A. Ammar, M. Ménétrier, A. Villesuzanne, S. Matar, B. Chevalier, J. Etourneau, G. Villeneuve, J. Rodríguez-Carvajal, H.-J. Koo, A. I. Smirnov, and M.-H. Whangbo
pp 4974 - 4987; DOI:
10.1021/ic049444c
PDF
Synthesis, Structure, and Bonding of BaAuTl3 and BaAuIn3: Stabilization of BaAl4-Type Examples of the Heavier Triels through Gold Substitution
Shengfeng Liu and John D. Corbett
pp 4988 - 4993; DOI:
10.1021/ic040010r
PDF
Excited-State Dynamics of fac-[ReI(L)(CO)3(phen)]+ and fac-[ReI(L)(CO)3(5-NO2-phen)]+ (L = Imidazole, 4-Ethylpyridine; Phen = 1,10-Phenanthroline) Complexes
Michael Busby, Anders Gabrielsson, Pavel Matousek, Michael Towrie, Angel J. Di Bilio, Harry B. Gray, and Antonín Vlek, Jr.
pp 4994 - 5002; DOI:
10.1021/ic035471b
PDF
Application of a Universal Force Field to Mixed Fe/Mo-S/Se Cubane and Heterocubane Clusters. 1. Substitution of Sulfur by Selenium in the Series [Fe4X4(YCH3)4]2-; X = S/Se and Y = S/Se
Axel Kern, Christian Näther, Felix Studt, and Felix Tuczek
pp 5003 - 5010; DOI:
10.1021/ic030347d
PDF
Application of a Universal Force Field to Mixed Fe/Mo-S/Se Cubane and Heterocubane Clusters. 2. Substitution of Iron by Molybdenum in Fe4(S/Se)4 Clusters with Terminal Halide and Thiolate Ligands
Axel Kern, Christian Näther, and Felix Tuczek
pp 5011 - 5020; DOI:
10.1021/ic030346l
PDF
Acidic Aqueous Decomposition of Thiocyanogen
Jon J. Barnett, Michael L. McKee, and David M. Stanbury
pp 5021 - 5033; DOI:
10.1021/ic049356s
PDF
Electronic Structures of Five-Coordinate Iron(III) Porphyrin Complexes with Highly Ruffled Porphyrin Ring
Takanori Sakai, Yoshiki Ohgo, Akito Hoshino, Takahisa Ikeue, Takashi Saitoh, Masashi Takahashi, and Mikio Nakamura
pp 5034 - 5043; DOI:
10.1021/ic049825q
PDF
Probing the Limits of the Zintl Concept: Structure and Bonding in Rare-Earth and Alkaline-Earth Zinc-Antimonides Yb9Zn4+xSb9 and Ca9Zn4.5Sb9
Svilen Bobev, Joe D. Thompson, John L. Sarrao, Marilyn M. Olmstead, Håkon Hope, and Susan M. Kauzlarich
pp 5044 - 5052; DOI:
10.1021/ic049836j
PDF
Synthesis and Characterization of a New Family of Bi-, Tri-, Tetra-, and Pentanuclear Ferric Complexes
Colette Boskovic, Andreas Sieber, Grégory Chaboussant, Hans U. Güdel, Jürgen Ensling, Wolfgang Wernsdorfer, Antonia Neels, Gael Labat, Helen Stoeckli-Evans, and Stefan Janssen
pp 5053 - 5068; DOI:
10.1021/ic049600f
PDF
Electronic Factors Affecting Second-Order NLO Properties: Case Study of Four Different Push-Pull Bis-Dithiolene Nickel Complexes
Simona Curreli, Paola Deplano, Christophe Faulmann, Andrea Ienco, Carlo Mealli, Maria Laura Mercuri, Luca Pilia, Gloria Pintus, Angela Serpe, and Emanuele F. Trogu
pp 5069 - 5079; DOI:
10.1021/ic0496469
PDF
Electrochemical Determination of Triple Helices: Electrocatalytic Oxidation of Guanine in an Intramolecular Triplex
Rebecca C. Holmberg and H. Holden Thorp
pp 5080 - 5085; DOI:
10.1021/ic049895x
PDF
Organic Cross-Linked Electropolymers as Supported Oxidation Catalysts: Poly((tetrakis(9,9'-spirobifluorenyl)porphyrin)manganese) Films
Cyril Poriel, Yann Ferrand, Paul Le Maux, Joëlle Rault-Berthelot, and Gérard Simonneaux
pp 5086 - 5095; DOI:
10.1021/ic049641b
PDF
Synthesis, Crystal Structure, and Luminescent Properties of a Binuclear Gallium Complex with Mixed Ligands
Juan Qiao, Li D. Wang, Lian Duan, Yang Li, De Q. Zhang, and Yong Qiu
pp 5096 - 5102; DOI:
10.1021/ic049603s
PDF
Emitting-State Displacements in Ligand-Centered Vibrational Modes in the trans-[OsO2(NCS)4]2- Complex Determined from Near-Infrared Luminescence Spectroscopy
John K. Grey, Ian S. Butler, and Christian Reber
pp 5103 - 5111; DOI:
10.1021/ic049840v
PDF
Ruthenium(II) Dipyridoquinoxaline-Norbornene: Synthesis, Properties, Crystal Structure, and Use as a ROMP Monomer
Ali Rezvani, Hassan S. Bazzi, Bingzhi Chen, Felaniaina Rakotondradany, and Hanadi F. Sleiman
pp 5112 - 5119; DOI:
10.1021/ic0498438
PDF
Selective Dehydrogenation of Amines with Respect to Coordination Geometry: Different Oxidation Products of Tricyano[bis(2-pyridylmethyl)amine]ferrate(II) between mer- and fac-Isomers
Masafumi Goto, Nobuhiro Koga, Yasuhiko Ohse, Yuka Kudoh, Michiko Kukihara, Yoshinori Okuno, and Hiromasa Kurosaki
pp 5120 - 5127; DOI:
10.1021/ic035289a
PDF
Mixed Valence Aspects of Diruthenium Complexes [{(L)ClRu}2(-tppz)]n+ Incorporating 2-(2-Pyridyl)azoles (L) as Ancillary Functions and 2,3,5,6-Tetrakis(2-pyridyl)pyrazine (Tppz) as Bis-Tridentate Bridging Ligand
Nripen Chanda, Biprajit Sarkar, Sanjib Kar, Jan Fiedler, Wolfgang Kaim, and Goutam Kumar Lahiri
pp 5128 - 5133; DOI:
10.1021/ic049605c
PDF
New Terpyridine-Containing Macrocycle for the Assembly of Dimeric Zn(II) and Cu(II) Complexes Coupled by Bridging Hydroxide Anions and -Stacking Interactions
Carla Bazzicalupi, Andrea Bencini, Emanuela Berni, Antonio Bianchi, Andrea Danesi, Claudia Giorgi, Barbara Valtancoli, Carlos Lodeiro, João Carlos Lima, Fernando Pina, and M. Alexandra Bernardo
pp 5134 - 5146; DOI:
10.1021/ic049660l
PDF
Comparative Structural Studies of Iodide Complexes of Uranium(III) and Lanthanide(III) with Hexadentate Tetrapodal Neutral N-Donor Ligands
Lydia Karmazin, Marinella Mazzanti, Jean-Philippe Bezombes, Christelle Gateau, and Jacques Pécaut
pp 5147 - 5158; DOI:
10.1021/ic049538m
PDF
Photochemistry of the Dinitrosyl Iron Complex [S5Fe(NO)2]- Leading to Reversible Formation of [S5Fe(-S)2FeS5]2-: Spectroscopic Characterization of Species Relevant to the Nitric Oxide Modification and Repair of [2Fe-2S] Ferredoxins
Ming-Li Tsai, Chiao-Chun Chen, I-Jui Hsu, Shyue-Chu Ke, Chung-Hung Hsieh, Kuo-An Chiang, Gene-Hsiang Lee, Yu Wang, Jin-Ming Chen, Jyh-Fu Lee, and Wen-Feng Liaw
pp 5159 - 5167; DOI:
10.1021/ic0494915
PDF
Structural Consequences of the Prohibition of Hydrogen Bonding in Copper-Guanidine Systems
Sarah H. Oakley, Martyn P. Coles, and Peter B. Hitchcock
pp 5168 - 5172; DOI:
10.1021/ic0495970
PDF

Issue 17


Octanuclear Metallocyclic Ni4Fc4 Compound: Synthesis, Crystal Structure, and Electrochemical Sensing for Mg2+
Mingxue Li, Ping Cai, Chunying Duan, Feng Lu, Jin Xie, and Qingjin Meng
pp 5174 - 5176; DOI:
10.1021/ic049530c
PDF
The Cation as a Tool to Get Spin-Canted Three-Dimensional Iron(III) Networks
Donatella Armentano, Giovanni De Munno, Teresa F. Mastropietro, Davide M. Proserpio, Miguel Julve, and Francesc Lloret
pp 5177 - 5179; DOI:
10.1021/ic049345z
PDF
Puckered-Boat Conformation Hexameric Water Clusters Stabilized in a 2D Metal-Organic Framework Structure Built from Cu(II) and 1,2,4,5-Benzenetetracarboxylic Acid
Sujit K. Ghosh and Parimal K. Bharadwaj
pp 5180 - 5182; DOI:
10.1021/ic049739q
PDF
Highly Selective Chromogenic Signaling of Hg2+ in Aqueous Media at Nanomolar Levels Employing a Squaraine-Based Reporter
Jose V. Ros-Lis, Ramón Martínez-Máñez, Knut Rurack, Félix Sancenón, Juan Soto, and Monika Spieles
pp 5183 - 5185; DOI:
10.1021/ic049422q
PDF
Electrical Properties of Single-Crystalline CaAl2Si2
Motoharu Imai, Hideki Abe, and Kei Yamada
pp 5186 - 5188; DOI:
10.1021/ic049720n
PDF
Ferromagnetic Coupling through Spin Polarization in the Hexanuclear [MnII3CuII3] Complex
Mirela Pascu, Francesc Lloret, Narcis Avarvari, Miguel Julve, and Marius Andruh
pp 5189 - 5191; DOI:
10.1021/ic0493651
PDF
Targeted Ferromagnetic Coupling in a Trinuclear Copper(II) Complex: Analysis of the St = 3/2 Spin Ground State
Thorsten Glaser, Maik Heidemeier, Stefan Grimme, and Eckhard Bill
pp 5192 - 5194; DOI:
10.1021/ic049252h
PDF
A Luminescent Chemosensor with Specific Response for Mg2+
Qing-Zheng Yang, Li-Zhu Wu, He Zhang, Bin Chen, Zi-Xin Wu, Li-Ping Zhang, and Chen-Ho Tung
pp 5195 - 5197; DOI:
10.1021/ic049815p
PDF
Radical Autoxidation and Autogenous O2 Evolution in Manganese-Porphyrin Catalyzed Alkane Oxidations with Chlorite
LeGrande M. Slaughter, James P. Collman, Todd A. Eberspacher, and John I. Brauman
pp 5198 - 5204; DOI:
10.1021/ic049922j
PDF
Stepwise Oxidation of Anilines by cis-[RuIV(bpy)2(py)(O)]2+
Won K. Seok and Thomas J. Meyer
pp 5205 - 5215; DOI:
10.1021/ic0302985
PDF
Kinetics and Mechanism of Platinum-Thallium Bond Formation: The Binuclear [(CN)5Pt-Tl(CN)]- and the Trinuclear [(CN)5Pt-Tl-Pt(CN)5]3- Complex
Péter Nagy, Imre Tóth, István Fábián, Mikhail Maliarik, and Julius Glaser
pp 5216 - 5221; DOI:
10.1021/ic049867e
PDF
Versatile Chelating Behavior of Benzil Bis(thiosemicarbazone) in Zinc, Cadmium, and Nickel Complexes
Elena López-Torres, M Antonia Mendiola, César J. Pastor, and Beatriz Souto Pérez
pp 5222 - 5230; DOI:
10.1021/ic035461a
PDF
A Large Thermal Hysteresis Loop Produced by a Charge-Transfer Phase Transition in a Rubidium Manganese Hexacyanoferrate
Hiroko Tokoro, Shin-ichi Ohkoshi, Tomoyuki Matsuda, and Kazuhito Hashimoto
pp 5231 - 5236; DOI:
10.1021/ic030332f
PDF
On the Mechanism of Dioxygen Formation from a Di--Oxo-Bridged Manganese Dinuclear Complex
Simon Petrie and Robert Stranger
pp 5237 - 5244; DOI:
10.1021/ic049967k
PDF
High Pressure Study of Ru3(CO)12 by X-ray Diffraction, Raman, and Infrared Spectroscopy
Carla Slebodnick, Jing Zhao, Ross Angel, Brian E. Hanson, Yang Song, Zhenxian Liu, and Russell J. Hemley
pp 5245 - 5252; DOI:
10.1021/ic049617y
PDF
Preparation of CH3TiF and (CH3)2TiF2 from the Reaction of CH3F with Laser-Ablated Ti Atoms
Han-Gook Cho and Lester Andrews
pp 5253 - 5257; DOI:
10.1021/ic049342m
PDF
New Riches in Carbaporphyrin Chemistry: Silver and Gold Organometallic Complexes of Benzocarbaporphyrins
Timothy D. Lash, Denise A. Colby, and Lisa F. Szczepura
pp 5258 - 5267; DOI:
10.1021/ic0400540
PDF
Photoisomerization of Matrix-Isolated Bis(trifluoromethyl) Sulfoxide: Formation of the Sulfenic Ester CF3SOCF3
S. E. Ulic, S. von Ahsen, and H. Willner
pp 5268 - 5274; DOI:
10.1021/ic049800r
PDF
Luminescent Ruthenium(II) Polypyridine Biotin Complexes: Synthesis, Characterization, Photophysical and Electrochemical Properties, and Avidin-Binding Studies
Kenneth Kam-Wing Lo and Terence Kwok-Ming Lee
pp 5275 - 5282; DOI:
10.1021/ic049750q
PDF
Synthesis and Characterization of a New Bisphosphonic Acid and Several Metal Hybrids Derivatives
M. Mar Gómez-Alcántara, Aurelio Cabeza, María Martínez-Lara, Miguel A. G. Aranda, Rafael Suau, Nattamai Bhuvanesh, and Abraham Clearfield
pp 5283 - 5293; DOI:
10.1021/ic049453l
PDF
Nitric Oxide Reactivity of Fluorophore Coordinated Carboxylate-Bridged Diiron(II) and Dicobalt(II) Complexes
Scott A. Hilderbrand and Stephen J. Lippard
pp 5294 - 5301; DOI:
10.1021/ic049649l
PDF
CD Spectra of d-f Heterobimetallic Helicates with Segmental Di-Imine Ligands
Shane G. Telfer, Nobuo Tajima, Reiko Kuroda, Martine Cantuel, and Claude Piguet
pp 5302 - 5310; DOI:
10.1021/ic049540d
PDF
Studies on Reactions INCX IXCN (X = O, S, and Se)
Yanli Zeng, Shijun Zheng, and Lingpeng Meng
pp 5311 - 5320; DOI:
10.1021/ic0496121
PDF
Mixed-Ligand Organometallic Polymers Containing the "Pd2(dmb)22+" Fragment: Properties of the {Pd2(dmb)2(diphos)2+}n Polymers/Oligomers in Solution and in the Solid State
Stéphanie Sicard, Jean-François Bérubé, Dalila Samar, Abdelhalim Messaoudi, Daniel Fortin, Frédéric Lebrun, Jean-François Fortin, Andreas Decken, and Pierre D. Harvey
pp 5321 - 5334; DOI:
10.1021/ic049923b
PDF
Self-Recognition in the Coordination Driven Self-Assembly of 2-D Polygons
Chris Addicott, Neeladri Das, and Peter J. Stang
pp 5335 - 5338; DOI:
10.1021/ic049326p
PDF
Linkage Isomerism, Structure, and Reactivity Studies of Sulfenamide Complexes of Cobalt(III)
M. J. Sisley, R. McDonald, and R. B. Jordan
pp 5339 - 5350; DOI:
10.1021/ic0350584
PDF
Further Mechanistic Information on the Reaction between FeIII(edta) and Hydrogen Peroxide: Observation of a Second Reaction Step and Importance of pH
Ariane Brausam and Rudi van Eldik
pp 5351 - 5359; DOI:
10.1021/ic0497580
PDF
A Chain of Changes: Influence of Noncovalent Interactions on the One-Dimensional Structures of Nickel(II) Dicarboxylate Coordination Polymers with Chelating Aromatic Amine Ligands
YongBok Go, Xiqu Wang, Ekaterina V. Anokhina, and Allan J. Jacobson
pp 5360 - 5367; DOI:
10.1021/ic049341u
PDF
Langmuir-Schäfer Films of an Amphiphilic Ruthenium Complex Bearing an "Almost Naked" Multicharged Headgroup
Santo Di Bella, Salvatore Sortino, Sabrina Conoci, Salvatore Petralia, Serena Casilli, and Ludovico Valli
pp 5368 - 5372; DOI:
10.1021/ic049381y
PDF
Phototoxicity against Tumor Cells and Sindbis Virus by an Octahedral Rhodium Bisbipyridyl Complex and Evidence for the Genome as a Target in Viral Photoinactivation
Elton L. Menon, Rushika Perera, Maribel Navarro, Richard J. Kuhn, and Harry Morrison
pp 5373 - 5381; DOI:
10.1021/ic0498586
PDF
Novel Eclipsed 2D Cadmium(II) Coordination Polymers with Open-Channel Structure Constructed from Terephthalate and 3-(2-Pyridyl)pyrazole: Crystal Structures, Emission Properties, and Inclusion of Guest Molecules
Ru-Qiang Zou, Xian-He Bu, and Ruo-Hua Zhang
pp 5382 - 5386; DOI:
10.1021/ic049625e
PDF
Gas-Phase Electron Diffraction Studies on Two 11-Vertex Dicarbaboranes, closo-2,3-C2B9H11 and nido-2,9-C2B9H13
Iain D. Mackie, Heather E. Robertson, David W. H. Rankin, Mark A. Fox, and John M. Malget
pp 5387 - 5392; DOI:
10.1021/ic0494509
PDF
Mechanisms of Ferriheme Reduction by Nitric Oxide: Nitrite and General Base Catalysis1
Bernadette O. Fernandez, Ivan M. Lorkovic, and Peter C. Ford
pp 5393 - 5402; DOI:
10.1021/ic049532x
PDF
Synthesis, Structure, and Substitution Mechanism of New Ru(II) Complexes Containing 1,4,7-Trithiacyclononane and 1,10-Phenanthroline Ligands
Xavier Sala, Isabel Romero, Montserrat Rodríguez, Antoni Llobet, Gabriel González, Manuel Martínez, and Jordi Benet-Buchholz
pp 5403 - 5409; DOI:
10.1021/ic0497533
PDF
Theoretical Study of the Magnetic Behavior of [Fe8] and [Fe16] Wheels
Rosa Carrasco, Joan Cano, Talal Mallah, Leigh F. Jones, David Collison, and Euan K. Brechin
pp 5410 - 5415; DOI:
10.1021/ic049547v
PDF
Acid-Catalyzed Oxidation of Iodide Ions by Superoxo Complexes of Rhodium and Chromium
Andreja Bakac, Chunkai Shi, and Oleg Pestovsky
pp 5416 - 5421; DOI:
10.1021/ic049629j
PDF
Immobilization of Oxomolybdenum Species in a Layered Double Hydroxide Pillared by 2,2'-Bipyridine-5,5'-dicarboxylate Anions
Sandra Gago, Martyn Pillinger, Anabela A. Valente, Teresa M. Santos, João Rocha, and Isabel S. Gonçalves
pp 5422 - 5431; DOI:
10.1021/ic049755n
PDF
High-Yield Carbon Nanorods Obtained by a Catalytic Copyrolysis Process
Guifu Zou, Jun Lu, Debao Wang, Liqiang Xu, and Yitai Qian
pp 5432 - 5435; DOI:
10.1021/ic049812c
PDF
Syntheses and Characterization of Some Mixed Te/Se Polychalcogenide Anions [TemSen]2-
Perumal Sekar and James A. Ibers
pp 5436 - 5441; DOI:
10.1021/ic040026h
PDF
Highly Sensitive WO3 Hollow-Sphere Gas Sensors
Xiao-Lin Li, Tian-Jun Lou, Xiao-Ming Sun, and Ya-Dong Li
pp 5442 - 5449; DOI:
10.1021/ic049522w
PDF
Hexaruthenium Carbonyl Cluster Complexes with Basal Edge-Bridged Square Pyramidal Metallic Skeleton: Efficient Synthesis of 2-Imidopyridine Derivatives and Determination of Their Reactive Sites in Carbonyl Substitution Reactions
Javier A. Cabeza, Ignacio del Río, Pablo García-Álvarez, Daniel Miguel, and Víctor Riera
pp 5450 - 5458; DOI:
10.1021/ic0492789
PDF
Bis-qtpy (qtpy = 2,2':6',2' ':6' ',2' ''-quaterpyridine) Metal Complexes, [M(qtpy)2]2+
Daniela Belli Dell' Amico, Fausto Calderazzo, Matteo Curiardi, Luca Labella, and Fabio Marchetti
pp 5459 - 5465; DOI:
10.1021/ic049595f
PDF
Phosphazene-Based Ionic Liquids: Synthesis, Temperature-Dependent Viscosity, and Effect as Additives in Water Lubrication of Silicon Nitride Ceramics
Bamidele A. Omotowa, Benjamin S. Phillips, Jeffery S. Zabinski, and Jean'ne M. Shreeve
pp 5466 - 5471; DOI:
10.1021/ic049483o
PDF
Syntheses and Characterizations of a Series of Novel Ln6Cu24 Clusters with Amino Acids as Ligands
Jian-Jun Zhang, Tian-Lu Sheng, Sheng-Qin Xia, Guido Leibeling, Franc Meyer, Sheng-Min Hu, Rui-Biao Fu, Sheng-Chang Xiang, and Xin-Tao Wu
pp 5472 - 5478; DOI:
10.1021/ic0497073
PDF

Issue 18


Spectroscopic Evidence for the Direct Coordination of the Pertechnetate Anion to the Uranyl Cation in [UO2(TcO4)(DPPMO2)2]+
Andrew D. Sutton, Gordon H. John, Mark J. Sarsfield, Joanna C. Renshaw, Iain May, Leigh R. Martin, Andrew J. Selvage, David Collison, and Madeleine Helliwell
pp 5480 - 5482; DOI:
10.1021/ic049588r
PDF
Feasibility of a Two-Metal, Four-Purine Nucleobase Quartet Motif
Michael Roitzsch and Bernhard Lippert
pp 5483 - 5485; DOI:
10.1021/ic0494152
PDF
Linear NiII-MnIII2-NiII Tetramers: An Oligomeric Component of the MnIII2NiII Single-Chain Magnets
Hitoshi Miyasaka, Tomohiro Nezu, Kunihisa Sugimoto, Ken-ichi Sugiura, Masahiro Yamashita, and Rodolphe Clérac
pp 5486 - 5488; DOI:
10.1021/ic049457q
PDF
A New Route to Obtain Shape-Controlled Gold Nanoparticles from Au(III)--diketonates
Subrata Kundu, Anjali Pal, Sujit Kumar Ghosh, Sudip Nath, Sudipa Panigrahi, Snigdhamayee Praharaj, and Tarasankar Pal
pp 5489 - 5491; DOI:
10.1021/ic0495214
PDF
Gadolinium(III) 1,2-Hydroxypyridonate-Based Complexes: Toward MRI Contrast Agents of High Relaxivity1
Jide Xu, David G. Churchill, Mauro Botta, and Kenneth N. Raymond
pp 5492 - 5494; DOI:
10.1021/ic049028s
PDF
Reactivity of Pyridine-2,4,6-tricarboxylic Acid toward Zn(II) Salts under Different Reaction Conditions
Sujit K. Ghosh, G. Savitha, and Parimal K. Bharadwaj
pp 5495 - 5497; DOI:
10.1021/ic049490c
PDF
Upward Temperature Shift of the Intrinsic Phase Lag of the Magnetization of Bis(phthalocyaniato)terbium by Ligand Oxidation Creating an S = 1/2 Spin
Naoto Ishikawa, Miki Sugita, Naohiro Tanaka, Tadahiko Ishikawa, Shin-ya Koshihara, and Youkoh Kaizu
pp 5498 - 5500; DOI:
10.1021/ic049348b
PDF
Synthesis, Structure, and Bonding of the Nonclassical Zintl Phase K5As3Pb3
Michael T. Klem and John D. Corbett
pp 5501 - 5504; DOI:
10.1021/ic040045r
PDF
Large Spin Differences in Structurally Related Fe6 Molecular Clusters and Their Magnetostructural Explanation
Cristina Cañada-Vilalta, Ted A. O'Brien, Euan K. Brechin, Maren Pink, Ernest R. Davidson, and George Christou
pp 5505 - 5521; DOI:
10.1021/ic049413h
PDF
Dramatic Structural Effects of a Single Hydrogen Atom in HNPBut3
Sarah L. Hinchley, Mairi F. Haddow, and David W. H. Rankin
pp 5522 - 5528; DOI:
10.1021/ic049467r
PDF
Synthesis of and Structural Studies on Lead(II) Cysteamin Complexes
Holger Fleischer and Dieter Schollmeyer
pp 5529 - 5536; DOI:
10.1021/ic0498889
PDF
Synthesis and Characterization of ReO4-Containing Microporous and Open Framework Structures
Junhua Luo, Ben Alexander, Timothy R. Wagner, and Paul A. Maggard
pp 5537 - 5542; DOI:
10.1021/ic049609h
PDF
Synthesis and Photochemical Properties of a Novel Iron-Sulfur-Nitrosyl Cluster Derivatized with the Pendant Chromophore Protoporphyrin IX1
Christa L. Conrado, Stephen Wecksler, Christian Egler, Douglas Magde, and Peter C. Ford
pp 5543 - 5549; DOI:
10.1021/ic049459a
PDF
Self-Assembly Using Dynamic Coordination Chemistry and Hydrogen Bonding: Mercury(II) Macrocycles, Polymers and Sheets
Tara J. Burchell, Dana J. Eisler, and Richard J. Puddephatt
pp 5550 - 5557; DOI:
10.1021/ic049500+
PDF
Powder Diffraction Study of a Coordination Polymer Comprised of Rigid Building Blocks: [Rh2(O2CCH3)4·2-Se2C5H8-Se,Se']
Evgeny V. Dikarev, Roman V. Shpanchenko, Kristian W. Andreini, Eric Block, Jin Jin, and Marina A. Petrukhina
pp 5558 - 5563; DOI:
10.1021/ic049497u
PDF
Reactivity of Iron(II) 5,10,15,20-Tetraaryl-21-oxaporphyrin with Arylmagnesium Bromide: Formation of Paramagnetic Six-Coordinate Complexes with Two Axial Aryl Groups
Miosz Pawlicki and Lechosaw Latos-Grayski
pp 5564 - 5571; DOI:
10.1021/ic0495463
PDF
Synthesis, Characterization, and X-ray Crystal Structures of Cyclam Derivatives. 5. Copper(II) Binding Studies of a Pyridine-Strapped 5,12-Dioxocyclam-Based Macrobicycle1
Michel Meyer, Laurent Frémond, Enrique Espinosa, Roger Guilard, Zhongping Ou, and Karl M. Kadish
pp 5572 - 5587; DOI:
10.1021/ic049518k
PDF
Silver-109 NMR Spectroscopy of Inorganic Solids
Glenn H. Penner and Wenli Li
pp 5588 - 5597; DOI:
10.1021/ic0349510
PDF
Structural Study by NMR of an Oxorhenium-RGD Decapeptide Complex for Application in Radiotherapy
Basil Costopoulos, Dimitra Benaki, Maria Pelecanou, Emmanuel Mikros, Chariklia I. Stassinopoulou, Alexandra D. Varvarigou, and Spyridon C. Archimandritis
pp 5598 - 5602; DOI:
10.1021/ic049519c
PDF
New Ag(I)-Containing Coordination Polymers Generated from Multidentate Schiff-Base Ligands
Yu-Bin Dong, Xia Zhao, Ru-Qi Huang, Mark D. Smith, and Hans-Conrad zur Loye
pp 5603 - 5612; DOI:
10.1021/ic049787a
PDF
Red Shifting Due to Nonplanarity in Alkylporphyrins: Solid-State Polarized UV-Vis Spectra and ZINDO Calculations of Two Nickel(II)octaethylporphyrins
Jeremy S. Evans and Ronald L. Musselman
pp 5613 - 5629; DOI:
10.1021/ic0496931
PDF
Syntheses, Crystal Structures, and Luminescent Properties of Novel Layered Lanthanide Sulfonate-Phosphonates
Jun-Ling Song, Chong Lei, and Jiang-Gao Mao
pp 5630 - 5634; DOI:
10.1021/ic049376u
PDF
Electrocatalytic Proton Reduction by Phosphido-Bridged Diiron Carbonyl Compounds: Distant Relations to the H-Cluster?
Mun Hon Cheah, Stacey J. Borg, Mark I. Bondin, and Stephen P. Best
pp 5635 - 5644; DOI:
10.1021/ic049746e
PDF
Pseudooctahedral Complexes of Vanadium(III): Electronic Structure Investigation by Magnetic and Electronic Spectroscopy
J. Krzystek, Adam T. Fiedler, Jennifer J. Sokol, Andrew Ozarowski, S. A. Zvyagin, Thomas C. Brunold, Jeffrey R. Long, Louis-Claude Brunel, and Joshua Telser
pp 5645 - 5658; DOI:
10.1021/ic0493503
PDF
Heterometallic Lanthanide Group 12 Metal Iodides
Louise Huebner, Anna Kornienko, Thomas J. Emge, and John G. Brennan
pp 5659 - 5664; DOI:
10.1021/ic049560f
PDF
Synthesis and Reactivity of Fluoro Complexes: Part 2.1 Rhodium(I) Fluoro Complexes with Alkene and Phosphine Ligands. Synthesis of the First Isolated Rhodium(I) Bifluoride Complexes. Structure of [Rh3(3-OH)2(COD)3](HF2) by X-ray Powder Diffraction
José Vicente, Juan Gil-Rubio, Delia Bautista, Angelo Sironi, and Norberto Masciocchi
pp 5665 - 5675; DOI:
10.1021/ic049585e
PDF
Hydrothermal Synthesis, Crystal Structure, Conductivity, and Thermal Decomposition of [Cu(4,4'-bipy)(H2O)(Mo3O10)]·H2O
Zuping Kong, Linhong Weng, Dejun Tan, Heyong He, Biao Zhang, Jilie Kong, and Bin Yue
pp 5676 - 5680; DOI:
10.1021/ic049608p
PDF
Structural and Functional Models of the Active Site of Zinc Phosphotriesterase
Håkan Carlsson, Matti Haukka, and Ebbe Nordlander
pp 5681 - 5687; DOI:
10.1021/ic0354522
PDF
Novel Nucleophilic Reactivity of Disulfido Ligands Coordinated Parallel to M-M (M = Rh, Ir) Bonds
Takanori Nishioka, Hiroaki Kitayama, Brian K. Breedlove, Kimie Shiomi, Isamu Kinoshita, and Kiyoshi Isobe
pp 5688 - 5697; DOI:
10.1021/ic049855t
PDF
Vibrational Study of Some Layered Structures Based on Titanium and Zirconium Phosphates
Pier Luigi Stanghellini, Enrico Boccaleri, Eliano Diana, Giulio Alberti, and Riccardo Vivani
pp 5698 - 5703; DOI:
10.1021/ic049565c
PDF
Synthesis, Structure, and Catalytic Properties of VIV, MnIII, MoVI, and UVI Complexes Containing Bidentate (N, O) Oxazine and Oxazoline Ligands
Karuppasamy Kandasamy, Harkesh B. Singh, Ray J. Butcher, and Jerry P. Jasinski
pp 5704 - 5713; DOI:
10.1021/ic0352093
PDF
Pyridine Substituted N-Heterocyclic Carbene Ligands as Supports for Au(I)-Ag(I) Interactions: Formation of a Chiral Coordination Polymer
Vincent J. Catalano, Mark A. Malwitz, and Anthony O. Etogo
pp 5714 - 5724; DOI:
10.1021/ic049604k
PDF
Steric and Hydrogen-Bonding Effects on the Stability of Copper Complexes with Small Molecules
Akira Wada, Yasutaka Honda, Syuhei Yamaguchi, Shigenori Nagatomo, Teizo Kitagawa, Koichiro Jitsukawa, and Hideki Masuda
pp 5725 - 5735; DOI:
10.1021/ic0496572
PDF
Syntheses, Structures, and Reactivities of {Fe-NO}6 Nitrosyls Derived from Polypyridine-Carboxamide Ligands: Photoactive NO-Donors and Reagents for S-Nitrosylation of Alkyl Thiols
Raman K. Afshar, Apurba K. Patra, Marilyn M. Olmstead, and Pradip K. Mascharak
pp 5736 - 5743; DOI:
10.1021/ic040057c
PDF
Electron Transfer Reaction of Oxo(salen)chromium(V) Ion with Anilines
Sundarsingh Premsingh, Natarajan Sathiyamoorthy Venkataramanan, Seenivasan Rajagopal, Shama. P. Mirza, Mariappanadar Vairamani, P. Sambasiva Rao, and K. Velavan
pp 5744 - 5753; DOI:
10.1021/ic049482w
PDF
Utility of Anhydrous Neodymium Nitrate as a Precursor to Extended Organoneodymium Nitrate Networks
William J. Evans, Dimitrios G. Giarikos, Penny S. Workman, and Joseph W. Ziller
pp 5754 - 5760; DOI:
10.1021/ic049187b
PDF
One-Dimensional Oxalato-Bridged Cu(II), Co(II), and Zn(II) Complexes with Purine and Adenine as Terminal Ligands
Juan P. García-Terán, Oscar Castillo, Antonio Luque, Urko García-Couceiro, Pascual Román, and Francesc Lloret
pp 5761 - 5770; DOI:
10.1021/ic049569h
PDF
Preparation, Characterization, and Magnetic Behavior of the Ln Derivatives (Ln = Nd, La) of a 2,6-Diiminepyridine Ligand and Corresponding Dianion
Hiroyasu Sugiyama, Ilia Korobkov, Sandro Gambarotta, Angela Möller, and Peter H. M. Budzelaar
pp 5771 - 5779; DOI:
10.1021/ic049820t
PDF
New Strontium Polysulfides, SrS3, and Sr2(OH)2S4·10H2O, Obtained by the High-pressure Treatment of a Sr-S Mixture
Hiroshi Fukuoka, Rimiko Suga, Kenji Komaguchi, Shoji Yamanaka, and Masaru Shiotani
pp 5780 - 5784; DOI:
10.1021/ic0494612
PDF

Issue 19


Copper(I) Complexes of Fluorinated Triazapentadienyl Ligands: Synthesis and Characterization of [N{(C3F7)C(Dipp)N}2]CuL (Where L = NCCH3, CNBut, CO; Dipp = 2,6-Diisopropylphenyl)
H. V. Rasika Dias and Shreeyukta Singh
pp 5786 - 5788; DOI:
10.1021/ic049229w
PDF
Simple Generation of Cationic Aluminum Alkyls and Alkoxides Based on the Pendant Arm Tridentate Schiff Base
Janusz Lewiski, Pawe Horeglad, Maciej Dranka, and Iwona Justyniak
pp 5789 - 5791; DOI:
10.1021/ic049337i
PDF
Formation of Hexacoordinate Complexes of PhCCSiF3 with 2,2'-Bipyridine and with 1,10-Phenanthroline through Intermolecular Silicon···Nitrogen Interactions
Moshe Nakash, Michael Goldvaser, and Israel Goldberg
pp 5792 - 5794; DOI:
10.1021/ic049125l
PDF
Trapping an Elusive Intermediate in Manganese-Oxo Cubane Chemistry
Jian-Zhong Wu, Eric Sellitto, Glenn P. A. Yap, John Sheats, and G. Charles Dismukes
pp 5795 - 5797; DOI:
10.1021/ic048988b
PDF
Accommodation of the Irregular Coordination Geometry of Lead(II) by a Square Planar N2S2 Ligand and Its Preference for Zinc(II)
Melissa L. Golden, Joseph H. Reibenspies, and Marcetta Y. Darensbourg
pp 5798 - 5800; DOI:
10.1021/ic049489d
PDF
A New Redox-Active Coordination Polymer with Cobalticinium Dicarboxylate
Mitsuru Kondo, Yuri Hayakawa, Makoto Miyazawa, Aiko Oyama, Kei Unoura, Hiroyuki Kawaguchi, Tetsuyoshi Naito, Kenji Maeda, and Fumio Uchida
pp 5801 - 5803; DOI:
10.1021/ic049273b
PDF
Nucleophilic Aromatic Substitution on Aryl-Amido Ligands Promoted by Oxidizing Osmium(IV) Centers
Jake D. Soper, Erik Saganic, David Weinberg, David A. Hrovat, Jason B. Benedict, Werner Kaminsky, and James M. Mayer
pp 5804 - 5815; DOI:
10.1021/ic0498743
PDF
EDTA and Mixed-Ligand Complexes of Tetravalent and Trivalent Plutonium
Hakim Boukhalfa, Sean D. Reilly, Wayne H. Smith, and Mary P. Neu
pp 5816 - 5823; DOI:
10.1021/ic035484p
PDF
Structure, Reactivity and Aromaticity of Acenes and Their BN Analogues: A Density Functional and Electrostatic Investigation
Ashwini Kumar Phukan, Rashmi P. Kalagi, Shridhar R. Gadre, and Eluvathingal D. Jemmis
pp 5824 - 5832; DOI:
10.1021/ic049690o
PDF
Sulfur Bridging Interactions of Cis-Planar NiII-S2N2 Coordination Units with Nickel(II), Copper(I,II), Zinc(II), and Mercury(II): A Library of Bridging Modes, Including NiII(2-SR)2MI,II Rhombs
P. Venkateswara Rao, Sumit Bhaduri, Jianfeng Jiang, and R. H. Holm
pp 5833 - 5849; DOI:
10.1021/ic040055s
PDF
Functionalized Metal Oxide Clusters: Synthesis, Characterization, Crystal Structures, and Magnetic Properties of a Novel Series of Fully Reduced Heteropolyoxovanadium Cationic Clusters Decorated with Organic Ligands-[MVIV6O6{(OCH2CH2)2N(CH2CH2OH)}6]X (M = Li, X = Cl·LiCl; M = Na, X = Cl·H2O; M = Mg, X = 2Br·H2O; M = Mn, Fe, X = 2Cl; M = Co, Ni, X = 2Cl·H2O)
M. Ishaque Khan, Saadia Tabussum, Robert J. Doedens, Vladimir O. Golub, and Charles J. O'Connor
pp 5850 - 5859; DOI:
10.1021/ic049417m
PDF
Au2(SeO3)2(SeO4): Synthesis and Characterization of a New Noncentrosymmetric Selenite-Selenate
Mathias S. Wickleder, Oliver Büchner, Claudia Wickleder, Sherif el Sheik, Gunther Brunklaus, and Hellmut Eckert
pp 5860 - 5864; DOI:
10.1021/ic049270z
PDF
Spontaneous Self-Assembly of an Unsymmetric Trinuclear Triangular Copper(II) Pyrazolate Complex, [Cu3(3-OH)(-pz)3(MeCOO)2(Hpz)] (Hpz = Pyrazole). Synthesis, Experimental and Theoretical Characterization, Reactivity, and Catalytic Activity
Maurizio Casarin, Carlo Corvaja, Corrado di Nicola, Daniele Falcomer, Lorenzo Franco, Magda Monari, Luciano Pandolfo, Claudio Pettinari, Fabio Piccinelli, and Pietro Tagliatesta
pp 5865 - 5876; DOI:
10.1021/ic049260y
PDF
Ultrasonic-Assisted Synthesis of Monodisperse Single-Crystalline Silver Nanoplates and Gold Nanorings
Li-Ping Jiang, Shu Xu, Jian-Min Zhu, Jian-Rong Zhang, Jun-Jie Zhu, and Hong-Yuan Chen
pp 5877 - 5883; DOI:
10.1021/ic049529d
PDF
Formation of Complex Three- and One-Dimensional Interpenetrating Networks within Carbodiimide Chemistry: NCN2--Coordinated Rare-Earth-Metal Tetrahedra and Condensed Alkali-Metal Iodide Octahedra in Two Novel Lithium Europium Carbodiimide Iodides, LiEu2(NCN)I3 and LiEu4(NCN)3I3
Wuping Liao, Chunhua Hu, Reinhard K. Kremer, and Richard Dronskowski
pp 5884 - 5890; DOI:
10.1021/ic049432r
PDF
Solvation of Uranyl(II) and Europium(III) Cations and Their Chloro Complexes in a Room-Temperature Ionic Liquid. A Theoretical Study of the Effect of Solvent "Humidity"
Alain Chaumont and Georges Wipff
pp 5891 - 5901; DOI:
10.1021/ic049386v
PDF
Transport of Alkali Halides through a Liquid Organic Membrane Containing a Ditopic Salt-Binding Receptor
Joseph M. Mahoney, Gayathri U. Nawaratna, Alicia M. Beatty, Peter J. Duggan, and Bradley D. Smith
pp 5902 - 5907; DOI:
10.1021/ic0494859
PDF
New Route to the Mixed Valence Semiquinone-Catecholate Based Mononuclear FeIII and Catecholate Based Dinuclear MnIII Complexes: First Experimental Evidence of Valence Tautomerism in an Iron Complex
Nizamuddin Shaikh, Sanchita Goswami, Anangamohan Panja, Xin-Yi Wang, Song Gao, Ray J. Butcher, and Pradyot Banerjee
pp 5908 - 5918; DOI:
10.1021/ic049579i
PDF
Mixed-Valence MnIIIMnIV Clusters [Mn7O8(O2SePh)8(O2CMe)(H2O)] and [Mn7O8(O2SePh)9(H2O)]: Single-Chain Magnets Exhibiting Quantum Tunneling of Magnetization
Nicole E. Chakov, Wolfgang Wernsdorfer, Khalil A. Abboud, and George Christou
pp 5919 - 5930; DOI:
10.1021/ic0494049
PDF
Intra and Intermolecular Magnetic Interactions in a Series of Dinuclear Cu(II)/hxta Complexes {H5hxta = N,N'-(2-hydroxy-1,3-xylylene)-bis-(N-carboxymethylglycine)}: Correlation of Magnetic Properties with Geometry
Steve Laborda, Rodolphe Clérac, Christopher E. Anson, and Annie K. Powell
pp 5931 - 5943; DOI:
10.1021/ic035333m
PDF
Hybrid DFT Study of the Mechanism of Quercetin 2,3-Dioxygenase
Per E. M. Siegbahn
pp 5944 - 5953; DOI:
10.1021/ic0498541
PDF
New Aluminate with a Tetrahedral Structure Closely Related to the C84 Fullerene
S. Boudin, B. Mellenne, R. Retoux, M. Hervieu, and B. Raveau
pp 5954 - 5960; DOI:
10.1021/ic049679o
PDF
Theoretical Studies of Ground and Excited Electronic States in a Series of Rhenium(I) Bipyridine Complexes Containing Diarylethynyl-Based Structure
Li Yang, Ai-Min Ren, Ji-Kang Feng, Xiao-Dong Liu, Yu-Guang Ma, and Hong-Xing Zhang
pp 5961 - 5972; DOI:
10.1021/ic049735l
PDF
Complex Reduction Chemistry of (abpy)PtCl2, abpy = 2,2'-Azobispyridine: Formation of Cyclic [(,2:1-abpy)PtCl]22+ with a New Coordination Mode for abpy and a Near-Infrared Ligand-to-Ligand Intervalence Charge Transfer Absorption of the One-Electron Reduced State
Akbey Dogan, Biprajit Sarkar, Axel Klein, Falk Lissner, Thomas Schleid, Jan Fiedler, Stanislav Záli, Vimal K. Jain, and Wolfgang Kaim
pp 5973 - 5980; DOI:
10.1021/ic049941t
PDF
Stabilized Arsenic(I) Iodide: A Ready Source of Arsenic Iodide Fragments and a Useful Reagent for the Generation of Clusters
Bobby D. Ellis and Charles L. B. Macdonald
pp 5981 - 5986; DOI:
10.1021/ic049281s
PDF
Mono-, Bi-, and Trinuclear CuII-Cl Containing Products Based on the Tris(2-pyridylmethyl)amine Chelate Derived from Copper(I) Complex Dechlorination Reactions of Chloroform
Baldo Lucchese, Kristi J. Humphreys, Dong-Heon Lee, Christopher D. Incarvito, Roger D. Sommer, Arnold L. Rheingold, and Kenneth D. Karlin
pp 5987 - 5998; DOI:
10.1021/ic0497477
PDF
Spectroscopic and Structural Characterizations of Novel Water-Soluble Tetraperoxo and Diperoxo[polyaminocarboxylato bis(N-oxido)]tantalate(V) Complexes
Daisy Bayot, Bernard Tinant, and Michel Devillers
pp 5999 - 6005; DOI:
10.1021/ic049639k
PDF
Synthesis, Characterization, and Structures of Indium In(DTPA-BA2) and Yttrium Y(DTPA-BA2)(CH3OH) Complexes (BA = Benzylamine): Models for 111In- and 90Y-Labeled DTPA-Biomolecule Conjugates
Wen-Yuan Hsieh and Shuang Liu
pp 6006 - 6014; DOI:
10.1021/ic049973g
PDF
Synthesis, Structure, Magnetism, and Spectroscopic Properties of Heterobinuclear Copper(II)-Zinc(II) Complexes and Their Copper(II)-Copper(II) Analogues in Asymmetric Ligand Environments
Dipesh Ghosh, Nabanita Kundu, Goutam Maity, Ki-Young Choi, Andrea Caneschi, Akira Endo, and Muktimoy Chaudhury
pp 6015 - 6023; DOI:
10.1021/ic049449+
PDF
Cyclohexene Oxide/CO2 Copolymerization Catalyzed by Chromium(III) Salen Complexes and N-Methylimidazole: Effects of Varying Salen Ligand Substituents and Relative Cocatalyst Loading
Donald. J. Darensbourg, Ryan M. Mackiewicz, Jody L. Rodgers, Cindy C. Fang, Damon R. Billodeaux, and Joseph H. Reibenspies
pp 6024 - 6034; DOI:
10.1021/ic049182e
PDF
Synthesis and Characterization of a Series of Rubidium Alkoxides and Rubidium-Titanium Double Alkoxides
Scott D. Bunge, Timothy J. Boyle, Harry D. Pratt III, Todd M. Alam, and Mark A. Rodriguez
pp 6035 - 6041; DOI:
10.1021/ic049325x
PDF
Pyrazolylborate-Zinc Alkoxide Complexes. 1. Basic Properties, Methylations, and Heterocumulene Insertions
Horst Brombacher and Heinrich Vahrenkamp
pp 6042 - 6049; DOI:
10.1021/ic049179v
PDF
Pyrazolylborate-Zinc Alkoxide Complexes. 2. Solvolytic Chemistry
Horst Brombacher and Heinrich Vahrenkamp
pp 6050 - 6053; DOI:
10.1021/ic0491783
PDF
Pyrazolylborate-Zinc Alkoxide Complexes. 3. Acid-Base Reactions
Horst Brombacher and Heinrich Vahrenkamp
pp 6054 - 6060; DOI:
10.1021/ic049177a
PDF
Synthesis of -MoTe2 Nanorods via Annealing Te-Seeded Amorphous MoTe2 Particles
Longhui Qiu, Yun Wei, Vilas G. Pol, and Aharon Gedanken
pp 6061 - 6066; DOI:
10.1021/ic049591a
PDF
Synthesis, Characterization, and Dynamic Studies of 12-Vertex 5-Ruthenium(II) closo-Phosphine Complexes with Monoanionic [10-L-nido-7-R-7,8-C2B9H9]- Ligands
O. Tutusaus, R. Núñez, C. Viñas, F. Teixidor, I. Mata, and E. Molins
pp 6067 - 6074; DOI:
10.1021/ic049322k
PDF
Ferromagnetic Anomaly Associated with the Antiferromagnetic Transitions in (Donor)[Ni(mnt)2]-Type Charge-Transfer Salts
Hideyasu Nakajima, Mao Katsuhara, Minoru Ashizawa, Tadashi Kawamoto, and Takehiko Mori
pp 6075 - 6082; DOI:
10.1021/ic049670m
PDF
Room Temperature Phosphorescence from Ruthenium(II) Complexes Bearing Conjugated Pyrenylethynylene Subunits
Denis V. Kozlov, Daniel S. Tyson, Christine Goze, Raymond Ziessel, and Felix N. Castellano
pp 6083 - 6092; DOI:
10.1021/ic049288+
PDF
Mechanistic Elucidation of the Substitution Behavior of Alkyl Cobaloximes in Water and Methanol as Solvents
Basam M. Alzoubi, Günter Liehr, and Rudi van Eldik
pp 6093 - 6100; DOI:
10.1021/ic049761j
PDF
An Unsymmetrical Tripodal Ligand with NOS2-Donor Set: Coordination Chemistry with Nickel(II) and Zinc(II)
F. Ekkehardt Hahn, Christian Ochs, Thomas Lügger, and Roland Fröhlich
pp 6101 - 6107; DOI:
10.1021/ic0491940
PDF
Isovalent and Mixed-Valent Diruthenium Complexes [(acac)2RuII (-bpytz)RuII(acac)2] and [(acac)2RuII(-bpytz)RuIII(acac)2](ClO4) (acac = Acetylacetonate and bpytz = 3,6-Bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine): Synthesis, Spectroelectrochemical, and EPR Investigation
Srikanta Patra, Biprajit Sarkar, Sandeep Ghumaan, Jan Fiedler, Wolfgang Kaim, and Goutam Kumar Lahiri
pp 6108 - 6113; DOI:
10.1021/ic049346r
PDF
Synthesis and H+, Cu2+, and Zn2+ Coordination Behavior of a Bis(fluorophoric) Bibrachial Lariat Aza-Crown
M. Paz Clares, Juan Aguilar, Ricardo Aucejo, Carlos Lodeiro, M. Teresa Albelda, Fernando Pina, J. C. Lima, A. Jorge Parola, João Pina, J. Seixas de Melo, Conxa Soriano, and Enrique García-España
pp 6114 - 6122; DOI:
10.1021/ic049694t
PDF

Issue 20


Nonclassical Bonding in the Novel Structure of Ba2Bi3 and Unexpected Site Preference in the Coloring Variant Ba2BiSb2
Siméon Ponou and Thomas F. Fässler
pp 6124 - 6126; DOI:
10.1021/ic0495719
PDF
Synthesis, Structures, and Solution Behavior of Di- and Trinuclear Titanium(IV)-Cyclophosphato Complexes
Sou Kamimura, Tsukasa Matsunaga, Shigeki Kuwata, Masakazu Iwasaki, and Youichi Ishii
pp 6127 - 6129; DOI:
10.1021/ic049206h
PDF
Unprecedented Acceleration of Zirconium(IV)-Assisted Peptide Hydrolysis at Neutral pH
Miki Kassai, R. Gnana Ravi, Sarah J. Shealy, and Kathryn B. Grant
pp 6130 - 6132; DOI:
10.1021/ic049433j
PDF
Synthesis and Characterization of a Tetrazolate-Bridged Coordination Framework Encapsulating D2h-Symmetric Cyclic (H2O)4 Cluster Arrays
Jun Tao, Zhi-Jie Ma, Rong-Bin Huang, and Lan-Sun Zheng
pp 6133 - 6135; DOI:
10.1021/ic0492946
PDF
Halogeno-Coordinated Iron Corroles
Liliya Simkhovich and Zeev Gross
pp 6136 - 6138; DOI:
10.1021/ic0491332
PDF
Dynamic Coordination Polymers with 4,4'-Oxybis(benzoate): Reversible Transformations of Nano- and Nonporous Coordination Frameworks Responding to Present Solvents
Mitsuru Kondo, Yasuhiko Irie, Yusuke Shimizu, Makoto Miyazawa, Hiroyuki Kawaguchi, Akira Nakamura, Tetsuyoshi Naito, Kenji Maeda, and Fumio Uchida
pp 6139 - 6141; DOI:
10.1021/ic0496166
PDF
Cooperative Formation of Trinuclear Zinc(II) Complexes via Complexation of a Tetradentate Oxime Chelate Ligand, Salamo, and Zinc(II) Acetate
Shigehisa Akine, Takanori Taniguchi, and Tatsuya Nabeshima
pp 6142 - 6144; DOI:
10.1021/ic049282k
PDF
Structural Variability in Neptunium(V) Oxalate Compounds: Synthesis and Structural Characterization of Na2NpO2(C2O4)OH·H2O
Amanda C. Bean, Eduardo Garcia, Brian L. Scott, and Wolfgang Runde
pp 6145 - 6147; DOI:
10.1021/ic0492082
PDF
K2[Ge(B4O9)]·2H2O: A Unique 3D Alternating Linkage Mode of a B4O9 Cluster and GeO4 Unit in Borogermanate with Two Pairs of Interweaving Double Helical Channels
Hong-Xia Zhang, Jie Zhang, Shou-Tian Zheng, Guo-Ming Wang, and Guo-Yu Yang
pp 6148 - 6150; DOI:
10.1021/ic049071f
PDF
The Nowotny Chimney Ladder Phases: Following the cpseudo Clue toward an Explanation of the 14 Electron Rule
Daniel C. Fredrickson, Stephen Lee, Roald Hoffmann, and Jianhua Lin
pp 6151 - 6158; DOI:
10.1021/ic049427n
PDF
The Nowotny Chimney Ladder Phases: Whence the 14 Electron Rule?
Daniel C. Fredrickson, Stephen Lee, and Roald Hoffmann
pp 6159 - 6167; DOI:
10.1021/ic049897h
PDF
Mono- and Dinuclear Complexes of Chiral Tri- and Tetradentate Schiff-Base Ligands Derived from 1,1'-Binaphthyl-2,2'-diamine
Shane G. Telfer, Tomohiro Sato, Takunori Harada, Reiko Kuroda, Julie Lefebvre, and Daniel B. Leznoff
pp 6168 - 6176; DOI:
10.1021/ic049910y
PDF
Binding of DNA Purine Sites to Dirhodium Compounds Probed by Mass Spectrometry
Helen T. Chifotides, John M. Koomen, Mijeong Kang, Shane E. Tichy, Kim R. Dunbar, and David H. Russell
pp 6177 - 6187; DOI:
10.1021/ic040040u
PDF
Metal-Metal Bonding in ScTaN2. A New Compound in the System ScN-TaN
R. Niewa, D. A. Zherebtsov, W. Schnelle, and F. R. Wagner
pp 6188 - 6194; DOI:
10.1021/ic040027+
PDF
Design and Study of Bi[1,8]naphthyridine Ligands as Potential Photooxidation Mediators in Ru(II) Polypyridyl Aquo Complexes
Ruifa Zong, Frederic Naud, Carrie Segal, John Burke, Feiyue Wu, and Randolph Thummel
pp 6195 - 6202; DOI:
10.1021/ic040051n
PDF
Mononuclear, Five-Coordinate Lanthanide Amido and Aryloxide Complexes Bearing Tetradentate (N2O2) Schiff Bases
Steven A. Schuetz, Carter M. Silvernail, Christopher D. Incarvito, Arnold L. Rheingold, Joanna L. Clark, Victor W. Day, and John A. Belot
pp 6203 - 6214; DOI:
10.1021/ic040006f
PDF
Synthesis, Characterization, and Detailed Electrochemistry of Binuclear Ruthenium(III) Complexes Bridged by Bisacetylacetonate. Crystal and Molecular Structures of [{Ru(acac)2}2(tae)] (acac = 2,4-Pentanedionate Ion, tae = 1,1,2,2-Tetraacetylethanate Dianion)
Tomohiro Koiwa, Yuki Masuda, Junpei Shono, Yuji Kawamoto, Yoshimasa Hoshino, Takeshi Hashimoto, Karuppannan Natarajan, and Kunio Shimizu
pp 6215 - 6223; DOI:
10.1021/ic030216c
PDF
Kinetics of Acid-Catalyzed O-Atom Transfer from a Hydroperoxorhodium Complex to Organic and Inorganic Substrates
Kelemu Lemma and Andreja Bakac
pp 6224 - 6227; DOI:
10.1021/ic049421y
PDF
Synthesis and Characterization of Novel Monocarbollide exo-closo-(-Arene)biruthenacarboranes [(PPh3)mClRu(6-C6H5R)Ru'CB10H11-n(OMe)n] (where R = H, m = 2, n = 1; R = -PPh2, m = 1, n = 0, 1)
Irina V. Pisareva, Vitalii E. Konoplev, Pavel V. Petrovskii, Evgenii V. Vorontsov, Fedor M. Dolgushin, Alexandr I. Yanovsky, and Igor T. Chizhevsky
pp 6228 - 6237; DOI:
10.1021/ic0497883
PDF
The Ionic Isomegethic Rule and Additivity Relationships: Estimation of Ion Volumes. A Route to the Energetics and Entropics of New, Traditional, Hypothetical, and Counterintuitive Ionic Materials
H. Donald Brooke Jenkins, Leslie Glasser, Thomas M. Klapötke, Margaret-Jane Crawford, Kaldip K. Bhasin, Joe Lee, Gary J. Schrobilgen, Lee S. Sunderlin, and Joel F. Liebman
pp 6238 - 6248; DOI:
10.1021/ic049186j
PDF
Alfred Werner's Inorganic Counterparts of Racemic and Mesomeric Tartaric Acid: A Milestone Revisited
W. Gregory Jackson, Josephine A. McKeon, and Silvia Cortez
pp 6249 - 6254; DOI:
10.1021/ic040042e
PDF
Zn(II) Coordination to Polyamine Macrocycles Containing Dipyridine Units. New Insights into the Activity of Dinuclear Zn(II) Complexes in Phosphate Ester Hydrolysis
Carla Bazzicalupi, Andrea Bencini, Emanuela Berni, Antonio Bianchi, Patrizia Fornasari, Claudia Giorgi, and Barbara Valtancoli
pp 6255 - 6265; DOI:
10.1021/ic049754v
PDF
pH-Dependent Isolations and Spectroscopic, Structural, and Thermal Studies of Titanium Citrate Complexes
Yuan-Fu Deng, Zhao-Hui Zhou, and Hui-Lin Wan
pp 6266 - 6273; DOI:
10.1021/ic0496018
PDF
Iron Chelation Properties of an Extracellular Siderophore Exochelin MS
Suraj Dhungana, Colin Ratledge, and Alvin L. Crumbliss
pp 6274 - 6283; DOI:
10.1021/ic049343e
PDF
Iron(III) Complexes of Sterically Hindered Tetradentate Monophenolate Ligands as Functional Models for Catechol 1,2-Dioxygenases: The Role of Ligand Stereoelectronic Properties
Marappan Velusamy, Ramasamy Mayilmurugan, and Mallayan Palaniandavar
pp 6284 - 6293; DOI:
10.1021/ic049802b
PDF
Reaction Properties of the trans-Hyponitrite Complex [Ru2(CO)4(-H)(-PBut2)(-Ph2PCH2PPh2)(-2-ONNO)]
Hans-Christian Böttcher, Christoph Wagner, and Karl Kirchner
pp 6294 - 6299; DOI:
10.1021/ic0496424
PDF
Unprecedented Oxo-Titanium Citrate Complex Precipitated from Aqueous Citrate Solutions, Exhibiting a Novel Bilayered Ti8O10 Structural Core
Tim Kemmitt, Najeh I. Al-Salim, Graeme J. Gainsford, Andrea Bubendorfer, and Mark Waterland
pp 6300 - 6306; DOI:
10.1021/ic049760r
PDF
Heterometallic Ln/Hg Compounds with Fluorinated Thiolate Ligands
Santanu Banerjee, Thomas J. Emge, and John G. Brennan
pp 6307 - 6312; DOI:
10.1021/ic049215q
PDF
Synthesis and Evaluation of a High Relaxivity Manganese(II)-Based MRI Contrast Agent
Jeffrey S. Troughton, Matthew T. Greenfield, Jaclyn M. Greenwood, Stéphane Dumas, Andrea J. Wiethoff, Jufeng Wang, Marga Spiller, Thomas J. McMurry, and Peter Caravan
pp 6313 - 6323; DOI:
10.1021/ic049559g
PDF
Binuclear Copper(II) Oxidation Products from Copper(I) Complexes with Tridentate Ligands. Magnetostructural Characterization
Darío Rojas, Ana M. García, Andrés Vega, Yanko Moreno, Diego Venegas-Yazigi, María T. Garland, and Jorge Manzur
pp 6324 - 6330; DOI:
10.1021/ic049648t
PDF
Hexacoordinate Planar Main Group Atoms Centered in Hexagonal Hydrocopper Complexes Cu6H6X (X = Si, P, As)
Si-Dian Li, Guang-Ming Ren, and Chang-Qing Miao
pp 6331 - 6333; DOI:
10.1021/ic049623u
PDF
Thienyl Carboxylate Ligands Bound to and Bridging MM Quadruple Bonds, M = Mo or W: Models for Polythiophenes Incorporating MM Quadruple Bonds
Matthew J. Byrnes, Malcolm H. Chisholm, Robin J. H. Clark, Judith C. Gallucci, Christopher M. Hadad, and Nathan J. Patmore
pp 6334 - 6344; DOI:
10.1021/ic040086n
PDF
Synthesis and Crystal Structure of Two New Discrete, Neutral Complexes of Manganese and Zinc Using a Rigid Organic Clip
Partha Sarathi Mukherjee, Kil Sik Min, Atta M. Arif, and Peter J. Stang
pp 6345 - 6350; DOI:
10.1021/ic0493088
PDF
Bilayers, Corrugated Bilayers, and Coordination Polymers of p-Sulfonatocalix[6]arene
Scott J. Dalgarno, Michaele J. Hardie, Jerry L. Atwood, and Colin L. Raston
pp 6351 - 6356; DOI:
10.1021/ic0493595
PDF
Reactions of meso-Hydroxyhemes with Carbon Monoxide and Reducing Agents in Search of the Elusive Species Responsible for the g = 2.006 Resonance of Carbon Monoxide-Treated Heme Oxygenase. Isolation of Diamagnetic Iron(II) Complexes of Octaethyl-meso-hydroxyporphyrin
Sankar Prasad Rath, Marilyn M. Olmstead, and Alan L. Balch
pp 6357 - 6365; DOI:
10.1021/ic049581+
PDF
Fluorescence-Based Nitric Oxide Detection by Ruthenium Porphyrin Fluorophore Complexes
Mi Hee Lim and Stephen J. Lippard
pp 6366 - 6370; DOI:
10.1021/ic035418n
PDF
Synthesis and Crystal Structure of Lithium Beryllium Deuteride Li2BeD4
Boris M. Bulychev, Roman V. Shpanchenko, Evgeny V. Antipov, Denis V. Sheptyakov, Svetlana N. Bushmeleva, and Anatoly M. Balagurov
pp 6371 - 6376; DOI:
10.1021/ic049267f
PDF
Density Functional Study of Valence Trapping in a Mixed-Valent Dimanganese Complex
Michael Bühl and Walter Thiel
pp 6377 - 6382; DOI:
10.1021/ic0493189
PDF
Synthesis, Characterization, and Photochemical and Computational Investigations of Ru(II) Heterocyclic Complexes Containing 2,6-dimethylphenylisocyanide (CNx) Ligand
John M. Villegas, Stanislav R. Stoyanov, Wei Huang, Loranelle L. Lockyear, Joseph H. Reibenspies, and D. Paul Rillema
pp 6383 - 6396; DOI:
10.1021/ic049099r
PDF
Characterization of 2,3-Dihydroxyterephthalamides as M(IV) Chelators1
Christine J. Gramer and Kenneth N. Raymond
pp 6397 - 6402; DOI:
10.1021/ic0496267
PDF
Synthesis and Characterization of the First Organically Templated Metal Oxalatophosphonate: (C3H12N2)0.5[Ga3(C2O4)(CH3PO3)4]·0.5H2O
Chia-Hui Lin and Kwang-Hwa Lii
pp 6403 - 6407; DOI:
10.1021/ic049598s
PDF
Charge-Transfer Hybrids Containing Covalently Bonded Polyoxometalates and Ferrocenyl Units
Jeonghee Kang, James A. Nelson, Meng Lu, Baohan Xie, Zhonghua Peng, and Douglas R. Powell
pp 6408 - 6413; DOI:
10.1021/ic049250x
PDF
Vanadium 7,7,8,8-Tetracyano-p-quinodimethane (V[TCNQ]2)-Based Magnets
Elaine B. Vickers, Trent D. Selby, Matthew S. Thorum, Michelle L. Taliaferro, and Joel S. Miller
pp 6414 - 6420; DOI:
10.1021/ic049552z
PDF
Insertion of Iodine in a Functionalized Inorganic Layered Solid
L. Mohanambe and S. Vasudevan
pp 6421 - 6425; DOI:
10.1021/ic0495721
PDF
The Role of Neutral Coligands on the Stabilization of Mono-TpiPr2 U(III) Complexes
Leonor Maria, Ângela Domingos, Adelino Galvão, José Ascenso, and Isabel Santos
pp 6426 - 6434; DOI:
10.1021/ic049261q
PDF
Cobalt(III) Complexes of Monodentate N(9)-Bound Adeninate (ade-), [Co(ade-N9)Cl(en)2]+ (en = 1,2-Diaminoethane): Syntheses, Crystal Structures, and Protonation Behaviors of the Geometrical Isomers
Takayoshi Suzuki, Yoko Hirai, Hideaki Monjushiro, and Sumio Kaizaki
pp 6435 - 6444; DOI:
10.1021/ic035336z
PDF
Unusual Reactivity of the {ReVO}3+ Core: Syntheses and Characterization of Novel Rhenium Halide Complexes with N-Methyl-o-diaminobenzene
Lihui Wei, John W. Babich, and Jon Zubieta
pp 6445 - 6454; DOI:
10.1021/ic049372p
PDF
Structural Characterization and Electronic Properties Determination by High-Field and High-Frequency EPR of a Series of Five-Coordinated Mn(II) Complexes
Claire Mantel, Carole Baffert, Isabel Romero, Alain Deronzier, Jacques Pécaut, Marie-Noëlle Collomb, and Carole Duboc
pp 6455 - 6463; DOI:
10.1021/ic049650k
PDF
Neutral Paddlewheel Diruthenium Complexes with Tetracarboxylates of Large -Conjugated Substituents: Facile One-Pot Synthesis, Crystal Structures, and Electrochemical Studies
Shuhei Furukawa and Susumu Kitagawa
pp 6464 - 6472; DOI:
10.1021/ic0493752
PDF
Crystal Structure and Physical Properties of a New CuTi2S4 Modification in Comparison to the Thiospinel
Navid Soheilnia, Katja M. Kleinke, Enkhtsetseg Dashjav, Heather L. Cuthbert, John E. Greedan, and Holger Kleinke
pp 6473 - 6478; DOI:
10.1021/ic0495113
PDF
Mechanism of H2O2 Dismutation Catalyzed by a New Catalase Mimic (a Non-Heme Dibenzotetraaza[14]annulene-Fe(III) Complex): A Density Functional Theory Investigation
Xin Wang, Shuhua Li, and Yuansheng Jiang
pp 6479 - 6489; DOI:
10.1021/ic049715j
PDF
Heavy-Metal Aromatic Rings: Cyclopentadienyl Anion Analogues Sn56- and Pb56- in the Zintl Phases Na8BaPb6, Na8BaSn6, and Na8EuSn6
Iliya Todorov and Slavi C. Sevov
pp 6490 - 6494; DOI:
10.1021/ic0491837
PDF
Identification, Isolation, and Characterization of Cysteinate and Thiolactate Complexes of Bismuth
Glen G. Briand, Neil Burford, Melanie D. Eelman, Nadia Aumeerally, Luke Chen, T. Stanley Cameron, and Katherine N. Robertson
pp 6495 - 6500; DOI:
10.1021/ic049594n
PDF
Tungsten(VI) Complexes with Aminobis(phenolato) [O,N,O] Donor Ligands
Ari Lehtonen and Reijo Sillanpää
pp 6501 - 6506; DOI:
10.1021/ic049448h
PDF

Issue 21


Borohydride Anions as Terminal Ligands on a Fe/Mo/S Cluster. Synthesis, Structure, and Characterization of the [(Cl4-cat)(PPr3)MoFe3S4(BH4)2]2(Bu4N)4 Double-Fused Cubane
Markos Koutmos and Dimitri Coucouvanis
pp 6508 - 6510; DOI:
10.1021/ic049275w
PDF
Dramatic Effect of Heteroatom Backbone Substituents on the Ethylene Polymerization Behavior of Bis(imino)pyridine Iron Catalysts
Theo M. Smit, Atanas K. Tomov, Vernon C. Gibson, Andrew J. P. White, and David J. Williams
pp 6511 - 6512; DOI:
10.1021/ic0490775
PDF
Synthesis and Luminescence of a Charge-Neutral, Cyclometalated Iridium(III) Complex Containing NCN- and CNC-Coordinating Terdentate Ligands
Andrew J. Wilkinson, Andrés E. Goeta, Clive E. Foster, and J. A. Gareth Williams
pp 6513 - 6515; DOI:
10.1021/ic049272j
PDF
C-S Bond Formation Reaction between a Phenolate and Disulfide-Bridged Dicopper(I) Complexes
Takao Osako, Yoshiki Ueno, Yoshimitsu Tachi, and Shinobu Itoh
pp 6516 - 6518; DOI:
10.1021/ic049495+
PDF
Preventing Nitrite Contamination in Tetramethylammonium Peroxynitrite Solutions
Petr Latal, Reinhard Kissner, D. Scott Bohle, and Willem H. Koppenol
pp 6519 - 6521; DOI:
10.1021/ic049161k
PDF
Rational Design and Crystal Structure Determination of a 3-D Metal-Organic Jungle-Gym-like Open Framework
Ryo Kitaura, Fumiyasu Iwahori, Ryotaro Matsuda, Susumu Kitagawa, Yoshiki Kubota, Masaki Takata, and Tatsuo C. KobayashiO
pp 6522 - 6524; DOI:
10.1021/ic049005d
PDF
Interweaving 3D Network with Double Helical Tubes Filled by 1D Coordination Polymer Chains
E Yang, Jian Zhang, Zhao-Ji Li, Song Gao, Yao Kang, Yu-Biao Chen, Yi-Hang Wen, and Yuan-Gen Yao
pp 6525 - 6527; DOI:
10.1021/ic049363g
PDF
[C5H14N2][(MoO3)3(SO4)]·H2O: Sulfated -Molybdena Chains
Jesse R. Gutnick, Eric A. Muller, Amy Narducci Sarjeant, and Alexander J. Norquist
pp 6528 - 6530; DOI:
10.1021/ic049192f
PDF
Synthesis and Magnetic Properties of Wheel-Shaped [Mn12] and [Fe6] Complexes
Evan M. Rumberger, Lev N. Zakharov, Arnold L. Rheingold, and David N. Hendrickson
pp 6531 - 6533; DOI:
10.1021/ic0488886
PDF
Addressing Lead Toxicity: Complexation of Lead(II) with Thiopyrone and Hydroxypyridinethione O,S Mixed Chelators
Jana A. Lewis and Seth M. Cohen
pp 6534 - 6536; DOI:
10.1021/ic0493696
PDF
Cu(I) -Diketiminates for Alkene Aziridination: Reversible Cu-Arene Binding and Catalytic Nitrene Transfer from PhI=NTs
LaTasha D. Amisial, Xuliang Dai, R. Adam Kinney, Ammani Krishnaswamy, and Timothy H. Warren
pp 6537 - 6539; DOI:
10.1021/ic048968+
PDF
Thermally Stable Hematite Hollow Nanowires
Yujie Xiong, Zhengquan Li, Xiaoxu Li, Biao Hu, and Yi Xie
pp 6540 - 6542; DOI:
10.1021/ic049018r
PDF
(R/S)A2- or (R,S/S,R)p,p'-[Pd(2-P,P-{P(OC6H3But2-2,4)2N(Me)C(O)N(Me)PPh2}Cl2]: Chirality Created by Ring Tilting
Olaf Kühl and Steffen Blaurock
pp 6543 - 6545; DOI:
10.1021/ic049222e
PDF
Persistent Phosphinyl Radicals Featuring a Bulky Amino Substituent and the 2,6-Bis(trifluoromethyl)phenyl Group
Anca Dumitrescu, Valentyn L. Rudzevich, Vadim D. Romanenko, Alain Mari, Wolfgang W. Schoeller, Didier Bourissou, and Guy Bertrand
pp 6546 - 6548; DOI:
10.1021/ic049152b
PDF
Pyridyl-Based Pentadentate Ligands: Base-Catalyzed Hydrolysis of asym-[Co(dmptacn)Cl]2+
W. Gregory Jackson, Alistair J. Dickie, Rajumati Bhula, Josephine A. McKeon, Leone Spiccia, Suzanne J. Brudenell, David C. R. Hockless, and Anthony C. Willis
pp 6549 - 6556; DOI:
10.1021/ic040041m
PDF
Factors Affecting the Solid-State Structure and Dimensionality of Mercury Cyanide/Chloride Double Salts, and NMR Characterization of Coordination Geometries
Neil D. Draper, Raymond J. Batchelor, Pedro M. Aguiar, Scott Kroeker, and Daniel B. Leznoff
pp 6557 - 6567; DOI:
10.1021/ic049792e
PDF
Synthesis, Characterization, and Structures of Copper(II)-Thiosulfate Complexes Incorporating Tripodal Tetraamine Ligands
Adam J. Fischmann, Andrew C. Warden, Jay Black, and Leone Spiccia
pp 6568 - 6578; DOI:
10.1021/ic0492800
PDF
Chiral Molecular Squares Based on Angular Bipyridines: Self-Assembly, Characterization, and Photophysical Properties
Suk Joong Lee, Jason S. Kim, and Wenbin Lin
pp 6579 - 6588; DOI:
10.1021/ic0497937
PDF
Copper(II) Complexes of N-Octylated Bis(benzimidazole) Diamide Ligands and Their Peroxide-Dependent Oxidation of Aryl Alcohols
Sarita Tehlan, M. S. Hundal, and Pavan Mathur
pp 6589 - 6595; DOI:
10.1021/ic0302884
PDF
An Infinite Zigzag Chain of Alternating Cl-Pd-Pd-Cl and Mo-Mo Units
Jianjun Yi, Takayuki Miyabayashi, Masato Ohashi, Tsuneaki Yamagata, and Kazushi Mashima
pp 6596 - 6599; DOI:
10.1021/ic049397o
PDF
Copper(III) and Vanadium(IV)-Oxo Corrolazines
Joseph P. Fox, Bobby Ramdhanie, Adelajda A. Zareba, Roman S. Czernuszewicz, and David P. Goldberg
pp 6600 - 6608; DOI:
10.1021/ic049384a
PDF
Impact of Variations in Design of Flexible Bitopic Bis(pyrazolyl)methane Ligands and Counterions on the Structures of Silver(I) Complexes: Dominance of Cyclic Dimeric Architecture
Daniel L. Reger, Russell P. Watson, James R. Gardinier, and Mark D. Smith
pp 6609 - 6619; DOI:
10.1021/ic0491377
PDF
New Types of Heterospin Complexes from trans-Oxamido-Bridged Copper(II) Binuclear Units and Nitronyl Nitroxide Radicals: Crystal Structure and Magnetic Characterization
Zhiliang Liu, Zhengliang Lü, Deqing Zhang, Zonghui Jiang, Licun Li, Caiming Liu, and Daoben Zhu
pp 6620 - 6627; DOI:
10.1021/ic049247d
PDF
Structure-Energy Relations in Methylcobalamin with and without Bound Axial Base
Carme Rovira, Xevi Biarnés, and Karel Kunc
pp 6628 - 6632; DOI:
10.1021/ic049810s
PDF
Magnetic Ordering in Iron Tricyanomethanide
Ralf Feyerherm, Anja Loose, Sven Landsgesell, and Jamie L. Manson
pp 6633 - 6639; DOI:
10.1021/ic049423i
PDF
Uranium (III) Scorpionates: Synthesis and Structure of [(TpMe2)2U{N(C6H5)2}] and [(TpMe2)2U{N(SiMe3)2}]
Maria Augusta Antunes, Gregory M. Ferrence, Ângela Domingos, Robert McDonald, Carol J. Burns, Josef Takats, and Noémia Marques
pp 6640 - 6643; DOI:
10.1021/ic049204x
PDF
Chiral Recognition and Resolution of the Enantiomers of Supramolecular Triangular Hosts: Synthesis, Circular Dichroism, NMR, and X-ray Molecular Structure of [Li(R,R,R)-{Cp*Rh(5-chloro-2,3-dioxopyridine)}3][-Trisphat]
Lamia Mimassi, Carine Guyard-Duhayon, Marie Noelle Rager, and Hani Amouri
pp 6644 - 6649; DOI:
10.1021/ic049361w
PDF
Synthesis and Characterization of a Discotic Uranium-Containing Liquid Crystal
Jonathan L. Sessler, Wyeth B. Callaway, Stephen P. Dudek, Richard W. Date, and Duncan W. Bruce
pp 6650 - 6653; DOI:
10.1021/ic0492690
PDF
Conformational Flexibility of Nickel(II) Benziporphyrins
Marcin Stpie, Lechosaw Latos-Grayski, and Ludmia Szterenberg
pp 6654 - 6662; DOI:
10.1021/ic049172d
PDF
Silver(I) Arylsulfonates: A Systematic Study of "Softer" Hybrid Inorganic-Organic Solids
Adrien P. Côté and George K. H. Shimizu
pp 6663 - 6673; DOI:
10.1021/ic0491229
PDF
Nature of Metal Binding Sites in Cu(II) Complexes with Histidine and Related N-Coordinating Ligands, As Studied by EXAFS
Flora Carrera, Enrique Sánchez Marcos, Patrick J. Merkling, Jesús Chaboy, and Adela Muñoz-Páez
pp 6674 - 6683; DOI:
10.1021/ic049699q
PDF
A Comparative XAS and X-ray Diffraction Study of New Binuclear Mn(III) Complexes with Catalase Activity. Indirect Effect of the Counteranion on Magnetic Properties
Gema Fernández, Montserrat Corbella, Montserrat Alfonso, Helen Stoeckli-Evans, and Isabel Castro
pp 6684 - 6698; DOI:
10.1021/ic0348897
PDF
New Tetranuclear Cu(II) Complexes: Synthesis, Structure, and Magnetic Properties
Ramesh Kapoor, Ashok Kataria, Paloth Venugopalan, Pratibha Kapoor, Montserrat Corbella, Montserrat Rodríguez, Isabel Romero,, and Antoni Llobet
pp 6699 - 6706; DOI:
10.1021/ic049882j
PDF
A Comparison of Structure and Stability between the Group 11 Halide Tetramers M4X4 (M = Cu, Ag, or Au; X = F, Cl, Br, or I) and the Group 11 Chloride and Bromide Phosphanes (XMPH3)4
Peter Schwerdtfeger, Robert P. Krawczyk, Anton Hammerl, and Reuben Brown
pp 6707 - 6716; DOI:
10.1021/ic0492744
PDF
Well-Defined Calcium Initiators for Lactide Polymerization
Malcolm H. Chisholm, Judith C. Gallucci, and Khamphee Phomphrai
pp 6717 - 6725; DOI:
10.1021/ic0490730
PDF
Decomposition Kinetics of Ni(III)-Peptide Complexes with Histidine and Histamine as the Third Residue
Teweldemedhin M. Tesfai, Brandon J. Green, and Dale W. Margerum
pp 6726 - 6733; DOI:
10.1021/ic049338a
PDF
Density Functional Investigation of Metal-Metal Interactions in Mixed-Valence d2d3 (Cr, Mo, W) and d3d4 (Mn, Tc, Re) Face-Shared [M2Cl9]2- Systems
Germán Cavigliasso, Peter Comba, and Robert Stranger
pp 6734 - 6744; DOI:
10.1021/ic049503m
PDF
Europium(III) Interaction with a Polyaza-Aromatic Extractant Studied by Time-Resolved Laser-Induced Luminescence: A Thermodynamical Approach
Sonia Colette, Badia Amekraz, Charles Madic, Laurence Berthon, Gérard Cote, and Christophe Moulin
pp 6745 - 6751; DOI:
10.1021/ic049311r
PDF
Zn2+-Catalyzed Methanolysis of Phosphate Triesters: A Process for Catalytic Degradation of the Organophosphorus Pesticides Paraoxon and Fenitrothion
William Desloges, Alexei A. Neverov, and R. S. Brown
pp 6752 - 6761; DOI:
10.1021/ic030325r
PDF
Fine Tuning of the Electronic Coupling between Metal Centers in Cyano-Bridged Mixed-Valent Trinuclear Complexes
Pablo Alborés, Leonardo D. Slep, Thomas Weyhermüller, and Luis M. Baraldo
pp 6762 - 6773; DOI:
10.1021/ic0493649
PDF
ZP8, a Neuronal Zinc Sensor with Improved Dynamic Range; Imaging Zinc in Hippocampal Slices with Two-Photon Microscopy
Christopher J. Chang, Elizabeth M. Nolan, Jacek Jaworski, Ken-Ichi Okamoto, Yasunori Hayashi, Morgan Sheng, and Stephen J. Lippard
pp 6774 - 6779; DOI:
10.1021/ic049293d
PDF
Acidities of Platinum(II) -Hydroxo Complexes Bearing Diphosphine Ligands
U. Anandhi and Paul R. Sharp
pp 6780 - 6785; DOI:
10.1021/ic049463m
PDF
Terminal Titanium-Ligand Multiple Bonds. Cleavages of C=O and C=S Double Bonds with Ti Imido Complexes
Shih-Hsien Hsu, Jr-Chiuan Chang, Chun-Liang Lai, Ching-Han Hu, Hon Man Lee, Gene-Hsiang Lee, Shie-Ming Peng, and Jui-Hsien Huang
pp 6786 - 6792; DOI:
10.1021/ic049474f
PDF
Structures and Properties of Ruthenium(II) Complexes of Pyridylamine Ligands with Oxygen-Bound Amide Moieties: Regulation of Structures and Proton-Coupled Electron Transfer
Takahiko Kojima, Ken-ichi Hayashi, and Yoshihisa Matsuda
pp 6793 - 6804; DOI:
10.1021/ic0495665
PDF
Functional Superoxide Dismutase Mimics. Structural Characterization and Magnetic Exchange Interactions of Copper(II)-N-Substituted Sulfonamide Dimer Complexes
R. Cejudo-Marín, G. Alzuet, S. Ferrer, J. Borrás, A. Castiñeiras, E. Monzani, and L. Casella
pp 6805 - 6814; DOI:
10.1021/ic049718w
PDF
Organometallic Derivatives of Fullerenes: A DFT Study of (2-Cx){Pt(PH3)2}n (x = 60, 70, 84; n = 1-6)
Josep M. Campanera, Jordi Muñoz, Jordi Vázquez, Carles Bo, and Josep M. Poblet
pp 6815 - 6821; DOI:
10.1021/ic048996s
PDF
A New Tridentate Pincer Phosphine/N-Heterocyclic Carbene Ligand: Palladium Complexes, Their Structures, and Catalytic Activities
Hon Man Lee, Jing Yao Zeng, Ching-Han Hu, and Ming-Tsung Lee
pp 6822 - 6829; DOI:
10.1021/ic049492x
PDF
Crystal Structures of Sr4Sn2Se9 and Sr4Sn2Se10 and the Oxidation State of Tin in an Unusual Geometry
Regina Pocha and Dirk Johrendt
pp 6830 - 6837; DOI:
10.1021/ic049663y
PDF
Rhodium-Hydrido-Benzylamine-Triphenylphosphine Complexes: Solid-State and Solution Structures and Implications in Catalyzed Imine Hydrogenation
Paolo Marcazzan, Brian O. Patrick, and Brian R. James
pp 6838 - 6841; DOI:
10.1021/ic049227b
PDF
An Unusual Open Cubane Structure in a 1,1-Azido- and Alkoxo-Bridged Tetranuclear Copper(II) Complex, [Cu4L2(1,1-N3)2]·5H2O (H3L = N,N'-(2-Hydroxylpropane-1,3-diyl)bis-salicylideneimine)
Yufei Song, Chiara Massera, Olivier Roubeau, Patrick Gamez, Anna Maria Manotti Lanfredi, and Jan Reedijk
pp 6842 - 6847; DOI:
10.1021/ic049317g
PDF
Studies on the Formation of Glutathionylcobalamin: Any Free Intracellular Aquacobalamin Is Likely to Be Rapidly and Irreversibly Converted to Glutathionylcobalamin
Ling Xia, Andrew G. Cregan, Louise A. Berben, and Nicola E. Brasch
pp 6848 - 6857; DOI:
10.1021/ic040022c
PDF
DFT Calculations of Isomer Shifts and Quadrupole Splitting Parameters in Synthetic Iron-Oxo Complexes: Applications to Methane Monoxygenase and Ribonucleotide Reductase
Tiqing Liu, Timothy Lovell, Wen-Ge Han, and LouisNoodleman:
pp 6858 - 6858; DOI:
10.1021/ic0401041
PDF

Issue 22


First Structurally Characterized Actinide Isocyanates
Margaret-Jane Crawford, Peter Mayer, Heinrich Nöth, and Max Suter
pp 6860 - 6862; DOI:
10.1021/ic049078x
PDF
DFT Study on the Five Isomers of PW12O403-: Relative Stabilization upon Reduction
Xavier López and Josep M. Poblet
pp 6863 - 6865; DOI:
10.1021/ic049119p
PDF
Formation of One-Dimensional Metal-Water Chain Containing Cyclic Water Hexamers
Bao-Hui Ye, Bing-Bing Ding, Yan-Qin Weng, and Xiao-Ming Chen
pp 6866 - 6868; DOI:
10.1021/ic049232f
PDF
Quantitative Photochemistry of Cp'Pt(CH3)3 (Cp' = 5-C5H4CH3) in Solution: A Highly Efficient Organometallic Photoinitiator for Hydrosilylation
Vladimir Jakubek and Alistair J. Lees
pp 6869 - 6871; DOI:
10.1021/ic0496222
PDF
Interwoven 2-D Coordination Network Prepared from the Molecular Host Tris(isonicotinoyl)cyclotriguaiacylene and Silver(I) Cobalt(III) Bis(dicarbollide)
Michaele J. Hardie and Christopher J. Sumby
pp 6872 - 6874; DOI:
10.1021/ic049160s
PDF
Observation of Hysteretic Bistability in [CoIIICp2]+[FeIIII4]-
Jesse M. Migliori, William M. Reiff, Atta M. Arif, and Joel S. Miller
pp 6875 - 6877; DOI:
10.1021/ic049000g
PDF
1-D Infinite Array of Metalloporphyrin Cages
Long Pan, Xiaoying Huang, Hoa-Loan N. Phan, T. J. Emge, Jing Li, and Xiaotai Wang
pp 6878 - 6880; DOI:
10.1021/ic049141i
PDF
A Three-Dimensional, Noninterpenetrating Metal-Organic Framework with the Moganite Topology: A Simple (42.62.82)(4.64.8)2 Net Containing Two Kinds of Topologically Nonequivalent Points
Cheng-Yong Su, Mark D. Smith, Andrea M. Goforth, and Hans-Conrad zur Loye
pp 6881 - 6883; DOI:
10.1021/ic048812+
PDF
Low-Dimensional Hybrid Copper Halides with Novel D6R Cu6I6 Cores
Guanghua Li, Zhan Shi, Xiaomin Liu, Zhimin Dai, and Shouhua Feng
pp 6884 - 6886; DOI:
10.1021/ic049164x
PDF
Structure of a Discrete Hexadecameric Water Cluster in a Metal-Organic Framework Structure
Sujit K. Ghosh and Parimal K. Bharadwaj
pp 6887 - 6889; DOI:
10.1021/ic049111f
PDF
In Situ Reduction of Copper(II) Forming an Unusually Air Stable Linear Complex of Copper(I) with a Fluorescent Tag
Sandip Banthia and Anunay Samanta
pp 6890 - 6892; DOI:
10.1021/ic0490019
PDF
[(IMo7O26)2]6-: A Missing Link between Molecular and Solid Oxides
Daisuke Honda, Tomoji Ozeki, and Atsushi Yagasaki
pp 6893 - 6895; DOI:
10.1021/ic0490425
PDF
Synthesis of Ru(II) Complexes of N-Heterocyclic Carbenes and Their Promising Photoluminescence Properties in Water
Seung Uk Son, Kang Hyun Park, Young-Shin Lee, Bo Yun Kim, Cheol Ho Choi, Myoung Soo Lah, Yun Hee Jang, Du-Jeon Jang, and Young Keun Chung
pp 6896 - 6898; DOI:
10.1021/ic049514f
PDF
One-Dimensional Octacyanomolybdate-Based Cu(II)-Mo(V) Bimetallic Assembly with a Novel Rope-Ladder Chain Structure
Young Sin You, Dohyeon Kim, Youngkyu Do, Sang Jun Oh, and Chang Seop Hong
pp 6899 - 6901; DOI:
10.1021/ic048856i
PDF
Liberation of Pnicogen Chains from Cu2P1.8As1.2I2: Synthesis and Characterization of a New Allotrope of P-As
Buddhimathie Jayasekera, Kanchana Somaskandan, and Stephanie L. Brock
pp 6902 - 6904; DOI:
10.1021/ic0490223
PDF
X-ray Crystal Structures of [XF6][Sb2F11] (X = Cl, Br, I); 35,37Cl, 79,81Br, and 127I NMR Studies and Electronic Structure Calculations of the XF6+ Cations
John F. Lehmann, Gary J. Schrobilgen, Karl O. Christe, Andreas Kornath, and Reijo J. Suontamo
pp 6905 - 6921; DOI:
10.1021/ic040015o
PDF
Local Structure and Charge Distribution in the UO2-U4O9 System
Steven D. Conradson, Dario Manara, Franck Wastin, David L. Clark, Gerard H. Lander, Luis A. Morales, Jean Rebizant, and Vincenzo V. Rondinella
pp 6922 - 6935; DOI:
10.1021/ic049748z
PDF
Binding of Inorganic Oxoanions to Macrocyclic Ligands: Effect of the Degree of Protonation on Supramolecular Assemblies Formed by Phosphate and [18]aneN6
Andrew C. Warden, Mark Warren, Milton T. W. Hearn, and Leone Spiccia
pp 6936 - 6943; DOI:
10.1021/ic049633v
PDF
Stepwise Synthesis, Structures, and Reactivity of Mono-, Di-, and Trimetallic Metal Complexes with a 6 + 6 Quinonoid Zwitterion
Jean-philippe Taquet, Olivier Siri, Pierre Braunstein, and Richard Welter
pp 6944 - 6953; DOI:
10.1021/ic049263a
PDF
Reaction Products of W(CO)6 with Formamidines; Electronic Structure of a W2(-CO)2 Core with Unsymmetric Bridging Carbonyls
F. Albert Cotton, James P. Donahue, Michael B. Hall, Carlos A. Murillo, and Dino Villagrán
pp 6954 - 6964; DOI:
10.1021/ic049116c
PDF
Isolation and Characterization of a Polymeric Lanthanum Citrate
Ricardo Baggio and Mireille Perec
pp 6965 - 6968; DOI:
10.1021/ic049165p
PDF
Electrochemical, Spectral, and Computational Studies of Metalloporphyrin Dimers Formed by Cation Complexation of Crown Ether Cavities
Raghu Chitta, Lisa M. Rogers, Amber Wanklyn, Paul A. Karr, Pawan K. Kahol, Melvin E. Zandler, and Francis D'Souza
pp 6969 - 6978; DOI:
10.1021/ic0497228
PDF
Spectroscopic Properties and Electronic Structure of Pentammineruthenium(II) Dinitrogen Oxide and Corresponding Nitrosyl Complexes: Binding Mode of N2O and Reactivity
Florian Paulat, Torben Kuschel, Christian Näther, V. K. K. Praneeth, Ole Sander, and Nicolai Lehnert
pp 6979 - 6994; DOI:
10.1021/ic049302i
PDF
Titanatranes Derailed: Static and Dynamic Triethanolamine Slippage Induced by Polyphenoxide Chelation
Aaron G. Maestri and Seth N. Brown
pp 6995 - 7004; DOI:
10.1021/ic0492901
PDF
A Europium-151 Mössbauer Spectral Study of Eu14MnP11, Eu14MnAs11, and Eu14MnSb11
Raphaël P. Hermann, Fernande Grandjean, Susan M. Kauzlarich, Jiong Jiang, Shawna Brown, and Gary J. Long
pp 7005 - 7013; DOI:
10.1021/ic0491682
PDF
Solid-State Coordination Chemistry of the Oxomolybdate-Organodiphosphonate/Nickel-Organoimine System: Structural Influences of the Secondary Metal Coordination Cation and Diphosphonate Tether Lengths
Eric Burkholder, Vladimir Golub, Charles J. O'Connor, and Jon Zubieta
pp 7014 - 7029; DOI:
10.1021/ic049201k
PDF
Theoretical Investigations of the Electronic Structure and Spectroscopy of Mononuclear, Non-Heme {Fe-NO}6 Complexes
Shannon N. Greene and Nigel G. J. Richards
pp 7030 - 7041; DOI:
10.1021/ic0499695
PDF
Preparation and Characterization of Novel Inorganic-Organic Hybrid Materials Containing Rare, Mixed-Halide Anions of Bismuth(III)
Andrea M. Goforth, Mark D. Smith, LeRoy Peterson, Jr., and Hans-Conrad zur Loye
pp 7042 - 7049; DOI:
10.1021/ic049212d
PDF
Antifluorite-Type Lithium Chromium Oxide Nitrides: Synthesis, Structure, Order, and Electrochemical Properties
Jordi Cabana, Christopher D. Ling, Judith Oró-Solé, Damien Gautier, Gerard Tobías, Stefan Adams, Enric Canadell, and M. Rosa Palacín
pp 7050 - 7060; DOI:
10.1021/ic049138z
PDF
Electronic Interaction in an Outer-Sphere Mixed-Valence Double Salt: A Polarized Neutron Diffraction Study of K3(MnO4)2
Roderick D. Cannon, Upali A. Jayasooriya, Claire Tilford, Christopher E. Anson, Frank E. Sowrey, David R. Rosseinsky, John A. Stride, Francis Tasset, Eric Ressouche, Ross P. White, and Rafik Ballou
pp 7061 - 7067; DOI:
10.1021/ic0492340
PDF
Rhenium(V) Oxo Complexes with N-Heterocyclic Carbenes
Theresa I. Kückmann and Ulrich Abram
pp 7068 - 7074; DOI:
10.1021/ic0497578
PDF
Supramolecular Copper Hydroxide Tennis Balls: Self-Assembly, Structures, and Magnetic Properties of Octanuclear [Cu8L8(OH)4]4+ Clusters (HL = N-(2-Pyridylmethyl)acetamide)
Arunendu Mondal, Yang Li, Masood A. Khan, Joseph H. Ross, Jr., and Robert P. Houser
pp 7075 - 7082; DOI:
10.1021/ic0493292
PDF
Tuning of Redox Potentials for the Design of Ruthenium Anticancer Drugs - an Electrochemical Study of [trans-RuCl4L(DMSO)]- and [trans-RuCl4L2]- Complexes, where L = Imidazole, 1,2,4-Triazole, Indazole
Erwin Reisner, Vladimir B. Arion, M. Fátima C. Guedes da Silva, Roman Lichtenecker, Anna Eichinger, Bernhard K. Keppler, Vadim Yu. Kukushkin, and Armando J. L. Pombeiro
pp 7083 - 7093; DOI:
10.1021/ic049479c
PDF
Stabilization of a Subvalent Oxidation State of Bismuth in N,N-Dimethylthioformamide Solution: An EXAFS, UV-Vis, IR, and Cyclic Voltammetry Study
Krzysztof Lyczko, Aleksander Bilewicz, and Ingmar Persson
pp 7094 - 7100; DOI:
10.1021/ic0400787
PDF
Synthesis and Properties of Palladium Diselenolenes: X-ray Crystal Structures of [Pd{SeC(R1)=C(R2)Se}(PBu3)2] [R1, R2 = (CH2)n, n = 4, 5, 6]
Susan Ford, Christopher P. Morley, and Massimo Di Vaira
pp 7101 - 7110; DOI:
10.1021/ic040069y
PDF
Zirconium, Hafnium, and Tantalum Amide Silyl Complexes: Their Preparation and Conversion to Metallaheterocyclic Complexes via -Hydrogen Abstraction by Silyl Ligands
Xianghua Yu, Siwei Bi, Ilia A. Guzei, Zhenyang Lin, and Zi-Ling Xue
pp 7111 - 7119; DOI:
10.1021/ic049023v
PDF
Synthesis and Characterization of Heavier Dioxouranium(VI) Dihalides
Margaret-Jane Crawford, Arkady Ellern, Konstantin Karaghiosoff, Peter Mayer, Heinrich Nöth, and Max Suter
pp 7120 - 7126; DOI:
10.1021/ic0354926
PDF
Mononuclear and Dinuclear Monoperoxovanadium(V) Complexes with a Hetero Ligand. 1.1 Self-Decomposition Reaction, Detection of Reactive Oxygen Species, and Oxidizing Ability
Kan Kanamori, Kazuya Nishida, Nanako Miyata, Toshiyuki Shimoyama, Kaori Hata, Chie Mihara, Ken-ichi Okamoto, Yuriko Abe, Shingo Hayakawa, and Seiichi Matsugo
pp 7127 - 7140; DOI:
10.1021/ic030292f
PDF
Cation Mobility and Kinetics of Ion Exchange in Zirconium Hydrogen Monothiophosphate Hydrate, Zr(HPO3S)2·1.5H2O
I. A. Stenina, A. D. Aliev, P. K. Dorhout, and A. B. Yaroslavtsev
pp 7141 - 7145; DOI:
10.1021/ic035293m
PDF
Solid Mercury Dihydride: Mercurophilic Bonding in Molecular HgH2 Polymers
Xuefeng Wang and Lester Andrews
pp 7146 - 7150; DOI:
10.1021/ic049100m
PDF
Effects of Peripheral Substituents and Axial Ligands on the Electronic Structure and Properties of Iron Phthalocyanine
Meng-Sheng Liao, Tapas Kar, Sergiu M. Gorun, and Steve Scheiner
pp 7151 - 7161; DOI:
10.1021/ic035263j
PDF
Synthesis, Characterization, and Crystal Structures of Novel Intramolecularly Base-Stabilized Borane Derivatives with Six- and Seven-Membered Chelate Rings
Harbi T. Al-Masri, Joachim Sieler, Peter Lönnecke, Peter C. Junk, and Evamarie Hey-Hawkins
pp 7162 - 7169; DOI:
10.1021/ic049352n
PDF
Copper(II) Complexes with Substituted Thiosemicarbazones of -Ketoglutaric Acid: Synthesis, X-ray Structures, DNA Binding Studies, and Nuclease and Biological Activity
Monica Baldini, Marisa Belicchi-Ferrari, Franco Bisceglie, Pier Paolo Dall'Aglio, Giorgio Pelosi, Silvana Pinelli, and Pieralberto Tarasconi
pp 7170 - 7179; DOI:
10.1021/ic049883b
PDF
New Ligand Systems Incorporating Two and Three 4,4'-Bipyridine Units. Characterization of Bi- and Trimetallic Rhodium and Iridium Complexes
Reto Dorta, Romano Dorta, Linda J. W. Shimon, and David Milstein
pp 7180 - 7186; DOI:
10.1021/ic049285x
PDF
Oxidation of Mixed-Valence CoIII/FeII Complexes Reversed at High pH: A Kinetico-Mechanistic Study of Water Oxidation
Paul V. Bernhardt, Fernando Bozoglian, Brendan P. Macpherson, Manuel Martínez, André E. Merbach, Gabriel González, and Beatriz Sienra
pp 7187 - 7195; DOI:
10.1021/ic0493191
PDF
Reactivity of a (-Oxo)(-hydroxo)diiron(III) Diamond Core with Water, Urea, Substituted Ureas, and Acetamide
Sonia Taktak, Sergey V. Kryatov, and Elena V. Rybak-Akimova
pp 7196 - 7209; DOI:
10.1021/ic049371x
PDF
A Platinum-Ruthenium Dinuclear Complex Bridged by Bis(terpyridyl)xanthene
Rei Okamura, Tohru Wada, Katsuji Aikawa, Toshi Nagata, and Koji Tanaka
pp 7210 - 7217; DOI:
10.1021/ic049680n
PDF
Syntheses and Magneto-Structural Study of Several Polynuclear Copper(II) Complexes Derived from 1,3-Bis(dimethylamino)-2-propanolato
M. Salah El Fallah, Albert Escuer, Ramon Vicente, Fatima Badyine, Xavier Solans, and Merce Font-Bardia
pp 7218 - 7226; DOI:
10.1021/ic049408d
PDF
New Details Concerning the Reactions of Nitric Oxide with Vanadium Tetrachloride
Trevor W. Hayton, Brian O. Patrick, and Peter Legzdins
pp 7227 - 7233; DOI:
10.1021/ic0491534
PDF
Selenolate Gold Complexes with Aurophilic Au(I)-Au(I) and Au(I)-Au(III) Interactions
Silvia Canales, Olga Crespo, M. Concepción Gimeno, Peter G. Jones, and Antonio Laguna
pp 7234 - 7238; DOI:
10.1021/ic0493806
PDF
Syntheses and Structural Characterization of a Monomeric Tin(II) Diamide and a Novel Chlorotin(II) Amide Trimer
Yongjun Tang, Ana M. Felix, Lev N. Zakharov, Arnold L. Rheingold, and Richard A. Kemp
pp 7239 - 7242; DOI:
10.1021/ic049154w
PDF
Addition of Pt(PBut3) Groups to Ru5(CO)12(6-C6H6)(5-C). Synthesis, Structures, and Dynamical Activity
Richard D. Adams, Burjor Captain, Perry J. Pellechia, and Lei Zhu
pp 7243 - 7249; DOI:
10.1021/ic049004l
PDF
Redox-Active Polymers Based on Nonbridged Metal-Metal Bonds. Electrochemical Formation of [Os(bpy)(CO)(L)]n (bpy = 2,2'-bipyridine; L = CO, MeCN) and of Their Reduced Forms: A Spectroelectrochemical Study
Frantiek Hartl, Taasje Mahabiersing, Sylvie Chardon-Noblat, Philippe Da Costa, and Alain Deronzier
pp 7250 - 7258; DOI:
10.1021/ic049216i
PDF

Issue 23


Photoinitiated DNA Binding by cis-[Ru(bpy)2(NH3)2]2+
Tanya N. Singh and Claudia Turro
pp 7260 - 7262; DOI:
10.1021/ic049075k
PDF
Reversible Electrochemical Conversion between Rh(II) and Rh(III) States in Rh Porphyrin Adsorbed on Carbon Black
Shin-ichi Yamazaki, Yusuke Yamada, and Kazuaki Yasuda
pp 7263 - 7265; DOI:
10.1021/ic0490472
PDF
Pentadecadentate Chelating Ligands as Building Blocks for a {Fe6} Cage with 12 Exo-Coordinated Sodium Cations
Geoffrey J. T. Cooper, Hamera Abbas, Paul Kögerler, De-Liang Long, and Leroy Cronin
pp 7266 - 7268; DOI:
10.1021/ic049068w
PDF
Structure and Magnetic Properties of a Giant Cu44II Aggregate Which Packs with a Zeotypic Superstructure
Muralee Murugesu, Rodolphe Clérac, Christopher E. Anson, and Annie K. Powell
pp 7269 - 7271; DOI:
10.1021/ic0487171
PDF
Synthesis, Characterization, and Reactivity of New Copper(II) Complexes of 2-Methylthio-N-(2-pyridylmethyl)acetamide
Eric L. Klein, Masood A. Khan, and Robert P. Houser
pp 7272 - 7274; DOI:
10.1021/ic049136e
PDF
Ditopic Double Pincer Palladacycle Catalyst for C-C Coupling
Md. Alamgir Hossain, Simone Lucarini, Douglas Powell, and Kristin Bowman-James
pp 7275 - 7277; DOI:
10.1021/ic0489645
PDF
Gas-Phase and Solution-Phase Polymerization of Epoxides by Cr(salen) Complexes: Evidence for a Dinuclear Cationic Mechanism
Eva Schön, Xiangyang Zhang, Zhiping Zhou, Malcolm H. Chisholm, and Peter Chen
pp 7278 - 7280; DOI:
10.1021/ic049120o
PDF
Modeling the Peroxide/Superoxide Continuum in 1:1 Side-on Adducts of O2 with Cu
Benjamin F. Gherman and Christopher J. Cramer
pp 7281 - 7283; DOI:
10.1021/ic049958b
PDF
The Renaissance of Aluminum Chemistry
Herbert W. Roesky
pp 7284 - 7293; DOI:
10.1021/ic0400641
PDF
New 1:3 Type Nickel-Bis(dithiolene) Salt (FcCHCHPymCH3)[Ni(dmit)2]3 (dmit: 2-Thioxo-1,3-dithiole-4,5-dithiolate): Its Electrocrystallization, Crystal Structure, Electrical Properties, and Electronic Band Structure Analysis
Yoon-Kyoung Han, Dong-Kyun Seo, Haeyong Kang, Woun Kang, and Dong-Youn Noh
pp 7294 - 7300; DOI:
10.1021/ic0497432
PDF
Synthesis, Structure, and Cooperative Proton-Electron Transfer Reaction of Bis(5,6-diethylpyrazinedithiolato)metal Complexes (M = Ni, Pd, Pt)
Takashi Kubo, Misako Ohashi, Katsuaki Miyazaki, Akio Ichimura, and Kazuhiro Nakasuji
pp 7301 - 7307; DOI:
10.1021/ic049621+
PDF
DOTP-Manganese and -Nickel Complexes: from a Tetrahedral Network with 12-Membered Rings to an Ionic Phosphonate
Deyuan Kong, Dmitri G. Medvedev, and Abraham Clearfield
pp 7308 - 7314; DOI:
10.1021/ic040076m
PDF
A Family of Mn16 Single-Molecule Magnets from a Reductive Aggregation Route
Philippa King, Wolfgang Wernsdorfer, Khalil A. Abboud, and George Christou
pp 7315 - 7323; DOI:
10.1021/ic048906j
PDF
Nonoxovanadium(IV) and Oxovanadium(V) Complexes with Mixed O, X, O-Donor Ligands (X = S, Se, P, or PO)
Tapan K. Paine, Thomas Weyhermüller, Leonardo D. Slep, Frank Neese, Eckhard Bill, Eberhard Bothe, Karl Wieghardt, and Phalguni Chaudhuri
pp 7324 - 7338; DOI:
10.1021/ic040052f
PDF
Size and Surface Effects of Prussian Blue Nanoparticles Protected by Organic Polymers
Takashi Uemura, Masaaki Ohba, and Susumu Kitagawa
pp 7339 - 7345; DOI:
10.1021/ic0488435
PDF
Terphenyl Ligand Stabilized Lead(II) Derivatives: Steric Effects and Lead-Lead Bonding in Diplumbenes
Shirley Hino, Marilyn Olmstead, Andrew D. Phillips, Robert J. Wright, and Philip P. Power
pp 7346 - 7352; DOI:
10.1021/ic049174y
PDF
Multi-Iron Silicotungstates: Synthesis, Characterization, and Stability Studies of Polyoxometalate Dimers
Travis M. Anderson, Wade A. Neiwert, Kenneth I. Hardcastle, and Craig L. Hill
pp 7353 - 7358; DOI:
10.1021/ic049517s
PDF
Mononuclear and Binuclear Wirelike Ruthenium(II) Complexes with Oligo-diethynyl-thiophene Bridged Back-to-Back Terpyridine Ligands: Synthesis and Electrochemical and Photophysical Properties
Andrea Barbieri, Barbara Ventura, Francesco Barigelletti, Antoinette De Nicola, Manuel Quesada, and Raymond Ziessel
pp 7359 - 7368; DOI:
10.1021/ic0493043
PDF
Influence of Anionic Functions on the Coordination and Photophysical Properties of Lanthanide(III) Complexes with Tridentate Bipyridines
Steve Comby, Daniel Imbert, Anne-Sophie Chauvin, Jean-Claude G. Bünzli, Loïc J. Charbonnière, and Raymond F. Ziessel
pp 7369 - 7379; DOI:
10.1021/ic049118x
PDF
Ultrafast Photochemical Dissociation of an Equatorial CO Ligand from trans(X,X)-[Ru(X)2(CO)2(bpy)] (X = Cl, Br, I): A Picosecond Time-Resolved Infrared Spectroscopic and DFT Computational Study
Anders Gabrielsson, Stanislav Záli, Pavel Matousek, Mike Towrie, and Antonín Vlek Jr.
pp 7380 - 7388; DOI:
10.1021/ic049548n
PDF
Modulation of Molybdenum-Centered Redox Potentials and Electron-Transfer Rates by Sulfur versus Oxygen Ligation
Darrell Uhrhammer and Franklin A. Schultz
pp 7389 - 7395; DOI:
10.1021/ic040082i
PDF
Silver(I) Complexes of a Sterically Demanding Fluorinated Triazapentadienyl Ligand [N{(C3F7)C(Dipp)N}2]- (Dipp = 2,6-Diisopropylphenyl)
H. V. Rasika Dias and Shreeyukta Singh
pp 7396 - 7402; DOI:
10.1021/ic0491231
PDF
Phosphorus-Nitrogen Donor Interaction Leading to Atrane Formation in Phosphate and Oxyphosphorane Compositions. Implications for Phosphoryl Transfer Enzymes1
Natalya V. Timosheva, A. Chandrasekaran, and Robert R. Holmes
pp 7403 - 7411; DOI:
10.1021/ic040073+
PDF
Kinetics and Mechanisms of Bromine Chloride Reactions with Bromite and Chlorite Ions
Ihab N. Odeh, Jeffrey S. Nicoson, Kara E. Huff Hartz, and Dale W. Margerum
pp 7412 - 7420; DOI:
10.1021/ic048982m
PDF
Molecular Design of Luminescence Ion Probes for Various Cations Based on Weak Gold(I)···Gold(I) Interactions in Dinuclear Gold(I) Complexes
Chi-Kwan Li, Xiao-Xia Lu, Keith Man-Chung Wong, Chui-Ling Chan, Nianyong Zhu, and Vivian Wing-Wah Yam
pp 7421 - 7430; DOI:
10.1021/ic049094u
PDF
An Investigation of Staudinger Reactions Involving cis-1,3,5-Triazidocyclohexane and Tri(alkylamino)phosphines
Xiaodong Liu, Natesan Thirupathi, Ilia A. Guzei, and John G. Verkade
pp 7431 - 7440; DOI:
10.1021/ic0492845
PDF
Alkyl- and Aryl-Substituted Corroles. 5. Synthesis, Physicochemical Properties, and X-ray Structural Characterization of Copper Biscorroles and Porphyrin-Corrole Dyads
Roger Guilard, Claude P. Gros, Jean-Michel Barbe, Enrique Espinosa, François Jérôme, Alain Tabard, Jean-Marc Latour, Jianguo Shao, Zhongping Ou, and Karl M. Kadish
pp 7441 - 7455; DOI:
10.1021/ic049651c
PDF
Unusual Reduction of Ammonium Heptamolybdate to Novel Molybdenum(IV)-Stabilized Azo Anion Radical Complexes
Anasuya Sanyal, Priyabrata Banerjee, Gene-Hsiang Lee, Shie-Ming Peng, Chen-Hsiung Hung, and Sreebrata Goswami
pp 7456 - 7462; DOI:
10.1021/ic049671e
PDF
Binding of the Oxo-Rhenium(V) Core to Methionine and to N-Terminal Histidine Dipeptides
Christian Tessier, Fernande D. Rochon, and André L. Beauchamp
pp 7463 - 7473; DOI:
10.1021/ic048776e
PDF
Considering FeII/IV Redox Processes as Mechanistically Relevant to the Catalytic Hydrogenation of Olefins by [PhBPiPr3]Fe-Hx Species
Erin J. Daida and Jonas C. Peters
pp 7474 - 7485; DOI:
10.1021/ic0488583
PDF
Selenium and Sulfur Trichalcogenides from the Chalcogenide Exchange Reaction
Juris Meija and Joseph A. Caruso
pp 7486 - 7492; DOI:
10.1021/ic0494206
PDF
Syntheses, Characterization, and Luminescence of PtII-MI (M = Cu, Ag, Au) Heterometallic Complexes by Incorporating Pt(diimine)(dithiolate) with [M2(dppm)2]2+ (dppm = Bis(diphenylphosphino)methane)
Yan-Dan Chen, Li-Yi Zhang, Lin-Xi Shi, and Zhong-Ning Chen
pp 7493 - 7501; DOI:
10.1021/ic049104r
PDF
YlideneIminophosphine Coordination Complexes and Reversible Dissociation of Dichlorophosphetidines
Neil Burford, C. Adam Dyker, Andrew D. Phillips, Heather A. Spinney, Andreas Decken, Robert McDonald, Paul J. Ragogna, and Arnold L. Rheingold
pp 7502 - 7507; DOI:
10.1021/ic049333d
PDF
Effects of Pt···Pt Bonding, Anions, Solvate Molecules, and Hydrogen Bonding on the Self-Association of Chugaev's Cation, a Platinum Complex with a Chelating Carbene Ligand
Jay R. Stork, Marilyn M. Olmstead, and Alan L. Balch
pp 7508 - 7515; DOI:
10.1021/ic049226j
PDF
(Fluoren-9-ylidene)methanedithiolato Complexes of Gold: Synthesis, Luminescence, and Charge-Transfer Adducts1
José Vicente, Pablo González-Herrero, Yolanda García-Sánchez, Peter G. Jones, and Manuel Bardají
pp 7516 - 7531; DOI:
10.1021/ic049132+
PDF
Bridged Di(alkyl- and 4,4,4-trifluorobutylimidazolium) Quaternary Salts Based on p-tert-Butylcalix[4]arene
Chuan-Ming Jin and Jean'ne M. Shreeve
pp 7532 - 7538; DOI:
10.1021/ic049041c
PDF
Synthesis, Structure, Spectroscopic Properties, and Electrochemistry of (1,8,15,22-Tetrasubstituted phthalocyaninato)lead Complexes
Yongzhong Bian, Lei Li, Jianmin Dou, Diana Y. Y. Cheng, Renjie Li, Changqin Ma, Dennis K. P. Ng, Nagao Kobayashi, and Jianzhuang Jiang
pp 7539 - 7544; DOI:
10.1021/ic049080o
PDF
Chlorine Dioxide Reduction by Aqueous Iron(II) through Outer-Sphere and Inner-Sphere Electron-Transfer Pathways
Lu Wang, Ihab N. Odeh, and Dale W. Margerum
pp 7545 - 7551; DOI:
10.1021/ic048809q
PDF
Synthesis and Characterization of Bismuth Single-Crystalline Nanowires and Nanospheres
Junwei Wang, Xun Wang, Qing Peng, and Yadong Li
pp 7552 - 7556; DOI:
10.1021/ic049129q
PDF

Issue 24


The First Sideways-Bonded Peroxo Complex for a Tetraaminecobalt(III) Species
A. F. M. Mokhlesur Rahman, W. Gregory Jackson, and Anthony C. Willis
pp 7558 - 7560; DOI:
10.1021/ic040044z
PDF
Immobilization of Phosphines on Silica: Identification of Byproducts via 31P CP/MAS Studies of Model Alkyl-, Aryl-, and Ethoxyphosphonium Salts
J. Sommer, Y. Yang, D. Rambow, and J. Blümel
pp 7561 - 7563; DOI:
10.1021/ic049065j
PDF
Multiple Coordination Geometries Supported by Methylene-Linked Guanidines
Sarah H. Oakley, Martyn P. Coles, and Peter B. Hitchcock
pp 7564 - 7566; DOI:
10.1021/ic0495416
PDF
Facile Formation of Molybdenum(VI) Monooxo Aryloxides MoO(OAr)4-nCln from Molybdenum Dioxo Dichloride
Tracy A. Hanna, Amit K. Ghosh, Catalina Ibarra, Lev N. Zakharov, Arnold L. Rheingold, and William H. Watson
pp 7567 - 7569; DOI:
10.1021/ic048976q
PDF
The First, Discrete Zn4 Tetrahedron with a Selenium Atom in the Center: X-ray Structure and Solution Study of [Zn4(4-Se){Se2P(OPr)2}6]
Bidyut Kumar Santra, Chiu-Mine Hung, Ben-Jie Liaw, Ju-Chun Wang, and C. W. Liu
pp 7570 - 7572; DOI:
10.1021/ic048791j
PDF
Isomerization and Oxygen Atom Transfer Reactivity in Oxo-Mo Complexes of Relevance to Molybdoenzymes
Justin T. Hoffman, Simon Einwaechter, Balwant S. Chohan, Partha Basu, and Carl J. Carrano
pp 7573 - 7575; DOI:
10.1021/ic048775m
PDF
Superloading of Tin Ligands into Rhodium and Iridium Carbonyl Cluster Complexes
Richard D. Adams, Burjor Captain, Jack L. Smith, Jr., Michael B. Hall, Chad L. Beddie, and Charles Edwin Webster
pp 7576 - 7578; DOI:
10.1021/ic0489589
PDF
Assembly of Positively Charged Porphyrins Driven by Metal Ions: A Novel Polymeric Arrangement of Cationic Metalloporphyrin
Silvano Geremia, Luigi Di Costanzo, Giorgio Nardin, Lucio Randaccio, Roberto Purrello, Domenico Sciotto, Rosaria Lauceri, and Fabio Pichierri
pp 7579 - 7581; DOI:
10.1021/ic049336q
PDF
Porphyrin Supermolecules: Synthesis and Self-Assembly Features of Zinc-5-(3'-pyridyl)-10,15,20-tris(4'-hydroxyphenyl)porphyrin
Mikki Vinodu, Zafra Stein, and Israel Goldberg
pp 7582 - 7584; DOI:
10.1021/ic049374+
PDF
Cobalt and Manganese Nets via Their Wires: Facile Transformation in Metal-Diorganophosphates
Ramasamy Pothiraja, Malaichamy Sathiyendiran, Ray J. Butcher, and Ramaswamy Murugavel
pp 7585 - 7587; DOI:
10.1021/ic048781i
PDF
[Gd-AAZTA]-: A New Structural Entry for an Improved Generation of MRI Contrast Agents
Silvio Aime, Luisella Calabi, Camilla Cavallotti, Eliana Gianolio, Giovanni B. Giovenzana, Pietro Losi, Alessandro Maiocchi, Giovanni Palmisano, and Massimo Sisti
pp 7588 - 7590; DOI:
10.1021/ic0489692
PDF
Observation of an Unprecedented Cu Bis-His Site: Crystal Structure of the H129V Mutant of Nitrite Reductase
Mark J. Ellis, Svetlana V. Antonyuk, Richard W. Strange, Gary Sawers, Robert R. Eady, and S. Samar Hasnain
pp 7591 - 7593; DOI:
10.1021/ic048966p
PDF
Magnetic Anisotropy of a High-Spin Octanuclear Nickel(II) Complex with a meso-Helicate Core
Emilio Pardo, Isidoro Morales-Osorio, Miguel Julve, Francesc Lloret, Joan Cano, Rafael Ruiz-García, Jorge Pasán, Catalina Ruiz-Pérez, Xavier Ottenwaelder, and Yves Journaux
pp 7594 - 7596; DOI:
10.1021/ic048965x
PDF
Anion-Templated Synthesis of Metallacages as a Means for the Colorimetric Detection of Chlorides
Pilar Diaz, D. Michael P. Mingos, Ramón Vilar, Andrew J. P. White, and David J. Williams
pp 7597 - 7604; DOI:
10.1021/ic049508j
PDF
Mixed Valence Mn(II)/Mn(III) [3 × 3] Grid Complexes: Structural, Electrochemical, Spectroscopic, and Magnetic Properties
Laurence K. Thompson, Timothy L. Kelly, Louise N. Dawe, Hilde Grove, Martin T. Lemaire, Judith A. K. Howard, Elinor C. Spencer, Craig J. Matthews, Stuart T. Onions, Simon J. Coles, Peter N. Horton, Michael B. Hursthouse, and Mark E. Light
pp 7605 - 7616; DOI:
10.1021/ic040083a
PDF
Selective Solid-Liquid Extraction of Lithium Halide Salts Using a Ditopic Macrobicyclic Receptor
Joseph M. Mahoney, Alicia M. Beatty, and Bradley D. Smith
pp 7617 - 7621; DOI:
10.1021/ic049066b
PDF
Synthesis and Characterization of PdII Complexes with Bis-Pyridinium and Isoquinolinium N-Ylides: Moderate C-H···O=C Intramolecular Hydrogen Bonds as Source of Conformational Preferences
Agustí Lledós, Jorge J. Carbó, Rafael Navarro, Elena Serrano, and Esteban P. Urriolabeitia
pp 7622 - 7635; DOI:
10.1021/ic040065t
PDF
Why Is Re-Re Bond Formation/Cleavage in [Re(bpy)(CO)3]2 Different from That in [Re(CO)5]2? Experimental and Theoretical Studies on the Dimers and Fragments
Etsuko Fujita and James T. Muckerman
pp 7636 - 7647; DOI:
10.1021/ic048910v
PDF
Oxidative Verdoheme Formation and Stabilization by Axial Isocyanide Ligation
Sankar Prasad Rath, Marilyn M. Olmstead, and Alan L. Balch
pp 7648 - 7655; DOI:
10.1021/ic0491433
PDF
Structure of YAG Crystals Doped/Substituted with Erbium and Ytterbium
ukasz Dobrzycki, Ewa Bulska, Dorota Anna Pawlak, Zygmunt Frukacz, and Krzysztof Woniak
pp 7656 - 7664; DOI:
10.1021/ic049920z
PDF
Synthesis of a Digermane-Containing Tricylic Nonadecadienedione Incorporating an Equivalent of Ring-Opened THF
Amy C. Gottfried, Jia Wang, Erin E. Wilson, Larry W. Beck, Mark M. Banaszak Holl, and Jeff W. Kampf
pp 7665 - 7670; DOI:
10.1021/ic0491027
PDF
Macrocyclic and Lantern Complexes of Palladium(II) with Bis(amidopyridine) Ligands: Synthesis, Structure, and Host-Guest Chemistry
Nancy L. S. Yue, Dana J. Eisler, Michael C. Jennings, and Richard J. Puddephatt
pp 7671 - 7681; DOI:
10.1021/ic048893+
PDF
Steric and Electronic Control over the Reactivity of a Thiolate-Ligated Fe(II) Complex with Dioxygen and Superoxide: Reversible -Oxo Dimer Formation
Roslyn M. Theisen, Jason Shearer, Werner Kaminsky, and Julie A. Kovacs
pp 7682 - 7690; DOI:
10.1021/ic0491884
PDF
Aqueous Speciation Studies of Europium(III) Phosphotungstate
Cheng Zhang, Robertha C. Howell, Kymora B. Scotland, Frances G. Perez, Louis Todaro, and Lynn C. Francesconi
pp 7691 - 7701; DOI:
10.1021/ic049655h
PDF
Computational Modeling of Di-Transition-Metal-Substituted -Keggin Polyoxometalate Anions. Structural Refinement of the Protonated Divacant Lacunary Silicodecatungstate
Djamaladdin G. Musaev, Keiji Morokuma, Yurii V. Geletii, and Craig L. Hill
pp 7702 - 7708; DOI:
10.1021/ic0490674
PDF
Homoleptic Cobalt and Copper Phenolate A2[M(OAr)4] Compounds: The Effect of Phenoxide Fluorination
Marisa C. Buzzeo, Amber H. Iqbal, Charli M. Long, David Millar, Sonal Patel, Matthew A. Pellow, Sahar A. Saddoughi, Abigail L. Smenton, John F. C. Turner, Jay D. Wadhawan, Richard G. Compton, James A. Golen, Arnold L. Rheingold, and Linda H. Doerrer
pp 7709 - 7725; DOI:
10.1021/ic0493954
PDF
Ligand Oxidations in High-Spin Nickel Thiolate Complexes and Zinc Analogues
Balwant S. Chohan, Steven C. Shoner, Julie A. Kovacs, and Michael J. Maroney
pp 7726 - 7734; DOI:
10.1021/ic049110n
PDF
Syntheses, Structure, Some Band Gaps, and Electronic Structures of CsLnZnTe3 (Ln = La, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Y)
Jiyong Yao, Bin Deng, Leif J. Sherry, Adam D. McFarland, Donald E. Ellis, Richard P. Van Duyne, and James A. Ibers
pp 7735 - 7740; DOI:
10.1021/ic040071p
PDF
Synthesis and Characterization of Nitrosyl Diruthenium Complexes. Interaction between NO and CO across the Metal-Metal Bond
Baocheng Han, Jianguo Shao, Zhongping Ou, Tuan D. Phan, Jing Shen, John L. Bear, and Karl M. Kadish
pp 7741 - 7751; DOI:
10.1021/ic048983e
PDF
Synthesis, Characterization, and Electrochemical Relationships of Dinuclear Complexes of Platinum(II) and Platinum(III) Containing Ortho-Metalated Tertiary Arsine Ligands
Martin A. Bennett, Suresh K. Bhargava, Alan M. Bond, Alison J. Edwards, Si-Xuan Guo, Steven H. Privér, A. David Rae, and Anthony C. Willis
pp 7752 - 7763; DOI:
10.1021/ic0498790
PDF
New Family of Lithium Salts for Highly Conductive Nonaqueous Electrolytes
Thomas J. Barbarich, Peter F. Driscoll, Suzette Izquierdo, Lev N. Zakharov, Christopher D. Incarvito, and Arnold L. Rheingold
pp 7764 - 7773; DOI:
10.1021/ic040070x
PDF
Complexes Having the fac-{M(CO)3}+ Core (M = Tc, Re) Useful in Radiopharmaceuticals: X-ray and NMR Structural Characterization and Density Functional Calculations of Species Containing Two sp3 N Donors and One sp3 O Donor
Malgorzata Lipowska, Renzo Cini, Gabriella Tamasi, Xiaolong Xu, Andrew T. Taylor, and Luigi G. Marzilli
pp 7774 - 7783; DOI:
10.1021/ic049544i
PDF
Synthesis and Structure of Nongeminally Substituted Cyclic Phosphazenes with Haloalkyl and Thioester Functional Groups
June-Ho Jung, Srinagesh K. Potluri, Hongming Zhang, and Patty Wisian-Neilson
pp 7784 - 7791; DOI:
10.1021/ic049063z
PDF
Synthesis, Structure, and Magnetic Properties of Heterometallic Dicyanamide-Bridged Cu-Na and Cu-Gd One-Dimensional Polymers
Jean-Pierre Costes, Ghenadie Novitchi, Sergiu Shova, Françoise Dahan, Bruno Donnadieu, and Jean-Pierre Tuchagues
pp 7792 - 7799; DOI:
10.1021/ic048942i
PDF
A Family of Dioxo-Molybdenum(VI) Complexes of N2X Heteroscorpionate Ligands of Relevance to Molybdoenzymes
Brian S. Hammes, Bal S. Chohan, Justin T. Hoffman, Simon Einwächter, and Carl J. Carrano
pp 7800 - 7806; DOI:
10.1021/ic049130p
PDF
Divalent Germanium Compound with a Radical-Anionic Ligand: Molecular Structures of (dpp-BIAN)-GeCl and Its Hydrochloration Products [(dpp-BIAN)(H)2]+[GeCl3]- and [{(dpp-BIAN)(H)2+}2(Cl-)]+[GeCl3]- (dpp-BIAN = 1,2-Bis{(2,6-diisopropylphenyl)imino}acenaphthene)
Igor L. Fedushkin, Natalie M. Khvoinova, Andrey Yu. Baurin, Georgii K. Fukin, Vladimir K. Cherkasov, and Mikhail P. Bubnov
pp 7807 - 7815; DOI:
10.1021/ic048801g
PDF
Nickel(II)-Phenoxyl Radical Complexes: Structure-Radical Stability Relationship
Yuichi Shimazaki, Stefan Huth, Satoru Karasawa, Shun Hirota, Yoshinori Naruta, and Osamu Yamauchi
pp 7816 - 7822; DOI:
10.1021/ic049040k
PDF
Rhenium(IV)-Copper(II) Heterobimetallic Complexes with a Bridge Malonato Ligand. Synthesis, Crystal Structure, and Magnetic Properties
Alicia Cuevas, Raúl Chiozzone, Carlos Kremer, Leopoldo Suescun, Alvaro Mombrú, Donatella Armentano, Giovanni De Munno, Francesc Lloret, Juan Cano, and Juan Faus
pp 7823 - 7831; DOI:
10.1021/ic0493853
PDF
Influence of Terpyridine as -Acceptor Ligand on the Kinetics and Mechanism of the Reaction of NO with Ruthenium(III) Complexes
Almut Czap, Frank W. Heinemann, and Rudi van Eldik
pp 7832 - 7843; DOI:
10.1021/ic0350685
PDF
Synthesis and Characterization of a Chromium(V) cis-Dioxo Bis(1,10-phenanthroline) Complex and Crystal and Molecular Structures of Its Chromium(III) Precursor
Colin L. Weeks, Aviva Levina, Carolyn T. Dillon, Peter Turner, Ronald R. Fenton, and Peter A. Lay
pp 7844 - 7856; DOI:
10.1021/ic049008q
PDF
Computational Insights into the Acceptor Chemistry of Phosphenium Cations
Bobby D. Ellis, Paul J. Ragogna, and Charles L. B. Macdonald
pp 7857 - 7867; DOI:
10.1021/ic0488738
PDF
Assembling Novel Heterotrimetallic Cu/Co/Ni and Cu/Co/Cd Cores Supported by Diethanolamine Ligand in One-Pot Reactions of Zerovalent Copper with Metal Salts
Dmytro S. Nesterov, Valeriya G. Makhankova, Olga Yu. Vassilyeva, Vladimir N. Kokozay, Larisa A. Kovbasyuk, Brian W. Skelton, and Julia Jezierska
pp 7868 - 7876; DOI:
10.1021/ic048955w
PDF
Mechanistic Variations in the Oxidation of Piloty's Acid by Metal Complexes
Patricia C. Wilkins, Hollie K. Jacobs, Michael D. Johnson, and Aravamudan S. Gopalan
pp 7877 - 7881; DOI:
10.1021/ic049627z
PDF
Mimicking the Two-Dimensional Spectrochemical Series Using Density Functional Computations
Christian Anthon, Jesper Bendix, and Claus E. Schäffer
pp 7882 - 7886; DOI:
10.1021/ic049507r
PDF
Dirhenium Paddlewheel Compounds Supported by N,N'-Dialkylbenzamidinates: Synthesis, Structures, and Photophysical Properties
Michael Q. Dequeant, Patricia M. Bradley, Guo-Lin Xu, Daniel A. Lutterman, Claudia Turro, and Tong Ren
pp 7887 - 7892; DOI:
10.1021/ic0487981
PDF

Issue 25


Enter the Forum...Exit the Paper Submission
Richard Eisenberg
pp 7893 - 7893; DOI:
10.1021/ic040116m
PDF
Metalloprotein Folding
Kara L. Bren, Vincent L. Pecoraro, and Harry B. Gray
pp 7894 - 7896; DOI:
10.1021/ic040121q
PDF
Site Selection in Tandem Arrays of Metal-Binding Domains
Karen R. Thickman, Alisa Davis, and Jeremy M. Berg
pp 7897 - 7901; DOI:
10.1021/ic048850t
PDF
Understanding Metalloprotein Folding Using a de Novo Design Strategy
Debdip Ghosh and Vincent L. Pecoraro
pp 7902 - 7915; DOI:
10.1021/ic048939z
PDF
Design, Folding, and Activities of Metal-Assembled Coiled Coil Proteins
Allison J. Doerr and George L. McLendon
pp 7916 - 7925; DOI:
10.1021/ic0490573
PDF
Role of Cofactors in Folding of the Blue-Copper Protein Azurin
Pernilla Wittung-Stafshede
pp 7926 - 7933; DOI:
10.1021/ic049398g
PDF
Folding, Conformational Changes, and Dynamics of Cytochromes c Probed by NMR Spectroscopy
Kara L. Bren, Jason A. Kellogg, Ravinder Kaur, and Xin Wen
pp 7934 - 7944; DOI:
10.1021/ic048925t
PDF
Insights into Partially Folded or Unfolded States of Metalloproteins from Nuclear Magnetic Resonance
Paola Turano
pp 7945 - 7952; DOI:
10.1021/ic048962k
PDF
Zinc-porphyrin Solvation in Folded and Unfolded States of Zn-cytochrome c
Judy E. Kim, Melanie A. Pribisko, Harry B. Gray, and Jay R. Winkler
pp 7953 - 7960; DOI:
10.1021/ic048972l
PDF
Synthesis and Structure of the Pentacopper(II) Substituted Tungstosilicate [Cu5(OH)4(H2O)2(A--SiW9O33)2]10-
Li-Hua Bi and Ulrich Kortz
pp 7961 - 7962; DOI:
10.1021/ic048689m
PDF
[Co(en)3][Sb12S19]: A New Antimony Sulfide with a Zeolite-like Structure Containing One-Dimensional Channels
Paz Vaqueiro, Ann M. Chippindale, and Anthony V. Powell
pp 7963 - 7965; DOI:
10.1021/ic048985z
PDF
Synthesis and Characterization of a Novel Tantalum Chalcogen-Rich Molecular Cluster with Square Planar Metal Core
Maxim N. Sokolov, Artyom L. Gushchin, Alexandr V. Virovets, Eugenia V. Peresypkina, Svetlana G. Kozlova, and Vladimir P. Fedin
pp 7966 - 7968; DOI:
10.1021/ic0489239
PDF
Photodecarbonylation of Ruthenium Carbonyl Octaethylporphyrin via Stepwise Two-Photon Absorption of Visible Light
Kazuyuki Ishii, Shun-ichi Hoshino, and Nagao Kobayashi
pp 7969 - 7971; DOI:
10.1021/ic0493604
PDF
Energetic Salts from N-Aminoazoles
Hong Xue, Sean W. Arritt, Brendan Twamley, and Jean'ne M. Shreeve
pp 7972 - 7977; DOI:
10.1021/ic048890x
PDF
Influence of the Halogen Ligand on the Near-UV-Visible Spectrum of [Ru(X)(Me)(CO)2(-diimine)] (X = Cl, I; -Diimine = Me-DAB, iPr-DAB; DAB = 1,4-Diaza-1,3-butadiene): An ab Initio and TD-DFT Analysis
S. Záli, N. Ben Amor, and C. Daniel
pp 7978 - 7985; DOI:
10.1021/ic049464e
PDF
Efficient DNA Binding by Optically Pure Ruthenium Tris(bipyridyl) Complexes Incorporating Carboxylic Functionalities. Solution and Structural Analysis
Régis Caspar, Léna Musatkina, Alexander Tatosyan, Hani Amouri, Michel Gruselle, Carine Guyard-Duhayon, Raphaël Duval, and Christine Cordier
pp 7986 - 7993; DOI:
10.1021/ic0494657
PDF
Chiral Induction in Self-Assembled Helicates: CHIRAGEN Type Ligands with Ferrocene Bridging Units
Boris Quinodoz, Gaël Labat, Helen Stoeckli-Evans, and Alex von Zelewsky
pp 7994 - 8004; DOI:
10.1021/ic049913a
PDF
A Novel Chainlike As-V-O Polymer Based on a Transition Metal Complex and a Dimeric Polyoxoanion
Xiao-Bing Cui, Ji-Qing Xu, He Meng, Shou-Tian Zheng, and Guo-Yu Yang
pp 8005 - 8009; DOI:
10.1021/ic0492892
PDF
Anion Ordering and Defect Structure in Ruddlesden-Popper Strontium Niobium Oxynitrides
Gerard Tobías, Daniel Beltrán-Porter, Oleg I. Lebedev, Gustaaf Van Tendeloo, Juan Rodríguez-Carvajal, and Amparo Fuertes
pp 8010 - 8017; DOI:
10.1021/ic049236k
PDF
Fluorescent Coordination Networks of 2,3,6,7,10,11-Hexakis(phenylthio)triphenylene and Silver(I) Triflate
Kunhao Li, Zhengtao Xu, and James C. Fettinger
pp 8018 - 8022; DOI:
10.1021/ic048917c
PDF
Synthesis, Structure, and Complexation of a Large 28-mer Macrocycle Containing Two Binding Sites for Either Anions or Metal Ions
Leroy Cronin, Pamela A. McGregor, Simon Parsons, Simon Teat, Robert O. Gould, Vivienne A. White, Nicholas J. Long, and Neil Robertson
pp 8023 - 8029; DOI:
10.1021/ic049190v
PDF
Snapshots of a Metamorphosing Cu(II) Ground State in a Galactose Oxidase-Inspired Complex
Russell C. Pratt, Liviu M. Mirica, and T. Daniel P. Stack
pp 8030 - 8039; DOI:
10.1021/ic048904z
PDF
Bending, Twisting, and Breaking CuCN Chains to Produce Framework Materials: The Reactions of CuCN with Alkali-Metal Halides
Ann M. Chippindale, Simon J. Hibble, and Andrew R. Cowley
pp 8040 - 8048; DOI:
10.1021/ic049011+
PDF
Structure and Bonding of the Vanadium(III) Hexa-Aqua Cation. 1. Experimental Characterization and Ligand-Field Analysis
Philip L. W. Tregenna-Piggott, David Spichiger, Graham Carver, Beatrice Frey, Roland Meier, Hgni Weihe, John A. Cowan, Garry J. McIntyre, Gernot Zahn, and Anne-Laure Barra
pp 8049 - 8060; DOI:
10.1021/ic049292l
PDF
Structure and Bonding of the Vanadium(III) Hexa-Aqua Cation. 2. Manifestation of Dynamical Jahn-Teller Coupling in Axially Distorted Vanadium(III) Complexes
Philip L. W. Tregenna-Piggott and Graham Carver
pp 8061 - 8071; DOI:
10.1021/ic049291t
PDF
A Chiral Molecular Conductor: Synthesis, Structure, and Physical Properties of [ET]3[Sb2(L-tart)2]·CH3CN (ET = Bis(ethylendithio)tetrathiafulvalene; L-tart = (2R,3R)-(+)-Tartrate)
Eugenio Coronado, José R. Galán-Mascarós, Carlos J. Gómez-García, Ana Murcia-Martínez, and Enric Canadell
pp 8072 - 8077; DOI:
10.1021/ic049257e
PDF
Structure of the Amodiaquine-FPIX Oxo Dimer Solution Complex at Atomic Resolution
Angel C. de Dios, Leah B. Casabianca, Andrew Kosar, and Paul D. Roepe
pp 8078 - 8084; DOI:
10.1021/ic0489948
PDF
Hydrothermal Syntheses, Crystal Structures, and Properties of a Novel Class of 3,3',4,4'-Benzophenone-tetracarboxylate (BPTC) Polymers
Jian Zhang, Zhao-Ji Li, Yao Kang, Jian-Kai Cheng, and Yuan-Gen Yao
pp 8085 - 8091; DOI:
10.1021/ic0491074
PDF
Comparative Kinetics and Mechanism of Oxygen and Sulfur Atom Transfer Reactions Mediated by Bis(dithiolene) Complexes of Molybdenum and Tungsten
Jun-Jieh Wang, Olga P. Kryatova, Elena V. Rybak-Akimova, and R. H. Holm
pp 8092 - 8101; DOI:
10.1021/ic040087f
PDF
Chiral Palladium Template Promoted Asymmetric Hydrophosphination Reaction between Diphenylphosphine and Vinylphosphines
Wee-Chuan Yeo, Si-Yin Tee, Hun-Beng Tan, Geok-Kheng Tan, Lip Lin Koh, and Pak-Hing Leung
pp 8102 - 8109; DOI:
10.1021/ic040091r
PDF
Electronic Structure of Bent Titanocene Complexes with Chelated Dithiolate Ligands
J. Jon A. Cooney, Matthew A. Cranswick, Nadine E. Gruhn, Hemant K. Joshi, and John H. Enemark
pp 8110 - 8118; DOI:
10.1021/ic049207+
PDF
Preparation, Structure Characterization, and Oxidation Activity of Ruthenium Complexes with Tripodal Ligands Bearing Noncovalent Interaction Sites
Koichiro Jitsukawa, Yoshiyuki Oka, Syuhei Yamaguchi, and Hideki Masuda
pp 8119 - 8129; DOI:
10.1021/ic0494399
PDF
Solution Structure and Thermolysis of Co-5'-Deoxyadenosylimidazolylcobamide, a Coenzyme B12 Analogue with an Imidazole Axial Nucleoside
Kenneth L. Brown, Xiang Zou, Rakesh R. Banka, Christopher B. Perry, and Helder M. Marques
pp 8130 - 8142; DOI:
10.1021/ic040079z
PDF
Chlorocarbonyl Trifluoromethanesulfonate, ClC(O)OSO2CF3: Structure and Conformational Properties in the Gaseous and Condensed Phases
Carlos O. Della Védova, Anthony J. Downs, Eleonora Moschione, Simon Parsons, and Rosana M. Romano
pp 8143 - 8149; DOI:
10.1021/ic0489488
PDF
Spin-Frustrated (VO)36+-Triangle-Sandwiching Octadecatungstates as a New Class of Molecular Magnets
Toshihiro Yamase, Eri Ishikawa, Keisuke Fukaya, Hiroyuki Nojiri, Tomohiro Taniguchi, and Tooru Atake
pp 8150 - 8157; DOI:
10.1021/ic049669n
PDF
Preparation of 1-p-Halophenyl and 1-p-Biphenylyl Substituted Monocarbadodecaborate Anions [closo-1-Ar-CB11H11]- by Insertion of Arylhalocarbenes into [nido-B11H14]-
Stefanie Körbe, Damian B. Sowers, Andreas Franken, and Josef Michl
pp 8158 - 8161; DOI:
10.1021/ic049255u
PDF
Structural and Conformational Properties of Fluoroformic Acid Anhydride, FC(O)OC(O)F
Florian Mayer, Heinz Oberhammer, Michael Berkei, Holger Pernice, Helge Willner, Karina Bierbrauer, Maximiliano Burgos Paci, and Gustavo A. Argüello
pp 8162 - 8168; DOI:
10.1021/ic049210t
PDF
Structural, Magnetic, and Transport Properties of the SrTi1-xCoxO3- Perovskite (0 x 0.9)
S. Malo and A. Maignan
pp 8169 - 8175; DOI:
10.1021/ic0490371
PDF
Can the Bis(diboranyl) Structure of B4H10 Be Observed? The Story Continues
Vinutha Ramakrishna and Brian J. Duke
pp 8176 - 8184; DOI:
10.1021/ic049558o
PDF
Alkynyldiphenylphosphine d8 (Pt, Rh, Ir) Complexes: Contrasting Behavior toward cis-[Pt(C6F5)2(THF)2]
Jesús R. Berenguer, María Bernechea, Juan Forniés, Ana García, Elena Lalinde, and M. Teresa Moreno
pp 8185 - 8198; DOI:
10.1021/ic048987j
PDF

Issue 26


Unprecedented (Cu2Ln)n Complexes (Ln = Gd3+, Tb3+): A New "Single Chain Magnet"
Jean-Pierre Costes, Juan Modesto Clemente-Juan, Françoise Dahan, and Julie Milon
pp 8200 - 8202; DOI:
10.1021/ic048921o
PDF
Di-Iron Aza Diphosphido Complexes: Mimics for the Active Site of Fe-Only Hydrogenase, and Effects of Changing the Coordinating Atoms of the Bridging Ligand in[Fe2{-(ECH2)2NR}(CO)6]
Pankaj Das, Jean-François Capon, Frédéric Gloaguen, François Y. Pétillon, Philippe Schollhammer, Jean Talarmin, and Kenneth W. Muir
pp 8203 - 8205; DOI:
10.1021/ic048772+
PDF
Uranyl Complexation by a Schiff-Base, Polypyrrolic Macrocycle
Polly L. Arnold, Alexander J. Blake, Claire Wilson, and Jason B. Love
pp 8206 - 8208; DOI:
10.1021/ic0487070
PDF
Porous Cu-Cd Mixed-Metal-Organic Frameworks Constructed from Cu(Pyac)2 {Bis[3-(4-pyridyl)pentane-2,4-dionato]copper(II)}
Banglin Chen, Frank R. Fronczek, and Andrew W. Maverick
pp 8209 - 8211; DOI:
10.1021/ic048992n
PDF
Bis(pyrazolyl)(thioimidazolyl)borate Ligands: The Missing Member in the N3···S3 Scorpionate Series
Boumahdi Benkmil, Mian Ji, and Heinrich Vahrenkamp
pp 8212 - 8214; DOI:
10.1021/ic048633s
PDF
A Direct Electrochemical Route to Construct a Polymer/Manganese Oxide Layered Structure
Masaharu Nakayama, Hiroki Tagashira, Sayaka Konishi, and Kotaro Ogura
pp 8215 - 8217; DOI:
10.1021/ic048691d
PDF
Design of a Five-Coordinate Heme Protein Maquette: A Spectroscopic Model of Deoxymyoglobin
Jinyou Zhuang, Jennifer H. Amoroso, Ryan Kinloch, John H. Dawson, Michael J. Baldwin, and Brian R. Gibney
pp 8218 - 8220; DOI:
10.1021/ic048502r
PDF
An Antiferromagnetic Mn(III) Chain Bridged by Hydrogencyanamide: [MnIII(5-Brsalen)(1,3-NCNH)]n
Mei Yuan, Song Gao, Hao-Ling Sun, and Gang Su
pp 8221 - 8223; DOI:
10.1021/ic048547s
PDF
A New Inorganic-Organic Hybrid Copper Iodate with Potentially Large Void Volume
Guanghua Li, Zhan Shi, Xiaomin Liu, Zhimin Dai, Lu Gao, and Shouhua Feng
pp 8224 - 8226; DOI:
10.1021/ic049098z
PDF
Evidence for Associative Ligand Exchange Processes on Solvated Lithium Cations
Ralph Puchta, Michael Galle, Nico van Eikema Hommes, Ewa Pasgreta, and Rudi van Eldik
pp 8227 - 8229; DOI:
10.1021/ic0487979
PDF
Three-Dimensional Helical Coordination Networks of a Hexanuclear Manganese Metallamacrocycle as a Helical Tecton
Dohyun Moon, Jiheh Song, Beom Jin Kim, Byoung Jin Suh, and Myoung Soo Lah
pp 8230 - 8232; DOI:
10.1021/ic049393j
PDF
Heteroligated Metallomacrocycles Generated via the Weak-Link Approach
Maxim V. Ovchinnikov, Aaron M. Brown, Xiaogang Liu, Chad A. Mirkin, Lev N. Zakharov, and Arnold L. Rheingold
pp 8233 - 8235; DOI:
10.1021/ic048785n
PDF
Theoretical Study of the Gas-Phase Fe(CO)5 Catalyzed Water Gas Shift Reaction: A New Mechanism Proposed
Susan E. Barrows
pp 8236 - 8238; DOI:
10.1021/ic049159t
PDF
[N(CH2CH2NH3)3][U3O2F13]·2H2O: A Novel Organically Templated Mixed-Valent Uranium Oxyfluoride with a Hybrid Network Structure
Chih-Min Wang, Chia-Hsien Liao, Hsiu-Mei Lin, and Kwang-Hwa Lii
pp 8239 - 8241; DOI:
10.1021/ic0488280
PDF
Homoleptic Lanthanide Triple-Deckers of 5,15-Diazaporphyrin with D2h Symmetry
Na Pan, Yongzhong Bian, Takamitsu Fukuda, Masaki Yokoyama, Renjie Li, Saburo Neya, Jianzhuang Jiang, and Nagao Kobayashi
pp 8242 - 8244; DOI:
10.1021/ic048744r
PDF
Gallium Halide Induced Heterocycle Expansion of Dihalodiphosphadiaryldiazanes [(XPNR)2] to the Corresponding Triphosphatriazanes [(XPNR)3]
Neil Burford, Korey D. Conroy, Jeff C. Landry, Paul J. Ragogna, Michael J. Ferguson, and Robert McDonald
pp 8245 - 8251; DOI:
10.1021/ic049217a
PDF
Nickel Complexes of Carboxylate-Containing Polydentate Ligands as Models for the Active Site of Urease
Håkan Carlsson, Matti Haukka, Azzedine Bousseksou, Jean-Marc Latour, and Ebbe Nordlander
pp 8252 - 8262; DOI:
10.1021/ic049048u
PDF
Voltammetric Reduction of - and *-[S2W18O62]4- and -, -, and -[SiW12O40]4-: Isomeric Dependence of Reversible Potentials of Polyoxometalate Anions Using Data Obtained by Novel Dissolution and Conventional Solution-Phase Processes
Jie Zhang, Alan M. Bond, Peter J. S. Richardt, and Anthony G. Wedd
pp 8263 - 8271; DOI:
10.1021/ic049043x
PDF
Photochemical Organic Oxidations and Dechlorinations with a -Oxo Bridged Heme/Non-Heme Diiron Complex
Ian M. Wasser, H. Christopher Fry, Paul G. Hoertz, Gerald J. Meyer, and Kenneth D. Karlin
pp 8272 - 8281; DOI:
10.1021/ic0490932
PDF
Cu(I)(2,9-Bis(trifluoromethyl)-1,10-phenanthroline)2+ Complexes: Correlation between Solid-State Structure and Photoluminescent Properties
Andrey Yu. Kovalevsky, Milan Gembicky, and Philip Coppens
pp 8282 - 8289; DOI:
10.1021/ic049638s
PDF
Paramagnetic Precursors for Supramolecular Assemblies: Selective Syntheses, Crystal Structures, and Electrochemical and Magnetic Properties of Ru2(O2CMe)4-n(formamidinate)nCl Complexes, n = 1-4
Panagiotis Angaridis, F. Albert Cotton, Carlos A. Murillo, Dino Villagrán, and Xiaoping Wang
pp 8290 - 8300; DOI:
10.1021/ic049108w
PDF
Multiple Pathways for the Oxygenation of a Ruthenium(II) Dithiocarbamate Complex: S-Oxygenation and S-Extrusion
Szeman Ng, Joseph W. Ziller, and Patrick J. Farmer
pp 8301 - 8309; DOI:
10.1021/ic048661a
PDF
The Zinspy Family of Fluorescent Zinc Sensors: Syntheses and Spectroscopic Investigations
Elizabeth M. Nolan and Stephen J. Lippard
pp 8310 - 8317; DOI:
10.1021/ic048778z
PDF
High Covalence in CuSO4 and the Radicalization of Sulfate: An X-ray Absorption and Density Functional Study
Robert K. Szilagyi, Patrick Frank, Serena DeBeer George, Britt Hedman, and Keith O. Hodgson
pp 8318 - 8329; DOI:
10.1021/ic030311l
PDF
Preparation and Characterization of Dimercury(I) Monofluorophosphate(V), Hg2PO3F: Crystal Structure, Thermal Behavior, Vibrational Spectra, and Solid-State 31P and 19F NMR Spectra
Matthias Weil, Michael Puchberger, and Enrique J. Baran
pp 8330 - 8335; DOI:
10.1021/ic048741e
PDF
Synthesis, Structure, and Solution Dynamics of UO22+-Hydroxy Ketone Compounds [UO2(ma)2(H2O)] and [UO2(dpp)(Hdpp)2(H2O)]ClO4 [ma = 3-Hydroxy-2-methyl-4-pyrone, Hdpp = 3-Hydroxy-1,2-dimethyl-4(1H)-pyridone]
Chryssoula Drouza, Volker Gramlich, Michael P. Sigalas, Ioannis Pashalidis, and Anastasios D. Keramidas
pp 8336 - 8345; DOI:
10.1021/ic049167+
PDF
Photochemical Expulsion of the Neutral Monodentate Ligand L in Ru(Terpy*)(Diimine)(L)2+: A Dramatic Effect of the Steric Properties of the Spectator Diimine Ligand
Sylvestre Bonnet, Jean-Paul Collin, Jean-Pierre Sauvage, and Emma Schofield
pp 8346 - 8354; DOI:
10.1021/ic0491736
PDF
Coordinated Hydrazone Ligands as Nucleophiles: Reactions of Fe(papy)2
Aaron Wood, Wasim Aris, and David J. R. Brook
pp 8355 - 8360; DOI:
10.1021/ic0492688
PDF
Unique Hydrogen Bonding Correlating with a Reduced Band Gap and Phase Transition in the Hybrid Perovskites (HO(CH2)2NH3)2PbX4 (X = I, Br)
Nicolas Mercier, Sylvain Poiroux, Amédée Riou, and Patrick Batail
pp 8361 - 8366; DOI:
10.1021/ic048814u
PDF
Palladium(II)-Substituted Tungstosilicate [Cs2K(H2O)7Pd2WO(H2O)(A--SiW9O34)2]9-
Li-Hua Bi, Ulrich Kortz, Bineta Keita, Louis Nadjo, and Horst Borrmann
pp 8367 - 8372; DOI:
10.1021/ic048864z
PDF
Paramagnetism at Ambient Temperature, Diamagnetism at Low Temperature in a Ru26+ Core: Structural Evidence for Zero-Field Splitting
F. Albert Cotton, Carlos A. Murillo, Joseph H. Reibenspies, Dino Villagrán, Xiaoping Wang, and Chad C. Wilkinson
pp 8373 - 8378; DOI:
10.1021/ic048946n
PDF
Synthesis, Crystal Structure from Single-Crystal and Powder X-ray Diffraction Data, and Thermal Behavior of Mixed Potassium Lanthanide Squarates: Thermal Transformations of Layered [Ln(H2O)6]K(H2C4O4)(C4O4)2 into Pillared LnK(C4O4)2 (Ln = Y, La, Gd, Er)
Nathalie Mahé and Thierry Bataille
pp 8379 - 8386; DOI:
10.1021/ic0488839
PDF
A Heterobimetallic Ruthenium(II)-Copper(II) Donor-Acceptor Complex as a Chemodosimetric Ensemble for Selective Cyanide Detection
Cheuk-Fai Chow, Michael H. W. Lam, and Wai-Yeung Wong
pp 8387 - 8393; DOI:
10.1021/ic0492587
PDF
Chiral Organometallic Triangles with Rh-Rh Bonds. 1. Compounds Prepared from Racemic cis-Rh2(C6H4PPh2)2(OAc)2
F. Albert Cotton, Carlos A. Murillo, Xiaoping Wang, and Rongmin Yu
pp 8394 - 8403; DOI:
10.1021/ic0492183
PDF
Bicyclic and Acyclic Diamides: Comparison of Their Aqueous Phase Binding Constants with Nd(III), Am(III), Pu(IV), Np(V), Pu(VI), and U(VI)
Serguei I. Sinkov, Brian M. Rapko, Gregg J. Lumetta, Benjamin P. Hay, James E. Hutchison, and Bevin W. Parks
pp 8404 - 8413; DOI:
10.1021/ic049377m
PDF
Metal Carbonyl Derivatives of Sulfur-Containing Quinones and Hydroquinones: Synthesis, Structures, and Electrochemical Properties
Richard D. Adams and Shaobin Miao
pp 8414 - 8426; DOI:
10.1021/ic048880w
PDF
Heterobimetallic Bi(III)-Ti(IV) Coordination Complexes: Synthesis and Solid-State Structures of BiTi4(sal)6(-OiPr)3(OiPr)4, and the Cyclic Isomers Bi4Ti4(sal)10(-OiPr)4(OiPr)4 and Bi8Ti8(sal)20(-OiPr)8(OiPr)8
John H. Thurston, Arvind Kumar, Cristina Hofmann, and Kenton H. Whitmire
pp 8427 - 8436; DOI:
10.1021/ic049061e
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Electrochemical Generation of Free Nitric Oxide from Nitrite Catalyzed by Iron meso-Tetrakis(4-N-methylpyridiniumyl)porphyrin
Yuwu Chi, Jingyuan Chen, and Koichi Aoki
pp 8437 - 8446; DOI:
10.1021/ic049323c
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Hydroxyl Radical is the Active Species in Photochemical DNA Strand Scission by Bis(peroxo)vanadium(V) Phenanthroline
Mui Sam, Jung H. Hwang, Guillaume Chanfreau, and Mahdi M. Abu-Omar
pp 8447 - 8455; DOI:
10.1021/ic0486419
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Coordination Chemistry at the Molybdenum Site of Sulfite Oxidase: Redox-Induced Structural Changes in the Cysteine 207 to Serine Mutant
Graham N. George, Robert M. Garrett, Roger C. Prince, and K. V. Rajagopalan
pp 8456 - 8460; DOI:
10.1021/ic0489847
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Rare-Earth Quinolinates: Infrared-Emitting Molecular Materials with a Rich Structural Chemistry
Rik Van Deun, Pascal Fias, Peter Nockemann, An Schepers, Tatjana N. Parac-Vogt, Kristof Van Hecke, Luc Van Meervelt, and Koen Binnemans
pp 8461 - 8469; DOI:
10.1021/ic048736a
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Reduction of the Ferrous -Verdoheme-Cytochrome b5 Complex
Christopher O. Damaso, Nick D. Rubie, Pierre Moënne-Loccoz, and Mario Rivera
pp 8470 - 8478; DOI:
10.1021/ic049029k
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Is the Enthalpy of Fusion of Tris(acetylacetonato)metal(III) Complexes Affected by Their Potential Energy in the Crystal State?
Jasmina Sabolovi, eljko Mrak, Sanja Kotrun, and August Janekovi
pp 8479 - 8489; DOI:
10.1021/ic048900u
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Preparation and Structural Characterization of Three Types of Homo- and Heterotrinuclear Boron Complexes: Salen{[B-O-B][O2BOH]}, Salen{[B-O-B][O2BPh]}, and Salen{[B-O-B][O2P(O)Ph]}
Gabriela Vargas, Irán Hernández, Herbert Höpfl, María-Eugenia Ochoa, Dolores Castillo, Norberto Farfán, Rosa Santillan, and Elizabeth Gómez
pp 8490 - 8500; DOI:
10.1021/ic048862e
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Bi- and Trinuclear Copper(II) Complexes of a Sterically Constrained Phenol-Based Tetradentate Ligand: Syntheses, Structures, and Magnetic Studies
Suman Mukhopadhyay, Debdas Mandal, Pabitra Baran Chatterjee, Cédric Desplanches, Jean-Pascal Sutter, Ray J. Butcher, and Muktimoy Chaudhury
pp 8501 - 8509; DOI:
10.1021/ic049271r
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DNA Binding and Photocleavage in Vitro by New Dirhodium(II) dppz Complexes: Correlation to Cytotoxicity and Photocytotoxicity
Alfredo M. Angeles-Boza, Patricia M. Bradley, Patty K.-L. Fu, Sara E. Wicke, John Bacsa, Kim R. Dunbar, and Claudia Turro
pp 8510 - 8519; DOI:
10.1021/ic049091h
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Toward Optimized High-Relaxivity MRI Agents: Thermodynamic Selectivity of Hydroxypyridonate/Catecholate Ligands1
Valérie C. Pierre, Marco Melchior, Dan M. J. Doble, and Kenneth N. Raymond
pp 8520 - 8525; DOI:
10.1021/ic0493447
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Complexes of the Heavier Alkaline Earth Metals Ca, Sr, and Ba with O-Functionalized Phosphanide Ligands
Stuart Blair, Keith Izod, William Clegg, and Ross W. Harrington
pp 8526 - 8531; DOI:
10.1021/ic048978a
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Synthesis and Structure of Mercurous Ion and Dinuclear Lead(II) Complexes of the 28-Membered Selenaaza Macrocycle: Dominance of the Chelate Ring Size Effect and Conformational Requirement over Soft-Soft Interactions
Snigdha Panda, Harkesh B. Singh, and Ray J. Butcher
pp 8532 - 8537; DOI:
10.1021/ic0351949
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Synthesis, Solution Behavior, Thermal Stability, and Biological Activity of an Fe(III) Complex of an Artificial Siderophore with Intramolecular Hydrogen Bonding Networks
Kenji Matsumoto, Tomohiro Ozawa, Koichiro Jitsukawa, and Hideki Masuda
pp 8538 - 8546; DOI:
10.1021/ic048761g
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Dititanium Complexes of Preorganized Binucleating Bis(amidinates)
Michael J. McNevin and John R. Hagadorn
pp 8547 - 8554; DOI:
10.1021/ic0488841
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Syntheses, Thermal Stability, and Structure Determination of the Novel Isostructural RBa3B9O18 (R = Y, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb)
X. Z. Li, C. Wang, X. L. Chen, H. Li, L. S. Jia, L. Wu, Y. X. Du, and Y. P. Xu
pp 8555 - 8560; DOI:
10.1021/ic049710m
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Structural Increment System for 11-Vertex nido-Boranes and Carboranes
Farooq A. Kiani and Matthias Hofmann
pp 8561 - 8571; DOI:
10.1021/ic049184z
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Synthesis, Characterization, and Tautomerism of Four Novel Copper(I) Complexes from 3-Hydroxy-3-(p-R-phenyl)-2-propenedithioic Acids
Ivan García-Orozco, José G. López-Cortés, M. Carmen Ortega-Alfaro, Rubén Alfredo Toscano, Guillermo Penieres-Carrillo, and Cecilio Alvarez-Toledano
pp 8572 - 8576; DOI:
10.1021/ic0488132
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Hetero-Tripodal Hydroxypyridonate Gadolinium Complexes: Syntheses, Relaxometric Properties, Water Exchange Dynamics, and Human Serum Albumin Binding1
Marlon K. Thompson, Dan M. J. Doble, Luke S. Tso, Serena Barra, Mauro Botta, Silvio Aime, and Kenneth N. Raymond
pp 8577 - 8586; DOI:
10.1021/ic048607u
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The (Calix[4]arene)chloromolybdate(IV) Anion [MoCl(Calix)]-: A Convenient Entry into Molybdenum Calix[4]arene Chemistry
Udo Radius and J. Attner
pp 8587 - 8599; DOI:
10.1021/ic049155o
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Luminescent Piano-Stool Complexes Incorporating 1-(4-Cyanophenyl)imidazole: Synthesis, Spectral, and Structural Studies
Sanjay K. Singh, Manoj Trivedi, M. Chandra, Abhaya N. Sahay, and Daya Shankar Pandey
pp 8600 - 8608; DOI:
10.1021/ic049256m
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Oxygen/Sulfur Substitution Reactions of Tetraoxometalates Effected by Electrophilic Carbon and Silicon Reagents
David V. Partyka and R. H. Holm
pp 8609 - 8616; DOI:
10.1021/ic040097g
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The Crucial Role of the Diphosphine Heteroatom X in the Stereochemistry and Stabilization of the Substitution-Inert [M(N)(PXP)]2+ Metal Fragments (M = Tc, Re; PXP = Diphosphine Ligand)
Francesco Tisato, Fiorenzo Refosco, Marina Porchia, Cristina Bolzati, Giuliano Bandoli, Alessandro Dolmella, Adriano Duatti, Alessandra Boschi, Christian M. Jung, Hans-Juergen Pietzsch, and Werner Kraus
pp 8617 - 8625; DOI:
10.1021/ic049139r
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Tetra-2,3-pyrazinoporphyrazines with Externally Appended Pyridine Rings. 1. Tetrakis-2,3-[5,6-di(2-pyridyl)pyrazino]porphyrazine: A New Macrocycle with Remarkable Electron-Deficient Properties
Maria Pia Donzello, Zhongping Ou, Fabrizio Monacelli, Giampaolo Ricciardi, Corrado Rizzoli, Claudio Ercolani, and Karl M. Kadish
pp 8626 - 8636; DOI:
10.1021/ic048909w
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Tetra-2,3-pyrazinoporphyrazines with Externally Appended Pyridine Rings. 2. Metal Complexes of Tetrakis-2,3-[5,6-di(2-pyridyl)pyrazino]porphyrazine: Linear and Nonlinear Optical Properties and Electrochemical Behavior
Maria Pia Donzello, Zoungping Ou, Danilo Dini, Moreno Meneghetti, Claudio Ercolani, and Karl M. Kadish
pp 8637 - 8648; DOI:
10.1021/ic0489084
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Assemblies of Redox-Active Metallodendrimers Using Hydrogen Bonding for the Electrochemical Recognition of the H2PO4- and Adenosine-triphosphate (ATP2-) Anions
Marie-Christine Daniel, Fatou Ba, Jaime Ruiz Aranzaes, and Didier Astruc
pp 8649 - 8657; DOI:
10.1021/ic0493999
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